• Journal of the Korean Magnetics Society
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• v.7 no.5
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• pp.232-236
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• 1997

We have gone into details about the velocity calibration of sinusoidal mode for Mossbauer spectrometer. Since sinusoidal Mossbauer spectrometer has a ${\gamma}$-ray source that oscillates at the end of loudspeaker with the natural frequency. Doppler velocity is accurate and stable. From the analyzing Mossbauer spectra of $Fe_3O_4$ and U $Fe_3O_4$ (unbalanced $Fe_3O_4$), we have shown the power of correct velocity for sinusoidal mode.

• Proceedings of the Korean Magnestics Society Conference
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• 2001.10a
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• pp.64-65
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• 2001

• Proceedings of the Korean Magnestics Society Conference
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• 2002.12a
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• pp.18-19
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• 2002

$^{57}$ Fe화합물에 대한 Mossbauer 분광학 연구로부터 이들 자성물질의 이성핵적이동값, 전기사중극자 분열값 및 초미세자기장의 크기를 결정하였으며 이들값으로부터 Fe의 이온상태, 큐리온도, 각 Site의 점유율, Debye온도, spin wave상수, exchange integral을 계산하였다. $^{57}$ Co감마선을 사용하는 등가속도형 Mossbauer 분광기를 이용하여 4.2 K 부터 900 K 온도영역에서 실험을 하였다. (중략)

• Proceedings of the Korean Magnestics Society Conference
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• 2001.10a
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• pp.98-98
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• 2001

• Journal of the Korean Magnetics Society
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• v.8 no.4
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• pp.203-209
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• 1998

Crystallographic and magnetic properties of single phase garnet $Y_{3-x}Bi_xFe_5O_{12}$ (x=0.0, 0.25, 0.5, 0.75, 1.0) were studied by using x-ray diffraction, Mossbauer spectroscopy and vibrating sample magnetometer (VSM). Ultra-fine polycrystalline cubic samples have been prepared by sol-gel method. The lattice constant increase linearly with increasing an amount of Bi. Annealing temperature was larger than 800 $^{\circ}C$ for the growth of a single-phase garnet powder. The second phase of garnet, $(BiFeO_3)$, was at 1000 $^{\circ}C$ for x=0.75, and 950 $^{\circ}C$ for x=1.00. From Mossbauer spectroscopy and VSM measurements, the magnetization and the coercivity were decreased and the Curie temperature $Y_{3-x}Bi_xFe_5O_{12}$(x=0.0, 0.25, 0.5, 0.75, 1.0) was slightly increased as increasing the Bi content.

• Korean Journal of Materials Research
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• v.6 no.11
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• pp.1107-1112
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• 1996

Ni를 Cd로 대치시켜 세라믹 소결법으로 합성한 Ni0.8Cd0.2Fe2O4 의 X-ray 회절선을 측정하여 구조를 확인하고, 형성된 결정체의 격자 상수를 조사하였다. 이 시료의 Mossbauer 스펙트럼을 80K-900K의 온도 영역에서 측정 분석하여 Mossbauer parameter의 온도 의존성과 Fe 이온에 대한 자료를 얻고, 이 자료를 토대로 Ni0.8Cd0.2Fe2O4 의 자기 전이 현상과 Curied 온도 Tc와 격자 비열 및 Debye 온도와 같은 물성을 조사하였다.

• Journal of the Korean Magnetics Society
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• v.8 no.6
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• pp.335-340
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• 1998

Colossal magnetoresistance $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ material has been produced by a metal-salt routed sol-gel process method. Magnetic properties of $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ have been studied with x-ray diffraction, Rutherford back-scattering spectroscopy(RBS), vibrating sample magnetometer, and Mossbauer spectroscopy. Crystalline $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ was perovskite cubic structure with a lattice parameter $a_0=3.868$\AA$$. And there was no appreciable change in the value of the lattice parameter when a small amount (x=0.01) of iron was added. However, Mossbauer and VSM data indicate the Curie temperature of the $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ decreased from 282 to 270 k and also the saturation magnetization from 84 to 81 emu/g at 77 K. Mossbauer spectra of $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ have been taken at various temperatures ranging form 4.2 K to room temperature. Analysis of $^{57}Fe$ Mossbauer data in terms of the local configurations of Mn atoms has permitted the influence of the magnetic hyperfine interactions to be monitored. The isomer shifts show that the charge state of all Fe ions are ferric. The magnetoresistance of $La_{0.67}Ca_{0.33}Mn_{0.99}^{57}Fe_{0.01}O_3$ was about 33 % at semiconductor-metal transition temperature $T_{SC-M}=250K$.

• Proceedings of the Korean Magnestics Society Conference
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• 2002.04a
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• pp.90-91
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• 2002

• Journal of the Korean Magnetics Society
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• v.9 no.1
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• pp.29-34
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• 1999

$Y_{2.5}La_{0.5}Fe_5O_{12}$ is fabricated by a sol-gel method and the magnetic properties of single phase garnet are investigated by using X-ray diffraction, vibrating sample magnetometer, scanning electron microscopy and M$\"{o}$ssbauer spectroscopy. The single phase powders garnet was fired at 100$0^{\circ}C$ for 8 hours. The crystal structures of samples are cubic garnet. Mossbauer spectroscopy were measured from 13 K to 750 K. M$\"{o}$ssbauer spectra show that the iron exist ferric trivalence in sample. The spin wave constants were determined $B_{3/2}=0.32{\pm}0.05,\; C_{5/2}=0.18{\pm}0.05$ and Debye temperature were determined 382 K at 24(d) site and 246 K at 16(a)-site. The saturation magnetization $M_s$ of powder is 25 emu/g. 25 emu/g.

• Journal of the Korean Magnetics Society
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• v.16 no.1
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• pp.51-59
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• 2006

$M\"{o}ssbauer$ spectroscopy is one of the very powerful analytical methods for studying the steel properties. It is the most important advantage that the steel properties can be quantitatively analyzed by Mossbauer analysis. The quantitative analysis could provide various information about corrosion products, environmental condition, kind of steel, foreign element, particle size, etc. It can be also applied for the study of strength and phase of steel, as functions of the kind of steel and foreign elements.