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Effect of $SO_2$ on DeNOx by Ammonia in Simultaneous Removal of SOx and NOx over Activated Coke (활성 코우크스상의 동시 탈황탈질에서 암모니아에 의한 탈질에 이산화황이 미치는 영향)

  • Kim, Hark-Joon;Yoon, Cho-Hee
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.2
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    • pp.201-208
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    • 2010
  • The $SO_2$ and $NO_x$ removal with an activated coke catalyst was conducted by a two-stage reaction which first $SO_2$ was oxidized to $H_2SO_4$ and then $NO_x$ was reduced to $N_2$. But if unreacted sulfur dioxide entered in the second stage, the $NO_x$ reduction was hindered by the reaction with ammonia. In this study, experimental investigations by using lab-scale column apparatus on the product and the reactivity of $SO_2$ with ammonia over coke catalyst which was activated with sulfuric acid was carried out through ultimate analysis DTA, TGA and SEM of catalyst before and after the reaction. Also, the effect of reaction emperature on the reactivity of $SO_2$ with ammonia was determined by means of breakthrough curves with time. The obtained results from this study were summarized as following; Activated cokes were decreased carbon component and increased oxygen and sulfur components in comparison with original cokes. The products over coke catalyst were faced fine crystal of $(NH_4)_2SO_4$, which results in the pressure loss of reacting system. The order of general reactivity in terms of the reaction temperature after breakthrough for $SO_2$ was found to be $150^{\circ}C$ > $200^{\circ}C$ > $100^{\circ}C$. This was related to adsorption amounts of ammonia on the activated cokes.

Reduction of Authentication Cost Based on Key Caching for Inter-MME Handover Support (MME 도메인간 핸드오버 지원을 위한 키캐싱 기반 인증비용의 감소기법)

  • Hwang, Hakseon;Jeong, Jongpil
    • The Journal of the Institute of Internet, Broadcasting and Communication
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    • v.13 no.5
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    • pp.209-220
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    • 2013
  • Handover is the technology to minimize data lose of mobile devices and make continuous communication possible even if the device could be moved from one digital cell site to another one. That is, it is a function that enables the mobile user to avoid the disconnection of phone conversations when moving from a specific mobile communication area to another. Today, there are a lot of ongoing researches for fast and efficient hand-over, in order to address phone call's delay and disconnection which are believed to be the mobile network's biggest problems, and these should essentially be resolved in all mobile networks. Thanks to recent technology development in mobile network, the LTE network has been commercialized today and it has finally opened a new era that makes it possible for mobile phones to process data at high speed. In LTE network environment, however, a new authentication key must be generated for the hand-over. In this case, there can be a problem that the authentication process conducted by the hand-over incurs its authentication cost and delay time. This essay suggests an efficient key caching hand-over method which simplifies the authentication process: when UE makes hand-over from oMME to nMME, the oMME keeps the authentication key for a period of time, and if it returns to the previous MME within the key's lifetime, the saved key can be re-used.

The Effects of Tacrolimus versus Cyclosporine on Acute Graft Rejection Episode and Acute Renal Dysfunction Following Pancreas Transplantation (췌장이식환자에서 Tacrolimus와 Cyclosporine이 급성거부반응과 신장장애에 미치는 영향)

  • Oh, Jung Mi;Klassen, David
    • Korean Journal of Clinical Pharmacy
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    • v.9 no.2
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    • pp.81-87
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    • 1999
  • 췌장이식의 성공률은 지난 10년 동안 상당히 상승되었다. International Pancreas Transplant Registry에 따르면 1995년 이래 미국에서만 매년 1,000건 이상의 췌장이식이 실시되고 있다. 장기이식후 나타나는 급성 거부반응은 이식 후 6개월 이내에 가장 높은 빈도수로 나타난다. 췌장이식환자에서는 신장을 이식한 것보다 두배나 높은 거부반응을 나타나며 이로 인한 입원율의 증가 항림프제(antilyinphocyte) 사용과 감염의 증가로 이환율이 높다. 더구나 Cyclosporine (CsA)을 기초로 한 면역억제제요법의 사용은 높은 급성 거부반응률(acute graft rejection)을 초래하여 이식한 장기의 조직손실이 문제가 되고 있다. 새로운 면역억제제인 Tacrolimus (FK506)의 사용은 이식환자에서의 거부반응을 감소시켜 생존율을 증가시키는 것으로 알려져 있다. Tacrolimus는 neutral macrolide로 cyclic peptide인 CsA과는 화학 구조는 매우 다르나 비슷한 면역억제 효과를 보인다. 하지만 Tacrolimus의 사용시 신경독성, 신독성, 특히 고혈당증의 발생률이 높아 일부 이식센터에서는 장기 이식 후에 사용하기를 꺼리기도 한다. 하지만 여러 연구논문에서 간과 신장 이식 후 급성 거부반응 예방에 Tacrolimus는 CsA에 비해 이점이 있는 결과를 발표하였다. 결과적으로, 현재 췌장이식 후 Tacrolimus를 기초로 한 면역억제의 효과에 대한 연구가 활발히 진행중이다. 따라서 본 연구에서는 1994-1996년 사이에 Tacrolimus 또는 CsA를 기초로 한 면역억제요법을 투여 받은 췌장이식환자 101명을 후향적으로 조사하여 Tacrolimus (n=54)와 CsA(n=57)의 급성 거부반응 예방 효과와 신부전 발생률을 비교하였다. 모든 환자는 항림프구 약물, Azathioprine, Prednisone을 이식 후 면역억제제로 투여 받았다 기준선으로부터 $20\%$ 이상의 혈청 creatinine의 상승이 있는 환자에서는 급성 신부전으로 정의하였고 신장생검법으로 거부반응을 진단하였다 Matched-pair analysis에 따르면 췌장이식환자의 6개월 생존율은 CsA군에서 $97\%$, Tacrolimus군에서 $96\%$로 별다른 차이가 없었으며 (p=0.57), 6개월간의 이식한 췌장의 보존율은 CsA군에서는 $88\%, Tacrolimus에서 $91\%$. 유의한 차이는 없었다(p=0.29). 췌장이식 후 6개월 동안 Tacrolimus의 사용은 생검으로 증명되는(biopsy-proven) 급성 거부반응의 발생빈도는 CsA보다 유의하게 낮았을 뿐만 아니라 (p<0.05) 거부반응 증상의 심각도 또한 감소시켰다 (p=0.03). 급성거부반응 발생빈도의 감소로 Tacrolimus군에서 antilymphocyte 치료가 유의하게 줄어들었다(p=0.01). CsA군에서 Tacrolimus보다 신부전의 발생률이 높았으나 통계학적 차이는 없었다. 췌장이식후의 최적의 면역억제요법의 결정하기 위해서는 향후 Tacrolimus와 CsA을 비교하는 전향적 무작위 연구가 필요하다.

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Cell Coverage Based on Calculation of the Voice-Data Erlang Capacity in a WCDMA Reverse Link with Multi-rate Traffic (WCDMA 역방향 링크에서 다중속도 트래픽에 따른 음성/데이터 얼랑용량 계산과 셀 커버리지)

  • Kwon, Young-Soo;Han, Tae-Young;Kim, Nam
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.15 no.4
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    • pp.387-396
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    • 2004
  • A scheme to evaluate the number of users and cell coverage of a WCDMA supporting multi-rate traffic is newly presented through calculation of the realizable Erlang capacity from a derived blocking probability and the path loss from the COST231 Walfisch-Ikegami(W) model. We evaluate the voice-data Erlang capacities at various data rates of 15 kbps to 960 kbps and it is shown that they have a linear relationship to each other. When the E$\_$b//N$\_$o/ is low from 4 ㏈ to 3 ㏈ in case of voice capacity of 50 Erlang at 8 kbps, the result shows the increase for the data capacity of 10 Erlang and the enlargement of 100 m for the cell coverage at low rate of 15 kbps, and the increase of 0.11 Erlang and the enlargement of 40 m at high rate of 960 kbps. The increase of the blocking probability results in the increase of the Erlang capacity, but not an effect on the cell coverage, and the increase of active users in a cell results in the decrease of the coverage.

Studies on Miniaturization and Notched Wi-Fi Bandwidth for UWB Antenna Using a Wide Radiating Slot (넓은 방사 슬롯을 이용한 초광대역 안테나의 소형화와 Wi-Fi 대역의 노치에 관한 연구)

  • Beom, Kyeong-Hwa;Kim, Ki-Chan;Jo, Se-Young;Ko, Young-Ho
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.2
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    • pp.265-274
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    • 2011
  • In this paper, it is studied on wide radiating slot antenna's miniaturization for ultra wide-band(UWB) technologies and notch structure to prevent interference between UWB systems and existing wireless systems for using Wi-Fi service of IEEE standards 802.11 a/n. Proposed antenna that wide slot is decreased from $\lambda/2$ to $\lambda/4$ length of resonant frequency has decreased by 72 % compared with conventional antenna. And optimized T-shaped CPW-fed stub has satisfied UWB bandwidth for 3.0~11.8 GHz. Then, creating 2-order Hilbert curve slot line in the stub's patch area, 4.9~5.6 GHz that centered frequency is 5 GHz is eliminated. Finally, the designed antenna constructed on FR4-epoxy has $20{\times}15\;mm^2$ dimension. The measured results that are obtained return loss under -10 dB through 3.2~11.8 GHz without Wi-Fi bandwidth, a linear phase characteristic, a stable group delay, and omnidirectional radiation patterns are presented.

AN EVALUATION OF WEAR CHARACTERISTICS OF LIGHT-CURED RESTORATIVE COMPOSITES ON ENAMEL SURFACE (광중합형 복합레진과 법랑질간의 마모특성 평가)

  • Baik, Byeong-Ju;Lee, Seung-Young;Lee, Doo-Cheol;Kim, Jae-Gon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.28 no.2
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    • pp.261-270
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    • 2001
  • This study was performed to evaluate wear characteristics of light-cured composites when opposed by human enamel. Seven light-cured restorative composites were selected and enamel cusps sectioned from premolars. All samples were stored in distilled water at $37^{\circ}C$ for 10 days. 68.6 N of weight was loaded during the test. The measurements of vertical loss of enamel cusps, weight loss and volume loss of composites, and SEM observations of the polished and abraded surfaces were made after 30,000 cycles. The results obtained were summarized as follows; 1. The highest hardness value of 70.4 was observed in the Spectrum group and the lowest value of 19.8 was observed in the Heliomolar group. Results of Tukey test showed that an overall significant difference was indicated except the Spectrum, Z100 and Clearfil AP-X groups(p<0.05). 2. Enamel showed the good abrasion resistance against the Heliomolar group of microfilled composite and the Palpique Toughwell group containing the submicron hybrid type spherical fillers. 3. The abrasive wear resistance of hybrid composites was improved with the decrease of mean particle size and hybrid of submicron particle fillers. 4. SEM observation of worn surfaces revealed the protrusion, attrition and missing of fillers, cracks developing and delamination in the matrix.

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Analysis of Isoflavone Contents of Soybean By-products with Acid Hydrolysis Method (산 가수분해시 가열방법과 시간 및 추출조건에 따른 대두가공 부산물의 이소플라본 함량 변화)

  • Han, Jin-Suk;Hong, Hee-Do;Kim, Sung-Ran
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.10
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    • pp.1420-1426
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    • 2006
  • To establish a rapid and effective method for the analysis of soy isoflavone which is known to have lots of variation in derivatives of glucoside, conversion rate from isoflavone conjugates to its aglycones, and decomposition of conversed aglycones were investigated with various acid hydrolysis conditions. A number of heating conditions for acid hydrolysis including heating at convection oven $(105^{\circ}C)$, water bath $(95^{\circ}C)$, heating block $(120^{\circ}C)$, and hot plate $(120^{\circ}C)$ were applied. Acid hydrolysis in heating block with reflux was chosen as the best heating condition. From the stability test of isoflavone aglycone during acid hydrolysis, genistein, daidzein, and glycitein did not show any significant changes in their contents for 60 min of hydrolysis. Ten to thirty milligram of sample per 1 mL HCl was the best ratio of sample to acid. As conclusion, acid hydrolysis for 60 min after addition of 15 mL HCl solution to 0.5 g soybean, and then fill up to 50 mL with methanol, followed by HPLC analysis was set as a final analysis method. From this method, isoflavone contents expressed as total aglycone of feed meal was the highest with content of $1288.5{\mu}g/g$ followed by those of dehulled meal.

Analysis of Amine Absorbents Volatility Based on the Chemical Structure (아민 흡수제의 화학구조에 따른 휘발 특성)

  • Lee, Kyung Ja;Lee, Ji Hyun;Kwak, No Sang;Lee, In Young;Kim, Jun Han;Eom, Yong Seok;Jang, Kyung Ryoung;Shim, Jae Goo;Lee, Yongtaek
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.348-352
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    • 2012
  • Amine volatility occurring on the $CO_2$ capture process may result in significant economic losses and environmental impact. In this study, using an volatility measurement apparatus, we measured a amine volatility of various amines including MEA(Monoethanolamine), MDEA(N-Methyldiethanolamine), Pz(Piperazine), AMP(2-Amino-2-methyl-1-propanol), 2-MP(2-Methylpiperazine), DGA(Diglycolamine). For the quantitative analysis of volatility, we analyzed the effects of temperature and $CO_2$ loading using an gas chromatography analysis. The result shows that the amine volatility was increased by increasing Henry's constant(MDEA$-CH_3$)(for AMP).

Performance Analysis of Beam Steering Algorithm According to the Signal Separation (신호 이격도에 따른 빔 제어 알고리즘 성능 분석)

  • Yun, Seonhui;Oh, Jongchan;Kim, Jun O;Nam, Juhun;Choi, Sangwook;Ahn, Jaemin
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39C no.11
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    • pp.1023-1030
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    • 2014
  • Beam steering algorithms using array antenna are mainly used in such a manner as anti-jamming method. However, the performance is changed according to the position of signals despite the same number of signals and the same received power. In this paper, we analyzed the effect of the position relationship of the signals on the performance of the beam steering algorithms. Therefore, we defined 'signal separation' as the minimum angle of the interference signals and the desired signal, and analysed the relationship between the C/N0 performance of beam steering algorithms as LCMV/PM and the signal separation. For simulation, we set many GPS signals and jamming signals compared to the degrees of freedom. And changed the position and the height of the receiver in order to obtain various signal separation angles. In addition, we examined the effects of signal separation and JSR on the anti-jamming performance by applying the loss factors of the received power. Through the research, there is a tendency that the performance of beam steering algorithms is increased with the increase of the signal separation, and signal separation is more severely affecting on the anti-jamming performance compared to the number of signals and JSR.

Ferroelectric Properties of ErMnO3 Thin Film Prepared by Sol-gel Method (졸겔법으로 제조한 ErMnO3 박막의 강유전 특성)

  • Kim, Yoo-Taek;Kim, Eung-Soo;Chae, Jung-Hoon;Ryu, Jae-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.9
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    • pp.829-834
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    • 2002
  • Ferroelectric properties of $ErMnO_3$ thin films deposited on Si(100) substrate using Sol-gel process with metal salts were investigated. $ErMnO_3$ thin films with a (001) preferred orientation were crystallized at 800$^{\circ}C$. The $ErMnO_3$ thin film post-annealed at 800$^{\circ}C$ for 1 h showed the dielectric constant(k) of 26 and the dielectric loss(tan ${\delta}$) of 0.032 at the frequency range from 1 to 100 KHz. The grain size of $ErMnO_3$ thin film post-annealed at 800 for 1 h was 10∼30 nm. The remanent polarization($P_r$) of the $ErMnO_3$ thin films increased with increasing (001) preferred orientation. The $ErMnO_3$ thin films post-annealed at 800$^{\circ}C$ for 1 h showed the remanent polarization($P_r$) of 400 nC/$cm^2$, with the increase of post-annealing time at 800$^{\circ}C$, the coercive field($E_c$) of thin films was lowered because the dense and homogeneous thin films were obtained.