• 제목/요약/키워드: Mordanting

검색결과 289건 처리시간 0.024초

새로운 천연염재로서 메타쉐콰이어 열매의 활용(1): 면섬유 염색을 중심으로 (Utilization of Metasequoia(Metasequoia glyptostroboides) Cone as a New Natural Dye Resource(1): Dyeing of Cotton Fiber)

  • 염준;류동일;신윤숙
    • 한국염색가공학회지
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    • 제27권2호
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    • pp.142-148
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    • 2015
  • The aim of this study was to investigate the possibility utilizing Metasequoia(Metasequoia glyptostroboides) cone as a new natural dye resource. Dyeing onto cotton fiber was carried out to study the effect of dyeing conditions and mordanting effect on dye uptake, color change, and colorfastness. FT-IR analysis supported that hydrolyzable tannins were contained in the extracted colorant. Metasequoia cone colorant showed low affinity to cotton fiber and maximum dye uptake was obtained at pH 3.5 showing YR Munsell color. Mordanting improved dye uptake regardless of mordant type, especially Fe($C_5H_{10}FeO_6$) mordant was effective as much as 2 times higher dye uptake comparing with un-mordanted sample. The color of dyed fabric with mordanting showed YR Munsell color except of the Fe($FeSO_4{\cdot}7H_2O$) mordanted sample showing Y Munsell color. Colorfastness to rubbing and washing was relatively good, whereas lightfastness of the dyed fabrics was above grade 3/4 except that the dyed samples with Fe mordanting showed grade 2. It is necessary to apply Metasequoia cone colorant onto other fibers, especially protein fibers, for evaluating its efficacy as a new natural dye resource.

생물자원 폐기물을 활용한 친환경 가죽염색(I): 양파껍질을 이용한 장어가죽 천연염색 (Eco-friendly Leather Dyeing using Biomass Wastes(I): Natural Dyeing of Eel Skin using Onion Peels)

  • 여영미;유동일;신윤숙
    • 한국염색가공학회지
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    • 제30권2호
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    • pp.141-149
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    • 2018
  • This study aimed to investigate the efficacy of eco-friendly leather dyeing by utilizing food wastes. Natural dyeing of eel skin was attempted using onion peels which have been used commonly for natural dyeing of textile fabrics. Eel skin is a by-product from fishery processing and is used mainly for making leather products. The colorant was extracted from onion peels in boiling water, concentrated, and freeze-dried. Dyeing of eel skin was carried out to study the effects of dyeing conditions, mordant type and mordanting method on dye uptake, color change, drape stiffness and colorfastness. The optimum dyeing conditions were $60^{\circ}C$ of dyeing temperature, 60min of dyeing time at 1:100($H_2O$ 90%: ethanol 10%) of bath ratio. The onion peels produced yellowish color on eel skin. The pre-mordanting was effective than the post-mordanting. As a result of the drape stiffness measurement, the Fe-mordanted sample was somewhat stiffer comparing to other mordanted samples. The light fastness of the non-mordant dye was excellent in 3-4 grade. Drycleaning fastness and rubbing fastness showed excellent results, but fastness was not significantly improved by mordanting.

신나무, 오리나무 및 자초를 이용한 라미직물의 천연염색 (Natural Dyeing of Ramie Fabrics with Acer Ginnala, Alnus Japonica and Gromwell Extracts)

  • 김상률
    • 패션비즈니스
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    • 제18권4호
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    • pp.15-27
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    • 2014
  • A natural colorant was extracted from Acer ginnala, Alnus japonica and gromwell as extractants. Studies have been made on the effects of the kind of extracts and dyeing/mordanting conditions on colorimetric changes of ramie fabrics. The color of fabrics tended to become darker as the numbers of dyeing process and mordanting process increased using three kinds of extracts. As the numbers of dyeing and mordanting increased, the ramie fabrics gradually increased to show reddish and bluish signs using Acer ginnala, Alnus japonica, and gromwell extracts(500ml and 1,000ml). In the case of 1,500ml of gromwell extracts, the ramie fabrics showed the color with more redness and yellowness. Color difference (${\Delta}E$) of dyed and mordanted fabrics increased as the numbers of dyeing and mordanting processes increased. The apparent colors of ramie fabrics using Acer ginnala were Y and GY. The Alnus japonica extracts produced Y and GY colors on ramie fabrics. With varying amount of gromwell extracts, the colors of dyed and mordanted fabrics were R, YR, GY, G, PB, P and RP, however, the main color was PB. It was concluded that the extracts of Acer ginnala, Alnus japonica and gromwell can be used as a natural dye producing black colors.

알칼리 처리한 PET 직물의 소목염색에서 키토산 및 매염제의 사용 (The Use of Chitosan and Mordanting in the Dyeing of Alkali Treated PET Fabrics with Wood of Caesalpinia Sappan)

  • 구강;김삼수;최종덕;유재영;박영미
    • 한국염색가공학회지
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    • 제18권1호
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    • pp.1-9
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    • 2006
  • Treatment of PET fabrics with alkali, chitosan and Al-mordanting has been carried out and the role of the chitosan coating in the dyeing process was clarified. The pre-treatment was effectively evaluated differences in dyeing behavior between its treated and untreated PET fabrics using wood of Caesalpinia sappan. The pre-treated on PET fabrics has been examined by SEM and evidence for the presence of chitosan sought using a air permeability test. Similar colour fastness by computer color matching(CCM) obtained on both untreated and pre-treated PET fabrics. The pre-treated PET was found to be of a deeper hue to that of its dyed untreated PET and, despite of its better colour depth, the wash fastness of the pre-treated dyeing was comparable to that of its dyed untreated PR. The application of chitosan or mordanting reveled that pre-treatment imparted to the PET additional functional groups that were available for coordination with the Brazilin.

문화재 보존·보관용 천연염색지 개발 (제1보) - 천연염색지의 제조 및 열화특성 - (Development of Natural Dyed Korean Traditional Paper for Cultural Properties Conservation and Storage (Part 1) - Manufacture and Aging Properties of Natural Dyed Hanji -)

  • 이상현;유승일;최태호
    • 펄프종이기술
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    • 제47권6호
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    • pp.139-146
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    • 2015
  • We manufactured natural dyed Korean traditional paper (Hanji) for cultural properties conservation and storage with goldthread (Coptis chinensis) and silver nitrate ($AgNO_3$). Goldthread and silver nitrate are known to be an excellent antimicrobial activity. The effect of content of goldthread and silver nitrate on properties of dyed Hanji was investigated. Color strength of dyed Hanji decreased with increasing content of silver nitrate. After-mordanting with 3% silver nitrate improved lightfastness of dyed Hanji. Tannic acid treatment increased K/S value of dyed Hanji. As the amount of the increase in goldthread content was reduced silver nitrate content. Sim-mordanting method was used for simplifying manufacture process. Silver nitrate sim-mordanting method increased K/S value of goldthread than after-mordanting method.

키토산 가교 처리된 면직물의 천연염색에 관한 연구(IV) - 코치닐을 중심으로 - (Natural Dyeing of Chitosan Crossinked Cotton Fabrics(IV) - Cochineal -)

  • 곽미정;이신희
    • 한국의류산업학회지
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    • 제12권3호
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    • pp.381-388
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    • 2010
  • The purpose of this study was investigate the dyeing property on chitosan crosslinked cotton fabric with cochineal at variable conditions. Chitosan crosslinked cotton fabrics were manufactured by crosslinking agent epichlorohydrin in the presence of chitosan. Chitosan crosslinked cotton fabrics dyed using cochineal were post-mordanted using Al, Fe and Cu. The dyeability(K/S) of chitosan crosslinked cotton fabrics were measured by computer color matching. Additionally the fastness to washing and light were also investigated. The dye-uptake of chitosan crosslinked cotton fabrics increased with the dyeing time. The saturated dyeing time was about 20minutes at $60^{\circ}C$. The dyeability(K/S) was remarkably increased with increasing content of crosslinked chitosan because of having a amine group of chitosan. Chitosan crosslinked cotton fabrics were dyed yellowish red by non and Fe mordanting, blueish red by Al and Cu mordanting, respectively. The washing and light fastness were increased by mordanting, especially Cu and Fe mordanting.

Effect of Rinsing after Mordanting on the Air-permeability and Dyeing of Fabrics with Cochineal Dyestuff

  • Na, Ho-Jin;Jeon, Dong-Won;Kim, Jong-Jun
    • 패션비즈니스
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    • 제8권6호
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    • pp.137-145
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    • 2004
  • According to the experimental results, it has been reported by several researchers that the air-permeability values of the fabrics mostly decreased by the mordanting during the dyeing procedure. The exact quantitative information, however, has not been presented so far. In this study, the change of the fabric air-permeability was investigated quantitatively. At the same time, the change of the fabric air-permeability according to the dyeing procedure. In order to investigate the possibility of the detachment of the metal ions on the fiber or fabric surface, the change of the air-permeability was investigated after several rinsing of the mordanted fabrics. By comparing the color differences of the cochineal dyed fabrics which were subjected to rinsing procedure after mordanting, the effect of the rinsing of the mordanted fabrics on the dyeing of fabrics was investigated. At the range of mordant concentration, 2% Cu, 2% Sn, 2% Fe, 2% Cr, 5% Al, the metal ions are not excessively absorbed on the fiber surface. Also, any remarkable detachment of the metal ions does not accompany after the mordanting with the subsequent rinsing procedure.

키토산과 녹차추출물을 이용한 인체친화적 자외선 차단 셀룰로오스 섬유의 개발 -키토산 매염과 녹차추출물 재염의 효과를 중심으로- (Developing Human-friendly UV Protective Cellulose Fabrics Using Chitosan and Green Tea Extract -Focusing on the Repetition Effect of Chitosan Mordanting and Green Tea Extract Dyeing-)

  • 정혜경;김신희
    • 한국의류학회지
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    • 제33권5호
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    • pp.817-826
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    • 2009
  • As UV radiation to the earth increased over recent years, many adverse effects of UV radiation have been reported. There are needs to develop UV-protective apparel and accessaries to protect skin from these harmful effects. Cellulose is one of the most frequently worn fiber during summer time. However, celllulose shows very low UV-protective property especially in case of thin and low fabric content. In this study, UV-protective cellulose textiles were developed using chiotsan mordanting and green tea dyeing. The repetition effect of chitosan and green tea treatment were focused. Three different cellulose fibers, cotton, linen, and ramie, were used for this study. All chitosan mordanted and green tea dyed fabrics showed increases in UV-protective property. The color of fabrics tended to darker as the numbers of mordanting process and green tea dyeing increased. UV-protective property did not increase significantly upon the repetition of mordanting and green tea dyeing treatment except ramie fabric. UV protective property was persisted upon washfastness test in all three cellulose fiber types.

벚나무 열매의 색소 추출물에 의한 견 및 면섬유에 대한 염색성 및 견뢰도 (Dyeing and Fastness of Silk and Cotton Fabrics Dyed with Cherry Extract)

  • 이영희;황은경;김한도
    • 한국염색가공학회지
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    • 제12권6호
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    • pp.389-395
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    • 2000
  • A natural colorants was extracted from cherry by 10wt% aqueous acetic acid solution as an extractant. Silk and cotton fabrics were dyed with the cherry extract in the temperature range of $40-80^\circ{C}$ and for the time range of 30-60min. by pre- and post-mordanting with various mordants, their dyeability and fastness were investigated. The natural cherry extract prepared in this study has a maximum absorbance at 520nm. It was found that the optimum dyeing temperature and time were $40^\circ{C}$ and 50min, respectively. The pre-mordanting method was more effective than post-mordanting. All mordants except $SnCl_2\cdot{2H}_2O\;and\;FeSO_4\cdot{7H}_2O$ were effective for silk fabrics. However, the dyeability on cotton fabrics increased in the order of $CrK(SO_4)_2\cdot{12H_2O>(CH_3COO)_2Cu\cdot{H}_2O>CuSO_4\cdot{5H}_2O>AlK(SO_4)_2\cdot{12H}_2O>FeSO_4\cdot{7H}_2O>SnCl_2\cdot{2H}_2O$ among the mordants used in this study Fastness(light, water, washing, perpspiration fastness) on the silk and cotton fabrics increased with using mordants. The post-mordanting using mordant$(CH_3COO)_2Cu\cdot{H}_2O$ among the various mordants in this study gave the best fastness.

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어성초 추출색소를 이용한 친환경 염색: 양모직물의 염색성과 기능성을 중심으로 (Eco-friendly Dyeing using Houttuynia cordata Extract: Dyeability and Functionality of Wool Fabrics)

  • 손경희
    • 한국염색가공학회지
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    • 제32권1호
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    • pp.1-8
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    • 2020
  • The objective was to study the efficiency of Houttuynia cordata extract colorants as eco-friendly and functional dye for wool fabrics. Effects of dyeing conditions and mordanting on dye uptake, color change, and colorfastness were investigated. Also, antimicrobial activity and deodorization performance were evaluated. The Houttuynia cordata colorants showed good affinity to wool fabrics and produced YR Munsell color. The optimum condition of dyeing was 2.0% of colorants concentration(o.w.b.) at 100℃ for 60 minutes under pH 5.3. Regardless of the mordant type and mordanting method, mordants improved dye uptake and the increase in dye uptake by Fe mordant was higher than that of Al mordant. Al post-mordanting and Fe mordanting changed the color of dyed fabrics with Y Munsell color. The colorfastness of un-mordanted and Al post-mordanted fabrics were excellent above grade 4. Bacteria reduction rate(Staphylococcus aureus) of wool fabrics dyed with Houttuynia cordata colorants was excellent at 98.2%. Also, the deodorization was good at 81%. The results show Houttuynia cordata colorants can be used as a functional natural dye for wool fabrics.