• Bulletin of the Korean Chemical Society
• /
• v.32 no.5
• /
• pp.1679-1684
• /
• 2011

Interfacial reactions kinetics often differ from kinetics of bulk reactions. Here, we describe how the density change of an immobilized reactant influences the kinetics of interfacial reactions. Self-assembled monolayers (SAMs) of alkanethiolates on gold were used as a model interface and the Diels-Alder reaction between immobilized quinones and soluble cyclopentadiene was used as a model reaction. The kinetic behavior was studied using varying concentrations of quinones. An unusual threshold density of quinones (${\Gamma}_c$ = 5.2-7.2%), at which the pseudo-first order rate constant started to vary as the reaction progressed, was observed. This unexpected kinetic behavior was attributed to the phase-separation phenomena of multi-component SAMs. Additional experiments using more phase-separated two-component SAMs supported this explanation by revealing a significant decrease in ${\Gamma}_c$ values. When the background hydroxyl group was replaced with carboxylic or phosphoric acid groups, ${\Gamma}_c$ was observed at below 1%. Also, more phase-separated thermodynamically controlled SAMs produced a lower critical density (3% < ${\Gamma}_c$ < 4.9%) than that of the less phaseseparated kinetically controlled SAMs (6.5% < ${\Gamma}_c$ < 8.9%).

• Computers and Concrete
• /
• v.15 no.5
• /
• pp.735-758
• /
• 2015

This work deals with unilateral effect of quasi-brittle materials, such as concrete. For this propose, a two-dimensional meso-scale model is presented. The material is considered as a three-phase material consisting of interface zone, matrix and inclusions - each constituent modeled by an appropriate constitutive model. The Representative Volume Element (RVE) consists of inclusions idealized as circular shapes randomly placed into the specimen. The interface zone is modeled by means of cohesive contact finite elements developed here in order to capture the effects of phase debonding and interface crack closure/opening. As an initial approximation, the inclusion is modeled as linear elastic as well as the matrix. Our main goal here is to show a computational homogenization-based approach as an alternative to complex macroscopic constitutive models for the mechanical behavior of the quasi-brittle materials using a finite element procedure within a purely kinematical multi-scale framework. A set of numerical examples, involving the microcracking processes, is provided. It illustrates the performance of the proposed model. In summary, the proposed homogenization-based model is found to be a suitable tool for the identification of macroscopic mechanical behavior of quasi-brittle materials dealing with unilateral effect.

• Korean Journal of Remote Sensing
• /
• v.19 no.5
• /
• pp.381-392
• /
• 2003

Multi-temporal approaches using sequential data acquired over multiple years are essential for satisfactory discrimination between many land-cover classes whose signatures exhibit seasonal trends. At any particular time, the response of several classes may be indistinguishable. A harmonic model that can represent seasonal variability is characterized by four components: mean level, frequency, phase and amplitude. The trigonometric components of the harmonic function inherently contain temporal information about changes in land-cover characteristics. Using the estimates which are obtained from sequential images through spectral analysis, seasonal periodicity can be incorporates into multi-temporal classification. The Normalized Difference Vegetation Index (NDVI) was computed for one week composites of the Advanced Very High Resolution Radiometer (AVHRR) imagery over the Korean peninsula for 1996 ～ 2000 using a dynamic technique. Land-cover types were then classified both with the estimated harmonic components using an unsupervised classification approach based on a hierarchical clustering algorithm. The results of the classification using the harmonic components show that the new approach is potentially very effective for identifying land-cover types by the analysis of its multi-temporal behavior.

• 한국전산유체공학회:학술대회논문집
• /
• 2009.11a
• /
• pp.211-217
• /
• 2009

The numerical program has been developed for the purpose of the complicate geometries application using CIP method. The non-staggered, non-orthogonal, and unstructured grid system can be also used for the various geometries in the program. For validating CIP solver, the lid-driven cavity flow and solitary wave propagation flow are carried out. Test results show a good agreement with the verified results. The dynamic solver was used for the behavior of moving body. Interface process between the two solvers is introduced. The research was performed on the flow problem around torpedo and log and the flow problem in a tank in order to analyze the three phase flow problem Although the comparison to the verified results was not quantitatively performed, the trend of the results was reasonable.

• Structural Engineering and Mechanics
• /
• v.65 no.4
• /
• pp.465-476
• /
• 2018

This article investigates buckling behavior of a multi-phase nanocrystalline nanobeam resting on Winkler-Pasternak foundation in the framework of nonlocal couple stress elasticity and a higher order refined beam model. In this model, the essential measures to describe the real material structure of nanocrystalline nanobeams and the size effects were incorporated. This non-classical nanobeam model contains couple stress effect to capture grains micro-rotations. Moreover, the nonlocal elasticity theory is employed to study the nonlocal and long-range interactions between the particles. The present model can degenerate into the classical model if the nonlocal parameter, and couple stress effects are omitted. Hamilton's principle is employed to derive the governing equations and the related boundary conditions which are solved applying an analytical approach. The buckling loads are compared with those of nonlocal couple stress-based beams. It is showed that buckling loads of a nanocrystalline nanobeam depend on the grain size, grain rotations, porosities, interface, elastic foundation, shear deformation, surface effect, nonlocality and boundary conditions.

• 한국초전도학회:학술대회논문집
• /
• v.9
• /
• pp.196-199
• /
• 1999

The coexistence of the superconductivity and magnetism in the Ho1-xDyxNi2B2C is studied by using Ginzburg-Landau theory. This material violates the standard do Gennes scaling showing the coexistence and complex interplay of superconducting and magnetic order yielding an anomalous phase diagram. We propose a phenomenological model which includes two magnetic and two superconducting order parameters accounting for the multi-band structure of this material. We describe the magnetic fluctuations and order and demonstrate that they lead to anomalous behavior of the upper critical field. The doping dependence of Tc in Ho1-xDyxNi2B2C showing a reentrance behavior are analyzed yielding a very good agreement with experimental data.

• Journal of IKEEE
• /
• v.8 no.1 s.14
• /
• pp.128-135
• /
• 2004

This paper proposes a phase measurement algorithm which is based on the recursive implementation of sliding-DFT. The algorithm is designed to have a robust behavior against the erroneous factors of frequency drift, additive noise, and twiddle factor approximation. The size of phase error caused by the finite wordlength implementation of DFT twiddle factors is shown significantly lower than that of magnitude error. The drastic reduction of the phase error is achieved by the exploitation of the quadruplet symmetry characteristics of the approximated twiddle factors in the complex plane. Four channel power-line phase measurement system is also designed and implemented based on the time-multiplexed sharing architecture of the proposed algorithm. The operation of the developed system is also verified by the experiment performed under the test environment implemented with the multi-channel function generator and the on-line interfaced host processor system. The proposed algorithm's features of phase measurement accuracy and its robustness against the finite wordlength effects can provide a significant impact especially for the ASIC or microprocessor based embedded system applications where the enhanced processing speed and implementation simplicity are crucial design considerations.

• Proceedings of the Korean Society for Technology of Plasticity Conference
• /
• 2009.05a
• /
• pp.318-321
• /
• 2009

Transformation plasticity is that when a phase transformation of ferrous or non-ferrous alloys progresses even under an extremely small applied stress compared with a yield stress of the material, a permanent deformation occurs. One of widely accepted description for the transformation was proposed by Greenwood and Johnson [1]. Their description is based on an assumption that a weaker phase of an ideal plastic material could deform plastically to accommodate the externally applied stress and the internal stress caused by the volumetric change accompanying the phase transformation. In this study, an implicit finite element model was developed to simulate the deformation behavior of a low carbon steel during phase transformation. The finite element model was coupled with a phase field model, which could simulate the kinetics for ferrite to austenite transformation of the steel. The thermo-elasto-plastic constitutive equation for each phase was adopted to confirm the weaker phase yielding, which was proposed by Greenwood and Johnson [1]. From the simulation, the origin of the transformation plasticity was quantitatively discussed comparing with the other descriptions of it.

• Journal of the Computational Structural Engineering Institute of Korea
• /
• v.24 no.1
• /
• pp.9-16
• /
• 2011

An approach to understand the phase distribution in a multi-phase polycrystalline material is important since it can affect material properties and mechanical behaviors. A proper method is needed to describe the phase distribution. For this purpose, contiguity and probability functions(two-point correlation and lineal-path functions) are investigated for representing the phase distributions of microstructures. The mechanical behaviors are evaluated using the finite element method. The characteristics of probability functions and mechanical reponses of virtual samples are represented. It is confirmed that the topology of phase clustering affects the mechanical behavior of materials and that the strength is reduced as the clustering size increases.

• Advances in nano research
• /
• v.9 no.4
• /
• pp.295-307
• /
• 2020

The vibrational characteristics of Multi-Phase Nanocomposite (MPC) reinforced annular/circular plate under initially stresses are presented using the state-space formulation based on three-dimensional elasticity theory (3D-elasticity theory) and Differential Quadrature Method (DQM). The MPC reinforced annular/circular plate is under initial lateral stress and composed of multilayers with Carbon Nanotubes (CNTs) uniformly dispersed in each layer, but its properties change layer-by-layer along the thickness direction. The State-Space based Differential Quadrature Method (SS-DQM) is presented to examine the frequency behavior of the current structure. Halpin-Tsai equations and fiber micromechanics are used in the hierarchy to predict the bulk material properties of the multi-scale composite. A singular point is investigated for modeling the circular plate. The CNTs are supposed to be randomly oriented and uniformly distributed through the matrix of epoxy resin. Afterward, a parametric study is done to present the effects of various types of sandwich circular/annular plates on frequency characteristics of the MPC reinforced annular/circular plate using 3D-elasticity theory.