• Title/Summary/Keyword: Monoterpene

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Study on Natural VOC Emission Rates and Characteristics Emitted from Larix Leptoleis (Sieb. et Zucc.) Gordon (낙엽송으로부터 배출되는 자연 VOC 배출속도 및 배출특성 연구)

  • Kim, Ki-Joon;Kim, Jo-Chun;Lim, Jun-Ho;SunWoo, Young;Park, Hyun-Ju;Cho, Kyu-Tak
    • Journal of Environmental Science International
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    • v.16 no.2
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    • pp.151-158
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    • 2007
  • In order to investigate the compositions and the emission rates of monoterpenes emitted from coniferous trees, those from Larix leptoleis (Sieb, et Zucc.) Gordon were measured. In spring and summer, the major monoterpenes were ${\alpha}-terpinene,\;{\alpha}-pinene$, myrcene; however, ${\alpha}-pinene\;and\;{\alpha}-terpinene$ were most abundant in fall. The total mean monoterpene emission rates were $0.455\;({\mu}gC/gdw/hr)$ during the whole period. The higher monoterpene emission rates were found in fall compared to those in spring and summer. In addition, the slopes (${\beta}\;value$) between emission rate and temperature were two times lower in fall than those in spring and summer. It was also found that Larix leptoleis (Sieb. et Zucc.) Cordon had lower monoterpene emission rates than P. densiflora and P. rigida.

A New Monoterpene from the Flower Buds of Buddleja officinalis

  • Lee, Chul;Lee, Sora;Park, So-Young
    • Natural Product Sciences
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    • v.19 no.4
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    • pp.355-359
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    • 2013
  • A new monoterpene, crocusatin M (1), was isolated from the flower buds of Buddleja officinalis, together with four known monoterpenes, (6R)-hydroxy-1,1,5-trimethylcyclohex-4-enone (2), (+)-dehydrovomifoliol (3), 7-epiloliolide (4), and crocusatin D (5). Their structures were determined by an extensive analysis of 1D, 2D NMR, HRESI-MS, and CD data as well as by comparison of their spectroscopic data with those of literatures. All isolates were evaluated for inhibitory activities on LPS-induced nitric oxide production in RAW 264.7 cells. Among them, compounds 2 and 3 showed moderate inhibitory effects with $IC_{50}$ values of 63.8 and 24.4 ${\mu}g/ml$, respectively.

A New Stereoisomeric Monoterpene Glycoside from Clematis heracleifolia leaves

  • Kim, Mi Ae;Yang, Heejung;Kim, Myong Jo;Chun, Wanjoo;Kwon, Yongsoo
    • Natural Product Sciences
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    • v.22 no.2
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    • pp.107-110
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    • 2016
  • A new stereoisomeric monoterpene glycoside and five already-known compounds were isolated from the n-BuOH soluble fraction of Clematis heracleifolia leaves. On the basis of spectral data, the structures of the isolated compounds were identified as protocatechuic acid (1), ferulic acid (2), caffeic acid (3), aesculin (4), (6Z)-9-hydroxylinaloyl glucoside (5), and 9-hydroxylinaloyl glucoside (6) and these were isolated for the first time from this plant. Among these compounds, (6Z)-9-hydroxylinaloyl glucoside (5) is a newly isolated from plant source.

A Study on the Estimation of BVOCs Emission in Jeju Island (1) (제주지역 BVOCs의 배출량 산정에 관한 연구(1))

  • Lee, Ki-Ho;Kim, Hyeong-Cheol;Hu, Chul-Goo
    • Journal of Environmental Science International
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    • v.23 no.12
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    • pp.2057-2069
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    • 2014
  • This study was carried out to estimate the BVOCs emissions with the emission factors which reflected the native conditions of forests in Jeju Island. This study made effective use of the previous data for the weather data and the emission rate of each organic volatile component measured at 10 species of conifers and broad leaved trees. The CORINAIR method and the grid system of $1km{\times}1km$ for whole area of Jeju Island were adopted in calculating the BVOCs emission emitted from forest. The vegetation information for Jeju Island was referred to GIS and a government report. By the results of BVOCs emission for Jeju Island, the 85% of monoterpene emission was emitted from conifers and the others was from broad leaved trees. Most of monoterpene emission was attributed to Pinus thunbergii and Cryptomeria japonica. The broad leaved trees greatly contributed to the isoprene emission and Quercus serrata played a dominant role in emission of isoprene. The total amount of BVOCs emission was estimated as $3612ton\;yr^{-1}$ in Jeju Island. The 51.1% of total emission was contributed to conifers, the 44.9% to broad leaved trees, and the 4.0% to grassland. Of total emission of BVOCs, monoterpene accounted for 32.3%, isoprene for 28.0%, and OVOCs for 39.7%. The BVOCs emission estimated by this study was less than that estimated by other previous study. This means that it is important to survey the emission rate at native conditions and gather the detailed information for various species of vegetation on target region.

A Cytotoxic Monoterpene-Neolignan from the Stem Bark of Magnolia officinalis

  • Youn, Ui-Joung;Lee, Ik-Soo;Chen, Quan Cheng;Na, Min-Kyun;Jung, Hyun-Ju;Lee, Sang-Myung;Choi, Jae-Sue;Woo, Mi-Hee;Bae, Ki-Hwan;Min, Byung-Sun
    • Natural Product Sciences
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    • v.17 no.2
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    • pp.95-99
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    • 2011
  • A monoterpene-neolignan, piperitylmagnolol (1), was isolated from the stem bark of Magnolia officinalis, together with syringaresinol (2), caffeic acid (3), and sinapaldehyde (4). The isolated compounds were established on the basis of spectroscopic and physicochemical analyses including 1D- and 2D-NMR techniques, as well as on comparing the spectral data with those in the literature and of authentic samples. Compounds 1 - 4 were tested for their cytotoxic activity against the HeLa, K562, A549, and HCT116 cancer cell lines in vitro. Of the isolates, piperitylmagnolol (1) exhibited cytotoxic activity against the tested cancer cell lines with $IC_{50}$ values of 7.7 - 9.5 ${\mu}g/ml$.

Characteristics of phytoncide production at the recreation forest in the Chungbuk area (충북지역 자연휴양림의 피톤치드 발생 특성)

  • Lee, Sang-Woo;Park, Deog Gyoo;Kim, Kwang-Yul
    • Journal of Environmental Impact Assessment
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    • v.21 no.2
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    • pp.279-287
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    • 2012
  • Phytoncide, which is emitted from plant against the insect species and bacterium, has been known as a health builder for human. Monoterpenes are major components of phytoncide. This study was conducted to investigate the distribution characteristics of phytoncide(monoterpene) depending on main species of tree, season, and meteorological factors in the 5 recreation forests, Chungbuk area. From the result of the study. it was shown that the annual concentrations of monoterpene are ranged in 236.0pptv - 698.3pptv depending on main species of tree. The variation of seasonal concentration was summer > spring > fall. The monoterpene concentration of coniferous forest was founded to be higher than broad leaved forest. In general, concentration of major components is ${\alpha}$-pinene > ${\beta}$-pinene > camphene > d-limonene. The concentration of terpene was founded to be greatly influenced by the meteological factors such as insolation and temperature.

A New Monoterpene Glucoside from Portulaca oleracea

  • Seo, Young-Wan;Shin, Jong-Heon;Cha, Hyo-Jun;Kim, You-Ah;Ahn, Jong-Woong;Lee, Burm-Jong;Lee, Dong-Seok
    • Bulletin of the Korean Chemical Society
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    • v.24 no.10
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    • pp.1475-1477
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    • 2003
  • Three monoterpene glucosides (1-3), including one new compound (3), have been isolated from the methanol extract of Portulaca oleracea. Structures of these compounds were determined to be (3S)-3-O-( ${\Beta}$-Dglucopyranosyl)-3,7-dimethylocta-1,6-dien-3-ol (1), (3S)-3-O-( ${\beta}$-D-glucopyranosyl)-3,7-dimethylocta-1,5-dien-3,7-diol (2) and (3S)-3-O-( ${\beta}$-D-glucopyranosyl)-3,7-dimethyl-7-hydroperoxyocta-1,5-dien-3-ol (3), respectively, by a combination of spectral analyses. Their stereochemistries were established by measurement of NOE and vicinal proton-proton coupling constants as well as comparisons of spectral data with those of previously related compounds.

Glycosides from the Flower of Clerodendrum trichotomum (누리장나무 꽃의 배당체 성분)

  • Lee, Jong-Wook;Bae, Jong Jin;Kwak, Jong Hwan
    • Korean Journal of Pharmacognosy
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    • v.47 no.4
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    • pp.301-306
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    • 2016
  • Four phenylpropanoid glycosides and a monoterpene glycoside were isolated from the flower of Clerodendrum trichotomum. Structures of the isolated compounds were identified as acteoside (1), martynoside (2), leucosceptoside A (3), isoacteoside (4) and neohancoside A (5) by spectroscopic analysis. Compounds 1-4 were isolated from the flower of C. trichotomum for the first time. Compound 5 was first obtained from genus Clerodendrum as well as family Verbenaceae. The antioxidant activity of compounds 1-5 were evaluated by the DPPH free radical scavenging assay. Compounds 1-4 exhibited strong antioxidant activity.

Microbial Transformation of a Monoterpene, Geraniol, by the Marine-derived Fungus Hypocrea sp.

  • Leutou, Alain S.;Yang, Guohua;Nenkep, Viviane N.;Siwe, Xavier N.;Feng, Zhile;Khong, Thang T.;Choi, Hong-Dae;Kang, Jung-Sook;Son, Byeng-Wha
    • Journal of Microbiology and Biotechnology
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    • v.19 no.10
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    • pp.1150-1152
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    • 2009
  • Geraniol (1) is the biogenetic precursor of a number of monoterpenes. We tested various marine-derived microorganisms to determine their ability to biotransform 1. Only Hypocrea sp. was capable of transforming 1 into its oxidized derivative, 1,7-dihydroxy-3,7-dimethyl-(E)-oct-2-ene (2). The structure of the metabolite obtained was assigned on the basis of detailed spectroscopic data analyses.