• 한국재료학회지
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• 제27권10호
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• pp.544-551
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• 2017

In order to develop a new commercial Al-12%Si casting alloy with improved physical properties, we investigated the effect of adding Sr and TiB to the alloy. Al-12%Si alloys were prepared by die casting at $660^{\circ}C$. The eutectic temperature of the Sr-modified Al-12%Si alloy decreased to $9^{\circ}C$ and the mushy zone region increased. The shape of the Si phase changed from coarse acicula to fine fiber with the addition of Sr. The addition of TiB in the Al-12%Si alloy reduced the size of the primary ${\alpha}$-Al and eutectic Si phases. When Sr and TiB were added together, it worked more effectively in refinement and modification. The density of twins in the Si phase-doped Sr increased and the width of the twins was refined to 5 nm. These results are related to the impurity induced twinning(IIT) growth.

• 태양에너지
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• 제12권3호
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• pp.107-115
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• 1992

혼합물의 응고과정에서 온도구배와 농도구배에 의한 복합자연대류의 영향을 정성적으로 알아보기 위하여 이원용액의 응고과정을 실험적으로 연구하였다. 이원용액으로는 $NH_4Cl-H_2O$용액을 사용하였으며 shadowgraph system을 이용하였다. 사진에서 고상영역과 mushy zone의 구별이 불가능하여, 이 두 영역을 합하여 고상으로 취급하였다. 자연대류의 영향으로 상변화물질은 매우 빨리 성층화가 이루어지며, 벽면으로부터 형성되는 고상은 초기에는 높이의 20%되는 곳이 가장 빨리 응고가 진행되어 고상의 두께는 이 지점으로부터 상하로 선형적으로 감소하는 형태를 유지한다. 그러나 고상이 많이 형성된 부분의 열저항은 증가하게 되므로 시간이 지남에 따라 두께가 균일화되려는 경향을 보였다. 응고질량비를 $(Ste{\cdot}Ra^{1/4})^{2-Ste}{\cdot}Fo^{1/2}$의 선형함수로 표시할 수 있었으며, 이로부터 농도구배에 의한 자연대류의 영향은 온도구배에 의한 자연대류의 영향에 비하여 작음을 알 수 있었다.

• 한국재료학회지
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• 제14권2호
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• pp.101-109
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• 2004

The influences of solidification rates and carbon contents on the formation of the $\delta$-ferrite were studied by directional solidification in modified 12%Cr-l %Mo steels. Directional solidification experimental results showed that solidification microstructure depended on solidification rate and carbon content and chromium equivalent. The length of the mushy zone increased and the dendrite arm spacings decreased as the solidification rate increased. The volume fraction of the 8-ferrite decreased with increasing the solidification rate and carbon content. The volume fraction of the ferrite showed much higher at low solidification rates with planar and cellular interfaces than that at high solidification rates with dendritic interface. It is expected that macro-segregation of C causes lower C content at the lower solidification fraction in the directionally solidified sample, where lower C results in higher volume fraction of the ferrite. In order to estimate solidification microstructure in modified 12Cr-l%Mo steels, various solidification conditions, such as solidification rate, cooling rate, segregation, alloy composition, should be considered.

• 한국광물학회지
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• 제20권2호
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• pp.103-114
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• 2007

제주도 동부 신산리해안과 산굼부리에 분포하는 현무암에는 최대 직경 15 cm의 개브로노라이트 성분의 포획암과 거정의 사장석 결정이 포획되어 있다. 이 포획암은 포이킬리틱과 등립질 조직으로 산출되며, 관찰된 모든 포획암에는 사장석의 함량이 가장 우세하며(42-94 vol%), 감람석은 산출되지 않는다. 포이킬리틱조직의 포획암은 사장석을 주정(主晶, oikocryst)으로 자형의 사방휘석과 단사휘석을 포함하고 있는 큐물레이트의 특성을 잘 나타내고 있으며 등립질조직의 포획암은 반자형에서 타형의 사방휘석, 단사휘석, 사장석으로 구성되어 있다. 조직적 특성, 지화학적 특성, 야외 노두에서의 산출상태에 의해 포이킬리틱조직을 보이는 포획암은 모암인 현무암 마그마와의 관계에 있어서 폐쇄계를 이룬 고화대에서, 등립질조직의 포획암은 포이킬리틱한 것에 비해 열린계의 특성을 보이며 마그마 쳄버의 회반죽대에서, 거정질의 사장석은 결정 부유대에 위치하던 암편 혹은 광물편으로 해석된다. 제주도의 반려암질포획암은 제주도를 형성한 마그마 쳄버계의 일부분으로, 분화과정이 제법 진행된 마그마에서 결정화된 암석으로 임시적으로 마그마쳄버를 채웠던 마그마 배치(batch)와 관련된 결정화작용-고립화-포획과정의 암편임을 나타낸다.

• 한국기계가공학회지
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• 제17권6호
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• pp.144-150
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• 2018

In this study, the freezing process of L-shaped pipe exposed to the outside was investigated numerically by considering the mushy zone of freezing water. From the numerical results, it was found that the flow was outwardly directed due to the influence of the L-shaped bending part in the outside exposed part of the pipe, and the ice was formed in the shape of longitudinal corrugation on the wall surface of the pipe after the bending part. It is confirmed that this phenomenon is caused by the venturi effect due to the freezing as seen in connection with the velocity distribution in the pipe. It is found that the remelting phenomenon at the end of the freezing section occur simultaneously during the process of forming the ice in the pipe section. In regard of the factors affecting freezing, it was found that the thickness of the freezing layer is increased as the exposed pipe surface temperature is decreased, and the pipe surface temperature had a significant effect on the change of the freezing layer thickness. At the same time, it was found that the freezing layer becomes relatively thin when the water inflow rate is increased. This phenomenon was caused by reducing the exposure time of freezing water due to the vigorous flow convection of the water fluid.

• Corrosion Science and Technology
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• 제23권2호
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• pp.104-112
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• 2024

Al-Zn-Mg-Si alloy coatings have been developed to inhibit corrosion of cold rolled steel sheets, and an understanding of the alloy system helps prevent coating defects. We used a Bridgman furnace to characterise the nature and formation mechanisms of the phases present in the quaternary system with 0.4 wt% Fe. In the directional solidification experiments we imposed steep temperature gradients and varied the pull rate. After the samples were quenched in the furnace, detailed characterization of the samples was carried out by electron microscopy (SEM/EDS). From the dT/dt vs T plots of the cooling curves of the alloys, the solidification path was determined to be $Liquid{\longrightarrow[80]^{544-558}}{\alpha}-Al{\longrightarrow[80]^{453-459}}Al/Mg_2Si{\longrightarrow[80]^{371-374}}Al/Zn{\longrightarrow[80]^{331-333}}Zn/mgZn_2$. The formation mechanisms of the Mg and Zn containing phases and their morphology was discussed together with the effects of the cooling rate. Key findings include the lengthening of the mushy zone in directionally solidified samples remelted against a positive temperature gradient, as well as an enrichening of the α-Al phase by Zn through remelting. Mg₂Si and other Si based phases were observed to adopt a much finer faceted microstructure in favour of a script-like microstructure when exposed to the higher cooling rate of coolant quenching.