• Title/Summary/Keyword: N release rate

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Numerical Investigation of Exhaust Gas Recirculation Effect under Boost Pressure Condition on Homogeneous Charge Compression Autoignition (HCCI엔진의 과급조건에서 EGR영향에 대한 수치해석적 연구)

  • Oh, Chung Hwan;Jamsran, Narankhuu;Lim, Ock Tack
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.6
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    • pp.451-464
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    • 2014
  • This study used numerical methods to investigates investigate the exhaust gas recirculation (EGR) effect under the condition of boost pressure condition on a homogeneous charge compression ignition (HCCI) combustion engine using numerical methods. The detailed chemical-kinetic mechanisms and thermodynamic parameters for n-heptane, iso-octane, and PRF50 from the Lawrence Livermore National Laboratory (LLNL) are were used for this study. The combustion phase affects the efficiency and power. To exclude these effects, this study decided to maintain a 50 burn point (CA50) at 5 CA after top dead center aTDC. The results showed that the EGR increased, but the low temperature heat release (LTHR), negative temperature coefficient (NTC), and high temperature heat release (HTHR) were weakened due by theto effect of the O2 reduction. The combined EGR and boost pressure enhanced the autoignition reactivity, Hhence, the LTHR, NTC, and HTHR were enhanced, and the heat-release rate was increased. also In addition, EGR decraeased the indicated mean effective pressure (IMEP), but the combined EGR and boost pressure increased the IMEP. As a results, combining the ed EGR and boost pressure was effective to at increase increasing the IMEP and maintaining the a low PRR.

Effects of Combining Feed Grade Urea and a Slow-release Urea Product on Characteristics of Digestion, Microbial Protein Synthesis and Digestible Energy in Steers Fed Diets with Different Starch:ADF Ratios

  • Lopez-Soto, M.A.;Rivera-Mendez, C.R.;Aguilar-Hernandez, J.A.;Barreras, A.;Calderon-Cortes, J.F.;Plascencia, A.;Davila-Ramos, H.;Estrada-Angulo, A.;Valdes-Garcia, Y.S.
    • Asian-Australasian Journal of Animal Sciences
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    • v.27 no.2
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    • pp.187-193
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    • 2014
  • As a result of the cost of grains, the replacement of grains by co-products (i.e. DDGS) in feedlot diets is a common practice. This change produces diets that contain a lower amount of starch and greater amount of fibre. Hypothetically, combining feed grade urea (U) with slow release urea (Optigen) in this type of diet should elicit a better synchrony between starch (high-rate of digestion) and fibre (low-rate of digestion) promoting a better microbial protein synthesis and ruminal digestion with increasing the digestible energy of the diet. Four cannulated Holstein steers ($213{\pm}4$ kg) were used in a $4{\times}4$ Latin square design to examine the combination of Optigen and U in a finishing diet containing different starch:acid detergent fibre ratios (S:F) on the characteristics of digestive function. Three S:F ratios (3.0, 4.5, and 6.0) were tested using a combination of U (0.80%) and Optigen (1.0%). Additionally, a treatment of 4.5 S:F ratio with urea (0.80% in ration) as the sole source of non-protein nitrogen was used to compare the effect of urea combination at same S:F ratio. The S:F ratio of the diet was manipulated by replacing the corn grain by dried distillers grain with solubles and roughage. Urea combination did not affect ruminal pH. The S:F ratio did not affect ruminal pH at 0 and 2 h post-feeding but, at 4 and 6 h, the ruminal pH decreased as the S:F ratio increased (linear, p<0.05). Ruminal digestion of OM, starch and feed N were not affected by urea combination or S:F ratio. The urea combination did not affect ADF ruminal digestion. ADF ruminal digestion decreased linearly (p = 0.02) as the S:F ratio increased. Compared to the urea treatment (p<0.05) and within the urea combination treatment (quadratic, p<0.01), the flow of microbial nitrogen (MN) to the small intestine and ruminal microbial efficiency were greater for the urea combination at a S:F ratio of 4.5. Irrespective of the S:F ratio, the urea combination improved (2.8%, p = 0.02) postruminal N digestion. As S:F ratio increased, OM digestion increased, but ADF total tract digestion decreased. The combination of urea at 4.5 S:F improved (2%, p = 0.04) the digestible energy (DE) more than expected. Combining urea and Optigen resulted in positive effects on the MN flow and DE of the diet, but apparently these advantages are observed only when there is a certain proportion of starch:ADF in the diet.

Releasing Characteristics of Nitrogen, Phosphorus and Metals of the Sediments in Boryung Lake (보령호 퇴적물중의 질소, 인 및 중금속의 용출특성)

  • Ryu, Byong-Ro
    • Journal of the Korean GEO-environmental Society
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    • v.2 no.4
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    • pp.29-38
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    • 2001
  • In this study, the fractional composition and the releasing of nutrients and metals from sediments of Boryung reservoir were investigated. Based on present study, the forms of sediment phosphorus of the four sites in reservoir were classified as adsorbed phosphorus, non apatite inorganic phosphorus(NAI-P), apatite phosphorus and residual phosphorus. Residual phosphorus showed the highest fration, NAI-P second, apatite phosphorus third and absorbed phosphorus fourth. The sedimentation rate of T-P and T-N in aerobic condition were $0.31mg/m^2{\cdot}day$ and $29mg/m^2{\cdot}day$. The sedimentation rate of T-P and T-N in anaerobic condition were $0.12mg/m^2{\cdot}day$ and $13.6mg/m^2{\cdot}day$. The releasing rate of T-P and T-N in anaerobic condition were $0.23mg/m^2{\cdot}day$ and $10.5mg/m^2{\cdot}day$.

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Effects of Synchronization of Carbohydrate and Protein Supply in Total Mixed Ration with Korean Rice Wine Residue on Ruminal Fermentation, Nitrogen Metabolism and Microbial Protein Synthesis in Holstein Steers

  • Piao, Min Yu;Kim, Hyun-J.;Seo, J.K.;Park, T.S.;Yoon, J.S.;Kim, K.H.;Ha, Jong-K.
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.11
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    • pp.1568-1574
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    • 2012
  • Three Holstein steers in the growing phase, each with a ruminal cannula, were used to test the hypothesis that the synchronization of the hourly rate of carbohydrate and nitrogen (N) released in the rumen would increase the amount of retained nitrogen for growth and thus improve the efficiency of microbial protein synthesis (EMPS). In Experiment 1, in situ degradability coefficients of carbohydrate and N in feeds including Korean rice wine residue (RWR) were determined. In Experiment 2, three total mixed ration (TMR) diets having different rates of carbohydrate and N release in the rumen were formulated using the in situ degradability of the feeds. All diets were made to contain similar contents of crude protein (CP) and neutral detergent fiber (NDF) but varied in their hourly pattern of nutrient release. The synchrony index of the three TMRs was 0.51 (LS), 0.77 (MS) and 0.95 (HS), respectively. The diets were fed at a restricted level (2% of the animal's body weight) in a $3{\times}3$ Latin-square design. Synchronizing the hourly supply of energy and N in the rumen did not significantly alter the digestibility of dry matter, organic matter, crude protein, NDF or acid detergent fiber (ADF) (p>0.05). The ruminal $NH_3$-N content of the LS group at three hours after feeding was significantly higher (p<0.05) than that of the other groups; however, the mean values of ruminal $NH_3$-N, pH and VFA concentration among the three groups were not significantly different (p>0.05). In addition, the purine derivative (PD) excretion in urine and microbial-N production (MN) among the three groups were not significantly different (p>0.05). In conclusion, synchronizing dietary energy and N supply to the rumen did not have a major effect on nutrient digestion or microbial protein synthesis (MPS) in Holstein steers.

Dredging Bottom Sediments of Seoha Weir at the Downstream of Kyongan Stream can be Used as a Feasible Pollutant Load Reduction Option in the Total Pollutant Load Management System of Kwangju City? (경안천 서하보 수저퇴적물 준설이 경기도 광주시 수질오염총량관리에 있어 추가적인 부하량 삭감수단으로써 타당한가?)

  • Yu, Seung-Hoon;Lee, Bum-Yeon;Lee, Kang-Hyun;Park, Shin Jung;Lee, Chang-Hee
    • Journal of Korean Society on Water Environment
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    • v.27 no.1
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    • pp.19-29
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    • 2011
  • In order to assess the influences of bottom sediment on water quality, following measurement were made. (1) Estimations of pollutant loads from the bottom sediment based on mass balance concept, (2) measurements of pollutant concentrations in the sediment to assess the pollution level and influence potential, (3) in situ and laboratory measurements of Sediment Oxygen Demants (SOD) and pollutant load (sediment release) from bottom sediment. Analyses of inflow and outflow loadings using simple mass balance show that there are some variations found according to the pollutants. However, there is no consistent evidence that the sediment can be a source of pollutants. Pollutant concentrations in the sediment range 16~724.8 mg/kg (COD), 1.68 ~12.64 mg/kg (T-P), 5.6~76.8 mg/kg (T-N), 0.32~21.6 mg/kg ($NH_3$-N), 0.092~0.544 mg/kg ($NO_2$-N), 4.8~18.4 mg/kg ($NO_3$-N), and 1.59~11.23 mg/kg ($PO_4$-P). Measured SOD ranges $0.190{\sim}0.802g{\cdot}m^{-2}{\cdot}d^{-1}$ and measured release rate ranges $-1618.42{\sim}10mg/m^2{\cdot}d$(COD), $-12{\sim}16mg/m^2{\cdot}d$(T-P), $-197.37{\sim}140mg/m^2{\cdot}d$(T-N), $0.4{\sim}74.32mg/m^2{\cdot}d$($NH_3$-N), $-2.04{\sim}0.8mg/m^2{\cdot}d$ ($NO_2$-N), $-70{\sim}40mg/m^2{\cdot}d$ ($NO_3$-N), and $-26.11{\sim}28.55mg/m^2{\cdot}d$($PO_4$-P). All study results indicate that bottom sediments in the Seoha weir show only limited effects on the water quality. It implies that sediment dredging is not an effective option or management measure to reduce pollutant loading.

The Study of TCE Dechlorination using Geobacter lovleyi with Slow Release Substrate Applied (Slow Release Substrate를 이용한 Geobacter lovleyi의 TCE 탈염소화 연구)

  • Cha, Jae Hun;An, Sang Woo;Park, Jae Woo;Chang, Soon Woong
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.9
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    • pp.53-59
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    • 2012
  • This study investigated characteristics of decomposition of tetrabutoxysilane (TBOS) as a slow release substrate (SRS) and on effect of TBOS decompostion compounds (acetate and butylate) for anaerobic dechlorination of trichloroethylene (TCE). In the batch experiment, TCE, cis-dichloroethene (cis-DCE), 1-butanol and TBOS were analysed by GC/FID and acetate and butylate were measured by HPLC. 1M of TBOS transferred and accumulated 4M of 1-butanol by abiotically hydrolysis reaction. The hydrolysis rate was in a range of 0.186 ${\mu}M/day$. On other hand, 1-butanol fermented to butyrate and acetate with indigenous culture from natural sediments. This results showed that TBOS could be used a slow release substrate in the natural sites. The dechlorinated potential of TCE with acetate and butyrate was increased with a decreasing initial TCE concentrations. In addition, first order coefficients of dechlorination with acetate as electron donor was higher then that with butyrate. It is because that dechlorination of Geobacter lovleyi was affected by substrate affinity, biodegradability and microbial acclimation on various substrates. However, dechlorinated potential of Geobacter lovleyi was decreased with accumulation cis-DCE in the anaerobic decholoronation process. The overall results indicated that SRS with Geobacter lovleyi might be a promising material for enhancing dechlorination of TCE on natural site and cis-DCE should be treated by ZVI as reductive material or by coexisting other dechlorinated bacteria.

Role of Peptides in Rumen Microbial Metabolism - Review -

  • Wallace, R.J.;Atasoglu, C.;Newbold, C.J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.12 no.1
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    • pp.139-147
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    • 1999
  • Peptides are formed in the rumen as the result of microbial proteinase activity. The predominant type of activity is cysteine ptoteinase, but others, such as serine proteinases, are also present. Many species of protozoa, bacteria and fungi are involved in ptoteolysis; large animal-to-animal variability is found when proteinase activities in different animals are compared. The peptides formed from proteolysis are broken down to amino acids by peptidases. Different peptides are broken down at different rates, depending on their chemical composition and particularly their N-terminal structure. Indeed, chemical addition to the N-terminus of small peptides, such as by acetylation, causes the peptides to become stable to breakdown by the rumen microbial population; the microorganisms do not appear to adapt to hydrolyse acetylated peptides even after several weeks exposure to dietary acetylated peptides, and the amino acids present in acetylated peptides are absorbed from the small intestine. The amino acids present in some acetylated peptides remain available in nutritional trials with rats, but the nutritive value of the whole amino acid mixture is decreased by acetylation. The genus Prevotella is responsible for most of the catabolic peptidase activity in the rumen, via its dipeptidyl peptidase activities, which release dipeptides rather than free amino acids from the N-terminus of oligopeptides. Studies with dipeptidyl peptidase mutants of Prevotella suggest that it may be possible to slow the rate of peptide hydrolysis by the mixed rumen microbial population by inhibiting dipeptidyl peptidase activity of Prevotella or the rate of peptide uptake by this genus. Peptides and amino acids also stimulate the growth of rumen microorganisms, and are necessary for optimal growth rates of many species growing on tapidly fermented substrates; in rich medium, most bacteria use pre-formed amino acids for more than 90% of their amino acid requirements. Cellulolytic species are exceptional in this respect, but they still incorporate about half of their cell N from pre-formed amino acids in rich medium. However, the extent to which bacteria use ammonia vs. peptides and amino acids for protein synthesis also depends on the concentrations of each, such that preformed amino acids and peptides are probably used to a much lesser extent in vivo than many in vitro experiments might suggest.

Effects of DME Additives on Combustion Characteristics and Nano-particle Distributions in a Single Cylinder Compression Ignition Engine (DME 연료에 첨가제를 혼합하였을 때의 연소 특성 및 배출가스 특성에 관한 연구)

  • Kwon, Seok-Joo;Cha, June-Pyo;Kang, Min-Gu;Lee, Chang-Sik;Park, Sung-Wook;Lim, Young-Kwan
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.5
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    • pp.19-25
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    • 2012
  • This study describes effects of DME additives on combustion and exhaust emissions characteristics including nano-particle in a single cylinder compression ignition engine. Considered additives include bio-diesel, n-butanol, and MTBE for increasing kinematic viscosity. Among three additives, n-butanol showed the greatest kinematic viscosity. In addition MTBE showed the highest vapor pressure. In the present study mixing ratios of additives were kept constant at 1 and 10% by volume. Experiments were performed at 1200rpm engine speed and nano-particles were measured by SMPS (Scanning mobility particle sizer) devices. Results of combustion characteristics showed that considered additives had little effects on combustion pressure. However, patterns of heat release rate were dependent on properties of additives. Nano-particles of MTBE were the lowest among considered additives.

Role of glutamine synthetase as as regulator of nitrogenase in rhodopseudomonas sphaeroides D-230 (광합성 세균에 있어서의 질소고정효소 합성 조절자로서의 glutamine synthetase의 역할)

  • 이혜주
    • Korean Journal of Microbiology
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    • v.24 no.2
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    • pp.113-118
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    • 1986
  • Optimum temperature and pH of glutamine synthetase activity (E.C. 3.6.1.2.) of R. sphaeroides D-230 was $35^{\circ}C$ and 6.8, respectively. The adenylated state of GS in R. sphaeroides D-230 was stabilized by addition of 0.2mg/ml of cethyltrimethylammoniumbromide. Valine, histidine, proline, isoleucine, and lysine were good nitrogen source for the growth of R. sphaeroides D-230. The growth of R. sphaeroides D-230 in $N_2,\;NaNO_3\;or\;NH_4Cl$ as sole nitrogen source was lower than in any otherculture conditions. GS activity was inhibited, more or less, by various amino acid. THe relative inhibition rate of the enzyme by added 7mM arginine, $NH_4Cl,\;N_2,\;and\;NaNO_3$ was 63.8%, 26.79%, 6.24%, and 10.64%, drespectively. THe hydrogen evolution of R. sphaeroides D-230 grown in N-limited media was inhibited by 0.1mM MSX, irreversible GS inhibitor. GS activity was completely inhibited by 1.0mM MSX but ammonia released maximally at the same concentration of MSX. Ammonia release by added MSX was increased up to 1.0mM MS, but decreased above 1.0mM MSX. It is probably due to inhibition of nitrogenase actixity by MSX. Nitrogenase activity was not inhibited at low concentration of MSX. These results suggests that the inhibition of nitrogenase activity by ammonia is mediated by products of ammonia assimilation rather than by ammonia itself.

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Introduction to Thermoacoustic Models for Combustion Instability Prediction Using Flame Transfer Function (화염 전달 함수를 이용한 열음향 연소 불안정 해석 모델 소개)

  • Kim, Dae-Sik
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.6
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    • pp.98-106
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    • 2011
  • This paper reviews the state-of-the-art thermoacoustic(TA) modeling techniques and research trend to predict major parameters determining combustion instabilities in lean premixed gas turbine combustors. Linear TA modeling results give us an information on eigenfrequencies and initial growth rate of the instabilities. For the prediction, linear relation equation between acoustic waves and heat release oscillations should be derived in the determined system. Key information for this analysis is to determine the heat release fluctuations in the combustor, which is typically obtained by using n-${\tau}$ function from flame transfer function measurements and/or predictions. Great advancement in the linear TA modeling has been made over a couple of decades, and some successful prediction results have been reported in actual gas turbine combustors. However nonlinear TA model developments which are required to analyze nonlinear system behaviors such as limit cycle saturation and transition phenomena are still limited in a very simple system. In order to fully understand combustion instabilities in a complicated real system, nonlinear flame dynamics and acoustic wave interaction with nonlinear system boundary conditions should be explained from the nonlinear TA model developments.