• Journal of Environmental Science International
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• v.15 no.1
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• pp.85-94
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• 2006

The simultaneous analysis of multi-residual pesticides was developed using a gas chromatography (GC) method. In this study, a simple and reliable methodology was improved to detect 154 kinds of pesticides in sinseng extract sample by using a liquid-liquid extraction procedure, open column chromagraphy and chromatographic analysis by CC electron capture detector (ECD) and GC nitrogen-phosphorus detector (NPD). The 154 kinds of pesticides were classified in 4 groups according to the chemical structure. The extraction of pesticides was experimented with $70\%$ acetone and dichloromethane/petroleum ether in order, and cleaned up via open column chromatography $(3\times30cm)$ packed with florisil $(30g,\;130^{\circ}C,\;12hrs)$. The final extract was concentrated in a rotator evaporator at $40^{\circ}C$ until dryness. Then the residue was redissolved to 2ml with acetone, and analyzed by GC-ECD and GC-NPD. The applied concentration of pesticides was over $1\~10{\mu}g/ml$. The recovery tests were ranged from $70.7\%$ to $115.2\%$ with standard deviations between 0.3 and $5.7\%$ of the standard spiked to the ginseng extract sample (Group $I\~IV$). The limit of detection (LOD) ranged from 0.001 to $0.099{\mu}g/ml$ (Group $I\~IV$). The 9 kinds of pesticides were not detected. The developed method was applied satisfactory to the determination of the 154 kinds of pesticides in the ginseng extract with good reproducibility and accuracy.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.08a
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• pp.389-390
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• 2012

In this study, we fabricate a superhydrophobic surface made of hierarchical nanostructures that combine wax crystalline structure with moth-eye structure using vacuum cluster system and measure their hydrophobicity and durability. Since the lotus effect was found, much work has been done on studying self-cleaning surface for decades. The surface of lotus leaf consists of multi-level layers of micro scale papillose epidermal cells and epicuticular wax crystalloids [1]. This hierarchical structure has superhydrophobic property because the sufficiently rough surface allows air pockets to form easily below the liquid, the so-called Cassie state, so that the relatively small area of water/solid interface makes the energetic cost associated with corresponding water/air interfaces smaller than the energy gained [2]. Various nanostructures have been reported for fabricating the self-cleaning surface but in general, they have the problem of low durability. More than two nanostructures on a surface can be integrated together to increase hydrophobicity and durability of the surface as in the lotus leaf [3,5]. As one of the bio-inspired nanostructures, we introduce a hierarchical nanostructure fabricated with a high vacuum cluster system. A hierarchical nanostructure is a combination of moth-eye structure with an average pitch of 300 nm and height of 700 nm, and the wax crystalline structure with an average width and height of 200 nm. The moth-eye structure is fabricated with deep reactive ion etching (DRIE) process. $SiO_2$ layer is initially deposited on a glass substrate using PECVD in the cluster system. Then, Au seed layer is deposited for a few second using DC sputtering process to provide stochastic mask for etching the underlying $SiO_2$ layer with ICP-RIE so that moth-eye structure can be fabricated. Additionally, n-hexatriacontane paraffin wax ($C_{36}H_{74}$) is deposited on the moth-eye structure in a thermal evaporator and self-recrystallized at $40^{\circ}C$ for 4h [4]. All of steps are conducted utilizing vacuum cluster system to minimize the contamination. The water contact angles are measured by tensiometer. The morphology of the surface is characterized using SEM and AFM and the reflectance is measured by spectrophotometer.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.6
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• pp.609-614
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• 2014

In this research, results of measuring temperature and relative humidity of underground-air-heat in Jeju showed $15{\sim}18^{\circ}C$ and 70~80% each which are somewhat high compare to other regions. So the Multi-effect dehumidifying and heating Heat Pump system which has merged functions of dehumidification and heating is made to solve this problem mentioned previously. When the suction air was $15^{\circ}C$ with 60% humidity, the outcome was 1.70 on $COP_h$ and 1.797(kg/h) on total amount of dehumidification, and also showed 1.87 $COP_h$ with 1.87 total amount of dehumidification under the condition of $20^{\circ}C$ and 80% humidity of suction air. Furthermore, $COP_h$ showed increased number which is 1.87 and also total amount of dehumidification increased which was 3.269(kg/h). The highest COP can be achieved at $17^{\circ}C$ and 70% relative humidity condition.

• Transactions of the Korean Society of Mechanical Engineers
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• v.13 no.2
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• pp.287-298
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• 1989

A numerical work was performed to study the flow behaviors of the open channel type flow with its geometric boundary conditions being similar to that of the Multi-Stage-Flash evaporator with and without a baffle. For the analysis, two-dimensional steady turbulent flow was assumed and the widely known k-.epsilon. turbulence model was usded. SIMPLE algorithm and the power difference scheme were used for the numerical approach. Numerical results generally agree with the previous experimental results though there are some uncertainties at far downstream and near the free surface due to the three dimensionality of the flow and surface waves. Without a baffle, the flow has basically the shape of the submerged plane wall jet with its upper boundary at downstream being sharply curved toward the free surface. For the flow with a baffle, recirculation flow patterns are observed at the upper inlet portion and at the backside of the baffle. For the case without a baffle, it was also confirmed that the ratio between the liquid level and the gate opening height is the most important parameter to determine the flow behavior.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.314-314
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• 2012

The dilute magnetic semiconductors (DMS) have been developed to multi-functional electro-magnetic devices. Specially, the Si based DMS formed by ion implantation have strong advantages to improve magnetic properties because of the controllable effects of carrier concentration on ferromagnetism. In this study, we investigated the deep level states of Fe- and Co-ions implanted Si wafer during rapid thermal annealing (RTA) process. The p-type Si (100) wafers with hole concentration of $1{\times}10^{16}cm^{-3}$ were uniformly implanted by Fe and Co ions at a dose of $1{\times}10^{16}cm^{-2}$ with an energy of 60 keV. After RTA process at temperature ranges of $500{\sim}900^{\circ}C$ for 5 min in nitrogen ambient, the Au electrodes with thickness of 100 nm were deposited to fabricate a Schottky contact by thermal evaporator. The surface morphology, the crystal structure, and the defect state for Fe- and Co- ion implanted p-type Si wafers were investigated by an atomic force microscopy, a x-ray diffraction, and a deep level transient spectroscopy, respectively. Finally, we will discuss the physical relationship between the electrical properties and the variation of defect states for Fe- and Co-ions implanted Si wafer after RTA.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.6
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• pp.1399-1406
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• 1988

Flow behaviors of the open channel type flow with its geometric boundary conditions being similar to that of the Multi-Stage-Flash evaporator were studied qualitatively by measuring the velocity distribution. Without a baffle, the flow was in the shape of a simple submerged plane wall jet. At the downstream of this flow, the jet boundary made sharp curve toward the free surface ; this is because the entrainment of the ambient liquid is restricted by the free surface boundary, similar to the Coanda effect. According to the experimental results the level of the free surface appeared to be the most important parameter. The flow with a baffle was in much complicated shape ; especially the recirculating region at the downstream free surface was detected according to the experimental conditions imposed. Inlet liquid velocity, heights of the liquid level and the baffle, and the opening heights of sluice gate of the entrance were the most important parameters in the baffle flow.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.381-382
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• 2007

IZO/Ag/IZO (IAI) anode films for flexible organic light emitting diodes (OLEDs) were grown on PC (polycarbonate) substrate using DC sputter (IZO) and thermal evaporator (Ag) systems as a function of Ag thickness. To investigate electrical and optical properties of IAI stacked films, 4-point probe and UV/Vis spectrometer were used, respectively. From a IAI stacked film with 12nm-thick Ag, sheet resistance of $6.9\;{\Omega}/{\square}$ and transmittance of above 82 % at a range of 500-550 nm wavelength were obtained. In addition, structural and surface properties of IAI stacked films were analyzed by XRD (X-ray diffraction) and SEM (scanning electron microscopy), respectively. Moreover, IAI stacked films showed dramatically improved mechanical properties when subjected to bending both as a function of number of cycles to a fixed radius. Finally, OLEDs fabricated on both flexible IAI stacked anode and conventional ITO/Glass were fabricated and, J-V-L characteristics of those OLEDs were compared by Keithley 2400.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.20 no.6
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• pp.65-70
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• 2020

In this paper, to establish a high-efficiency air-conditioning and heating system, we developed a simultaneous air-conditioning and heating system that can do both air-conditioning and heating at the same time. It was applied to hybrid plant plants to enable automation of complex farms. For this purpose, the heat exchanger, which functions as a condenser during heating, was required to function as an evaporator during cooling so that air conditioning and heating could be implemented simultaneously. For experiments, the simultaneous air conditioning system for heating and cooling was produced and applied to the plant factories in the farms so that plants could be grown, stored, and dried. As a result, a single system was able to control the temperature environment of agricultural products with an energy-saving system that simultaneously resolves heating and cooling. Therefore, efficient crop management was possible by implementing an air conditioning system that did not require installing air conditioners and boilers at the same time.

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.3
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• pp.197-201
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• 2017

Most fishing vessels use an ice cooling system to manage and store captured fish. However, it is difficult to maintain an adequate temperature and salt concentration as well as operating time limitations in ice cooling systems. The purpose of this study is to investigate the heat transfer characteristics of flooded-type evaporators for a seawater cooling system to maintain proper seawater temperature in a fish tank. Experiments were conducted to investigate the heat transfer characteristics by changing the seawater temperature, flow rate, and saturation temperature of the refrigerant. It was confirmed that the heat transfer coefficient of an aluminum-brass tube was approximately 10% higher than that of a copper-nickel tube at the same heat flux. Furthermore, it was confirmed that applying the aluminum-brass tube to the heat transfer tube of a seawater heat exchanger was effective in terms of heat transfer. A comparison of the overall heat transfer coefficient of a single-tube heat exchanger and the flooded-type multi-tube heat exchanger for an 18-kW cooling system showed that the heat transfer coefficient of the single-tube heat exchanger was 25% higher under the same conditions. These results are considered to be important data for designing a flooded-type multi-tube heat exchanger.

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.3
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• pp.182-190
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• 2017

All liquids contain a small amount of gaseous components and the amount of gases dissolved in a liquid is in accordance with Henry's Law. In a multi-stage thermal-type seawater desalination plant, as the supplied seawater undergoes variations in temperature and pressure in each evaporator, the gases dissolved in the seawater are discharged from the liquid. The discharged gases are carbon dioxide, nitrogen, oxygen, and argon, and these emitted gases are non-condensable. From the viewpoint of convective heat transfer, the evaluation of non-condensable gas released during a vacuum evaporation process is a very important design factor because the non-condensable gases degrade the performance of the cooler. Furthermore, in a thermal-type seawater desalination plant, most evaporators operate under vacuum, which maintained through vacuum system such as a steam ejector or a vacuum pump. Therefore, for the proper design of a vacuum system, estimating the non-condensable gases released from seawater is highly crucial. In the study, non-condensable gases released in a thermal-type seawater desalination plant were calculated quantitatively. The calculation results showed that the NCG releasing rate decreased as the stage comes getting a downstream and it was proportional to the freshwater production rate.