• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.247-253
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• 2007

The effect of heat treatment and acid leaching of siliceous mudstone on the purity of silica precursors, such as sodium silicate and silicic acid, was studied. As well as the temperatures for the heat treatment of siliceous mudstone, the concentrations of hydrochloric acid and sulfuric acid were varied to achieve the highest content of silicon in the precursors while minimizing energy and chemical consumption. It was found that the optimum conditions were achieved at the heat treatment temperature of $600^{\circ}C$ and hydrochloric acid of 1.56 M. The relative concentrations of silicon in the synthesized sodium silicate and silicic acid were as high as 99.2 and 99.5%, respectively.

• Journal of the Korean earth science society
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• v.39 no.6
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• pp.545-554
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• 2018

The Cretaceous Eumsung (Eumseong) Basin is a pull-apart basin, formed along a series of the Gongju strike-slip faults trending NE-SW. The Nongdari-Meer forest of the Gugokri area in the southwestern part of the basin is comprised of thick purple mudstone, intercalating conglomerate, pebbly sandstone, and green mudstone beds. The succession mainly consists of seven sedimentary facies: stratified conglomerate (C2), conglomerate encased in siltstone (CE), stratified pebbly sandstone encased in siltstone (PSE2), purple sandy siltstone (Zp), green sandy siltstone (Zg), purple mudstone (Mp), and green mudstone (Mg). Sedimentary environment is mainly indicative of alluvial-plain setting in an alluvial-to-lacustrine sedimentary system, developed in the southwestern part of the basin. Geological survey was fulfilled in succession of the Gugokri sedimentary system using 1:5000 topographic map, which resulted in a geological route map. This study newly suggested that there be fluvial systems showing ENE and NNE trends in the study area, based on data of palaeocurrent direction and sedimentary characteristics in new outcrops of the forest. The study also revised the precedent sedimentation model of the Gugokri system.

• Journal of the Korean Geotechnical Society
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• v.16 no.2
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• pp.61-70
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• 2000

When clay foundations of embankments are treated with vertical drain, essentially, the strain occurs to vertical direction but the water flow is radial. The initial horizontal permeability and its variation with the vertical compression are key parameters for the choice of the type of drains, their spacing, and affect to the cost of the project. In this study, CRS consolidation test is performed to investigate the anisotropic characteristics of decomposed mudstone soil and direct permeability test is performed on the same specimens. The results of testing show that Ch is larger than Cv. specially, the Cv - $\sigma$v relationship for a soil sample is viewed from three different curve segments corresponding to overconsolidated, transition and normally consolidated states. The anisotropic ratio, rk(kh/kv) is 2.19. Coefficient of permeability in normally consolidated state is related to its void ratio and permeability parameter n. C can be determined from a linear plot of log[k(1+e)] versus log e. The slope, n, of graphs is the same, whereas the vertical intercept, log C, seems to vary somewhat for anisotropic.

• Geomechanics and Engineering
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• v.31 no.1
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• pp.87-97
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• 2022

The excessive settlement and deformation of disintegrated carbonaceous mudstone (DCM) embankments under dynamic loading have long been problems for engineers and technicians. In this work, the characteristics and mechanism of the plastic deformation of DCM under different degrees of compaction, water contents and confining pressures were studied by static triaxial, dynamic triaxial and scanning electron microscopy testing. The research results show that the axial stress increases with increasing confining pressure and degree of compaction and decreases with increasing water content when DCM failure. The axial strain at failure of the DCM decreases with increasing confining pressure and degree of compaction and increases with increasing water content. Under cyclic dynamic stress, the change in the axial stress level of the DCM can be divided into four stages: the stable stage, transition stage, safety reserve stage and unstable stage, respectively. The effects of compaction, water content and confining pressure on the critical axial stress level which means shakedown of the DCM are similar. However, an increase in confining pressure reduces the effects of compaction and water content on the critical axial stress level. The main deformation of DCM is fatigue cracking. Based on the allowable critical axial stress, a method for embankment deformation control was proposed. This method can determine the degree of compaction and fill range of the embankment fill material according to the equilibrium moisture content of the DCM embankment.

• Journal of Korean Society of Forest Science
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• v.19 no.1
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• pp.1-23
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• 1973

The results of ground vegetation experiment conducted at completely denuded forestland in the mudstone region are summerized as follows: On the reaults of soiling quantity the effect of soiling was observed where depth of soiling over 10 cm was practiced, and a plot where treated with 15cm soiling and without fertilizer showed poor growth and it was even worser than the plot where soiling was practiced only 1 cm in thikness but applied adequate amount of fertilizers. The depth of slits between 30cm and 40cm showed no significant difference in the effect. A plot where covered with vegetation bag showed somewhat better results in seed loss and early growth but no differences observed in the fall result over the none covered plot. And then, it is recommendable to have soiling over 10cm in thikness with slit of 30cm and 30cm in depth and to apply 30 gram of fertilizer (22;22:11, 50 gram) per slit. On various soiling materials trial there were no striking differences in the effect of soiling between weathered granite soil, wheathered tuffs soil and weathered mudstone soil. In the treatment with various green materials, a plot treated with straw mat showed a significant difference at 1 percent. The results show that weathered mudstone soil is effective to use as soiling materials and straw mat treatment was better. On forest fertilization trial, in the mudstone region where red and black pine trees already existing at a rate of 2,000-3,000 trees per hectare had applied 110kg of compound fertilizers (9:12:3 and 22:22:11) per hectare basis in terms of plant nutrient. As a result, the difference in effect between the compound fertilizers was not found however the leaf color and leaf length of the fertilizer added plot showed darker and longer at 30 percent over the no fertilizer received plot. Compound fertilizers, 14:37:12 and 9:12:3 were applied to alder trees at a rate of 20 gram and 40 gram per tree in terms of plant nutrient and a remarkable growth accelerantion was observed where 40 grams of plant nutrient applied. The effect difference between the compound fertilizers was not found. On investigation of tree root elongation, forty years old red pine trees showed only 15cm tap root elongation through mudstone while black pine had 23 cm tap root elongation. The total length of supporting root elongtion of red and black pines showed 20 and 13 meters, respectively. The tap roots of Black locusts were not able to elongate through mudstone, however, the supporting roots tended to develop to the underneath of pine tree where some moisture content is available. Black locusts And grown on the residual soil of mudstone normally die between 8 to 10 years. The red pine trees show flat in tree shape while black pine had triangle in the shape. With the results it can be said that in an artificial reforestation in denuded forest land of the mudstone region the adequate slit and enough amount of fertiliizer application must be provided for the succesful performance of the program. On integrated experimental results of 1972. for the establishment of ground vegetation on the completely denuded forest land in mudstone region, soiling could be effectively practiced with weathered mudstone soil and it would not specially necessiate to have either weathered granite or tuffssoil for the soiling. And the soiling depth should be more than 10 cm in thickness. Among green materials used the straw mat proved to be the most effective reatment. Three major factors which enable to establish ground vegetation by the shortest period of time: A. Physical improvement of soil is necessary to breakdown of the horizontal cracks sushas Slit, contour line plot, seeding hole and etc., and soiling with weathered mudstone soil. B. Chemical improvement of soil: is needed sufficient amount of fertilizer application 300~400kg ha, $N+P_2O_5+K_2O$), and increased production of ground covering and expedite resolution of the vegetation (ground vegetation, fallen leaves and twigs). C. Complete establishment of the basic structure for the erosion control (Prevention of surface soil erosion)

• Journal of the Korean GEO-environmental Society
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• v.1 no.1
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• pp.5-12
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• 2000

Mudstone, found Du-Ho Dong and around there in Po-Hang, is used as construction material. When it is exposed to the air and contacts with water, the strength is decreased rapidly and then it causes a lot of problems. In the field, clay soils with $K_o$ condition have anisotropic characteristics which behave differently according to the change of principal stress direction. In this study, $K_o$ consolidation is performed to make the completely weathered mudstone under the same conditions of construction place. Then, the triaxial compression test is performed at different shear velocity and anisotropy by sampling degree and the stress - strain behavior is shown the strain softening behavior. The stress - strain relationship from triaxial compression test is compared with the prediction value of Cam-clay model. From the results of tests, $K_o$ value decreases with the increase of sampling degree. Generally the behavior of $K_o$ consolidated specimen shows work-softening characteristic. The trend of behaviour of the measured is nearly to same to the predicted by Cam-clay model. But the measured value of deviator stress is very higher than the predicted. Therefore, Cam-clay model was not appropriate to the completely weathered mudstone consolidated with $K_o$ condition in Pohang region.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.4
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• pp.123-131
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• 2018

This study analyzed the collapse course of a mud stone cut slope during the construction of a express and suggested a countermeasure. Experiments were carried out on bedrock mudstone to investigate the engineering characteristics and the slope stability analysis at the time the design was reviewed. In addition, stability analysis, considering the strength softening characteristics of the slope due to the Swelling-Slaking phenomenon, was also performed. As a result of the Swelling-Slaking test, the slake durability was Low-Medium, and the swell potential was Very Low. A review of the stability analysis performed at the time of the design showed different results from the actual results because LEM analysis had been performed without considering the engineering characteristics of mudstone. As a result of additional stability analysis considering the strength softening characteristics, the slope collapse point and the maximum shear strain point of the stability analysis were the same and the standard safety factor was not satisfied. As a countermeasure, a slope mitigation method was found to be most appropriate. The mitigation slope was calculated by Finite element Analysis. A comparison with BIPS to determine the applicability of a mitigation slope revealed most of the unconsolidated mudstone.

• Journal of the Korean Geosynthetics Society
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• v.20 no.3
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• pp.1-10
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• 2021

The purpose of this study is to present the possibility a utilization of the tertiary mudstone in Pohang as road subsoil material through pilot experiments on the road embankment structure. This mudstone is an unconsolidated rock that is distributed in the soft rock sedimentary layer, the tertiary layer of the Cenozoic, and causes physical problems such as slaking, swelling, and reduced shear strength and chemical problem like acid drainage. In order to solve various complex problems, an laboratory mixing test was conducted, and the optimal mixing conditions of the tertiary mudstone (90%), composite slag (steel making 70%, blast furnace 30%), and neutralization and coating agent treatment were derived. In order to prove its utilization, a real-scale road embankment structure was constructed and tests were conducted for each section. The pre-processing section is stable due to the design of optimal mixing conditions, while in post-processing section, natural weathering proceeded rapidly, and structural problems were concerned. Since the effect of neutralizing and coating agents was confirmed in temporary-staking section, the neutralizing and coating agents can be applied during the temporary storage period.

• Journal of the Korean Geotechnical Society
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• v.35 no.10
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• pp.33-45
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• 2019

In this study, in order to recycle a large amount of rocks and weathered mudstones produced by civil engineering projects such as railways and highways, as materials for roadbeds or embankment materials, circumferential specimens with a diameter of 5 cm and a height of 10 cm were made. A mudstone that weathered rapidly during rainfall was collected from Pohang construction sites. The weathered mudstone passed through a 2 mm sieve. It was prepared with the cement ratio, the sand ratio, curing condition and curing days. Three specimens were prepared according to each condition and then the unconfined compressive test, durability test and SEM analysis were performed to evaluate the engineering properties of the cemented soil. In the case of 28 days cured specimen, the strength of under-water cured specimens was 32-55% and the durability index was about 15% higher than air cured specimens. In addition, when the CR increased from 8% to 16%, the unconfined compressive strength (UCS) of pure mudstone cemented soil under water increased by about 1.6 times and the durability index increased by about 1.9 times. When the SR increased from 0% to 50%, the UCS of the specimen with SR = 10% was slightly less than or equal to specimen with SR = 0%. Then, as the SR became 30-50%, the UCS increased up to 51%. Unlike the UCS, the durability index increased continuously as the SR increased. As a result of SEM analysis, when SR was 50% rather than SR = 0%, the contact between sand particles increased and they were connected to each other. Such contact between these particles resulted in the increase of strength.

• Journal of the Korean Geotechnical Society
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• v.37 no.11
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• pp.83-92
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• 2021

In this study, effective porosity measurement, electron microscope (SEM) observation, X-ray diffraction analysis (XRD), slaking, swelling, and unconfined compression strength according to water immersion were analyzed to evaluate the properties of mudstone with high porosity in Pohang. As a result of the test for 16 square samples (5 cm), the effective porosity was 14.67% on average, higher than porosity of general mudstone, and electron microscope observation confirmed that the porosity was actually high. As a result of X-ray diffraction analysis, the swelling clay mineral content was 2.3~4.1%, which was lower than the results of previous studies in Pohang. The slake durability index was 37.73~87.73%, showing low to medium durability, which was lower than the results of previous studies. It was confirmed that the swelling property rapidly expanded to 1.79~1.82% of maximum swelling strain in the major axis direction for 30 minutes. As the properties of decreasing the unconfined compression strength according to water immersion, the samples rapidly weathered after 10 minutes of water immersion, and the strength decreased. It was confirmed that the results of previous studies related to mudstone in Pohang were different. This is judged to be due to the high porosity of mudstone in study.