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Research on Microstructure and Properties of TiN, (Ti, Al)N and TiN/(Ti, Al)N Multilayer Coatings

  • Wang, She Quan;Chen, Li;Yin, Fei;Jia, Li
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.658-659
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    • 2006
  • Magnetron sputtered TiN, (Ti, Al)N and TiN/(Ti, Al)N multilayer coatings grown on cemented carbide substrates have been characterized by using electron probe microanalysis (EPMA), X-ray diffraction (XRD), scanning electron spectroscopy (SEM), nanoindentation, scratcher and cutting tests. Results show that TiN coating is bell mouth columnar structures, (Ti, Al)N coating is straight columnar structures and the modulation structure has been formed in the TiN/(Ti, Al)N multilayer coating. TiN/(Ti, Al)N multilayer coating exhibited higher hardness, better adhesion with substrate and excellent cutting performance compared with TiN and (Ti, Al)N coating.

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A Study of Physical and Optical Properties of GaN grown using In-situ SiN Mask by MOCVD (In-situ SiN Mask를 이용하여 성장한 GaN 박막의 물성적, 광학적 특성 연구)

  • Kim, Deok-Kyu;Jeong, Jong-Yub;Park, Choon-Bae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.121-124
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    • 2004
  • We have grown GaN layers with in-situ SiN mask by metal organic chemical vapor deposition(MOCVD) and study the physical properties of the GaN layer. We have also investigate the effect of the SiN mask on its optical property. By inserting a SiN mask, (102) the full width at half maximum(FWHM) decreased from 480 arcsec to 409 arcsec. The PL intensity of GaN with SiN mask improved 2 times to that without SiN mask. We have thus shown that the SiN mask improved significantly the physical and optical properties of the GgN layer.

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CHARACTERIZATIONS OF THE WEIBULL DISTRIBUTION BY THE INDEPENDENCE OF THE UPPER RECORD VALUES

  • Chang, Se-Kyung;Lee, Min-Young
    • The Pure and Applied Mathematics
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    • v.15 no.2
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    • pp.163-167
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    • 2008
  • This paper presents characterizations of the Weibull distribution by the independence of record values. We prove that $X\;{\in}\;W\;EI ({\alpha})$, if and only if $\frac {X_{U(n+l)}} {X_{U(n+1)}\;+\;X_{U(n)}}$ and $X_{U(n+1)}$ for $n{\geq}1$ are independent or $\frac {X_{U(n)}} {X_{U(n+1)}\;+\;X_{U(n)}}$ and $X_{U(n+1)}$ for $n{\geq}1$ are independent. And also we establish that $X\;{\in}\;W\;EI({\alpha})$, if and only if $\frac {X_{U(n+1)}\;-\;X_{U(n)}} {X_{U(n+1)}\;+\;X_{U(n)}}$ and $X_{U(n+1)}$ for $n{\geq}1$ are independent.

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The Degradation of hydrocarbons in Petal of Azalea by Gokja (진달래꽃 탄화수소류의 곡자에 의한 분해)

  • 홍태희
    • The Korean Journal of Food And Nutrition
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    • v.12 no.4
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    • pp.415-420
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    • 1999
  • Petal of Azalea(Rhododendron mucronulatum Turcz) was incubated with Gokja at 3$0^{\circ}C$ for seven days and the essential oil components of petal of Azalea before and after incubated were analyzed using a GC/MSD. Ten or more essential oil components including n-heneicosane n-tricosane n-tetreacosane n-pentacosane n-heptacosane n-nonacosane and n-hentriacontane were identified from the petal of Azal-ea before incubated while oxygen-containng compounds including (E)-heptenal 2-ethoxy-1 -hexanol n-hexadecanoic acid methyl ester 9, 12-octadecadienoic acid methyl ester 9,12,15-octadecatrienoic acid methyl ester, n-octadecanoic acid methyl ester n-eicosanoic acid methyl ester and 9-docosaenoic acid methyl ester as well as n-alkanes such as n-tricosane that n-pentacosane were identified from the petal of Azalea after incubated. These results suggest that n-alkanes in petal of Azalea might be degraded and some oxygen-containing compounds such as aldehyde, esters and /or acids might be produced when pet-al of Azalea is incubated with Gokja.

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The Stereochemistry of the Metal Complexes of Novel Stereospecific Quadridentate Ligands, Cobalt(Ⅲ) Complexes of N,N$^\prime$-dimethylethlenediamine-N,N$^\prime$-di-$\alpha$-propionato and N,N$^\prime$-dimethlethylenediamine-N,N$^\prime$-diacetato Ligands

  • Jun, Moo- Jin;Jung, Jin- Seung;Kim, Chang-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.6 no.6
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    • pp.369-374
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    • 1985
  • A new flexible quadridentate ligand, N,N'-dimethylethylenediamine-N,N'-di-${\alpha}$-propionic acid (dmedpa) has been synthesized, and diammine and ethylenediamine cobalt(III) complexes of dmedpa, $[Co(dmedpa)(NH_3)_2]^+$ and $[Co(dmedpa(en)]^+,$ have been prepared. Only s-cis isomer has been yielede. A known N,N'-dimethylethylediamine-N,N'-diacetic acid (dmedda) has also been prepared. Dichloro cobalt(III) complexes of both dmedda and dmedpa have been prepared. Only the s-cis isomer has been yielded in the $[Co(dmedda)Cl_2]^-$ complex, while only the uns-cis isomer has been obtained for the $[Co(dmedpa)Cl_2]^-$ complex.

Syntheses of Phosphonamides Containing Aminobenzylphosphonic Acid and Aminopenicillanic Acid

  • Hong, Suk-In;Kim, Chang-Sick;Kim, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.4 no.4
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    • pp.171-175
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    • 1983
  • This paper reports new phosphonamide derivatives which contain diethyl aminomethylphosphonate, diethyl DL-1-aminobenzylphosphonate and 6-aminopenicillanic acid; N-(ethyl phthalimidomethylphosphonyl)-L-methionine methyl ester, N-(ethyl phthalimidomethylphosphonyl)-L-valine ethyl ester, N-[ethyl N-(methoxycarbonylmethyl)benzylphosphonamido]-2-phthalimidoacetamide, N-[ethyl N-(diethyl phosphonylbenzyl)methylphthalamido] phthalimide, N-[ethyl {ethyl N-(diethyl phosphonylbenzyl)aminomethylphosphonamido} phosphonylmethyl] phthalimide, N-[ethyl N-(diethyl phosphonylbenzyl)methylphosphonamido]-2-phthalimidoacetamide, N, N'-bis (ethyl phthalimidomethylphosphonyl)ethylene diamine, 6-(ethyl DL-1-aminobenzylphosphonamido) penicillanic acid, ethyl N-(ethoxycarbonylmethyl)-1-aminobenzylphosphonamide, ethyl N-(diethyl phosphonylbenzyl)aminomethylphosphonamide and N,N'-bis (ethyl aminomethylphosphonyl) ethylene diamine.

SEMIPRIME RINGS WITH INVOLUTION AND CENTRALIZERS

  • ANSARI, ABU ZAID;SHUJAT, FAIZA
    • Journal of applied mathematics & informatics
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    • v.40 no.3_4
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    • pp.709-717
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    • 2022
  • The objective of this research is to prove that an additive mapping T : R → R is a left as well as right centralizer on R if it satisfies any one of the following identities: (i) T(xnyn + ynxn) = T(xn)yn + ynT(xn) (ii) 2T(xnyn) = T(xn)yn + ynT(xn) for each x, y ∈ R, where n ≥ 1 is a fixed integer and R is any n!-torsion free semiprime ring. In addition, we talk over above identities in the setting of *-ring(ring with involution).

SOME CLASSES OF OPERATORS RELATED TO (m, n)-PARANORMAL AND (m, n)*-PARANORMAL OPERATORS

  • Shine Lal Enose;Ramya Perumal;Prasad Thankarajan
    • Communications of the Korean Mathematical Society
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    • v.38 no.4
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    • pp.1075-1090
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    • 2023
  • In this paper, we study new classes of operators k-quasi (m, n)-paranormal operator, k-quasi (m, n)*-paranormal operator, k-quasi (m, n)-class 𝒬 operator and k-quasi (m, n)-class 𝒬* operator which are the generalization of (m, n)-paranormal and (m, n)*-paranormal operators. We give matrix characterizations for k-quasi (m, n)-paranormal and k-quasi (m, n)*-paranormal operators. Also we study some properties of k-quasi (m, n)-class 𝒬 operator and k-quasi (m, n)-class 𝒬* operators. Moreover, these classes of composition operators on L2 spaces are characterized.

Characteristics of W-TiN Gate Electrode Depending on the Formation of TiN Thin Film (W-TiN 복층 전극 소자에서 TiN 박막 형성 조건에 따른 특성 분석)

  • 윤선필;노관종;양성우;노용한;김기수;장영철;이내응
    • Journal of the Korean Vacuum Society
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    • v.10 no.2
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    • pp.189-193
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    • 2001
  • We have characterized physical and electrical properties of W-TiN stacked gate electrode structure with TiN as a diffusion barrier of fluorine. As the $N_2/Ar$ gas ratio increased during sputter deposition, TiN thin films became N-rich, and the resistivity of the films increased. However, the resistivity of W-TiN stacked gate reduced as a result of the crystallization of tungsten with the increase of $N_2/Ar$ gas ratio. On the other hand, tungsten in W-TiN stacked gate structure have the (100)-oriented crystalline structure although TiN films were subjected to annealing at high temperature (600~$800^{\circ}C$). Leakage currents of W-TiN gate MOS capacitors were less than $10^{-7}\textrm{/Acm}^2$ and also were lowered by the order of 2 compared with those of pure W gate electrode.

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Estimation of N Mineralization Potential and N Mineralization Rate of Organic Amendments as Affected by C:N Ratio and Temperature in Paddy Soil

  • Shin, Jae-Hoon;An, Nan-Hee;Lee, Sang-Min;Ok, Jung-Hun;Lee, Byun-Woo
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.6
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    • pp.712-719
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    • 2016
  • Understanding N mineralization dynamics in soil is essential for efficient nutrient management. An anaerobic incubation experiment was conducted to examine N mineralization potential and N mineralization rate of the organic amendments with different C:N ratio in paddy soil. Inorganic N in the soil sample was measured periodically under three temperature conditions ($20^{\circ}C$, $25^{\circ}C$, $30^{\circ}C$) for 90 days. N mineralization was accelerated as the temperature rises by approximately $10%^{\circ}C^{-1}$ in average. Negative correlation ($R^2=0.707$) was observed between soil inorganic N and C:N ratio, while total organic carbon extract ($R^2=0.947$) and microbial biomass C ($R^2=0.824$) in the soil were positively related to C:N ratio. Single exponential model was applied for quantitative evaluation of N mineralization process. Model parameter for N mineralization rate, k, increased in proportion to temperature. N mineralization potential, $N_p$, was very different depending on C:N ratio of organic input. $N_p$ value decreased as C:N ratio increased, ranged from $74.3mg\;kg^{-1}$ in a low C:N ratio (12.0 in hairy vetch) to $15.1mg\;kg^{-1}$ in a high C:N ratio (78.2 in rice straw). This result indicated that the amount of inorganic N available for crop uptake can be predicted by temperature and C:N ratio of organic amendment. Consequently, it is suggested that the amount of organic fertilizer application in paddy soil would be determined based on temperature observations and C:N ratio, which represent the decomposition characteristics of organic amendments.