• Title/Summary/Keyword: Monolayer,

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Effects of Ethanol on the Fluidity of Plasma Membrane Vesicles Isolated from Cultured Mouse Myeloma Cell Line Sp2/0-Ag14 (Ethanol이 배양된 Mouse Myeloma Cell Line Sp2/0-Ag14로부터 분리한 형질막의 유동성에 미치는 영향)

  • Yun, Il;Chung, In-Kyo;Park, Yeong-Min;Kim, Jin-Bom;Yu, Seoung-Ho;Kang, Jung-Sook
    • The Korean Journal of Pharmacology
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    • v.29 no.1
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    • pp.149-156
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    • 1993
  • Intramolecular excimerization of 1,3-di(1-pyrenyl)propane (Py-3-Py) and fluorescence polarization of 1,6-diphenyl-1,3,5-hexatriene (DPH) were used to examine the effects of ethanol on the rate and range of lateral diffusion of bulk bilayer structures of plasma membrane vesicles isolated from cultured mouse myeloma cell line Sp2/0-Ag14 (Sp2/0-PMV). In a concentration-dependent manner, ethanol increased the excimer to monomer fluorescence intensity ratio (I'/I) of Py-3-Py in the Sp2/0-PMV and decreased the anisotropy (r), limiting anisotropy $(r_{\infty})$, and order parameter (S) of DPH in the Sp2/0-PMV. This indicates that ethanol increased both the lateral and rotational diffusion of the probes in the Sp2/0-PMV. Selective quenching of DPH by trinitrophenyl groups was utilized to examine the transbilayer asymmetric rotational diffusion of the Sp2/0-PMV. The anisotropy (r), limiting anisotropy $(r_{\infty})$, and order parameter (S) of DPH in the inner monolayer were 0.022, 0.029, and 0.063, respectively, greater than calculated for the outer monolayer of the Sp2/0-PMV. Selective quenching of DPH by trinitrophenyl groups was also utilized to examine the transbilayer asymmetric effects of ethanol on the range of rotational diffusion of the Sp2/0-PMV. Ethanol had a greater fluidizing effect on the outer monolayer as compared to the inner monolayer of the Sp2/0-PMV. It has been proven that ethanol exhibits a selective rather than nonselective fluidizing effect within transbilayer domains of the Sp2/0-PMV.

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Structure Analysis for Surface of LB Films Complexed Metal Ion (금속이온 착체에 의한 LB막의 표면 구조 분석)

  • Shin, Hoon-Kyu;Yoo, Seung-Yeop;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.881-883
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    • 1998
  • We fabricated IMI-O polymer containing imidazole group that can be form a complex structure between the monolayer and the metal ions at the air-water interface. Also, the monolayer behavior at the air-water interface and Langmuir-Blodget films by complexes formation have been investigated by $\pi$-A isotherms, Brewster Angle Microscopy and the scanning Maxwell-stress microscopy.

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Transport of anti-allergic drugs across the passage cultured human nasal epithelial cell monolayer

  • Lin, Hongxia;Yoo, Jin-Wook;Lee, Chi-Ho;Kim, Dae-Duk
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.291.2-292
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    • 2003
  • The purpose of this study was to investigate the transport characteristics of passage cultured l1uman nasal epithelial cell monolayers grown on Transwell@ inserts using liquid-covered culture (LCC) method. The monolayer of passage 2 and 3 exhibited tight barrier (TEER>1,000 ohmxcm$^2$) in 2-3 days after seeding. In the morphological studies by actin staining and SEM/TEM, the existence of tight junction was clearly observed. (omitted)

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Structural change of cobalt dodecanesulfate (Cobalt dodecanesulfate의 구조변화)

  • 허영덕;권석순;김지현
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.2
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    • pp.63-67
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    • 2004
  • The layered structure of cobalt dodecanesulfate was synthesized. A phase transition takes place at various temperature ranges and results in a drastic change of the layer distance. A monolayer structure of cobalt dodecanesulfate at room temperature transformed to a bilayer structure as a dehydrated form at high temperature.

Anti-corrosive surface treatment of Mg alloy steel using organic self assembly monolayer technique (유기 단분자막을 이용한 마그네슘 합금 판재 (AZ31)의 내식성 표면처리 기술 연구)

  • Park, Jong-Won;Lee, Gyeong-Hwang;Park, Yeong-Hui
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2009.05a
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    • pp.113-114
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    • 2009
  • 기존의 습식 및 건식 표면처리 공정의 단점을 극복하고, 마그네슘 합금의 가장 큰 문제점인 내식성개선을 위해 열화학기상증착(thermal Chemical Vapor Deposition)법을 이용하여 자기조직화 유기 단분자막(Self-Assembled organic Monolayer, SAM)을 제작하여 마그네슘 합금(AZ31)의 내식성을 검토하였다.

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Geometry Optimization of Au Adsorption on MoS2 Monolayer

  • Hong, Yu-Jin
    • Proceeding of EDISON Challenge
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    • 2014.03a
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    • pp.511-513
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    • 2014
  • $MoS_2$ monolayer에 Au 원자를 흡착시켰을 때 가장 안정한 위치를 찾아 내기위한 연구를 수행하였다. 이를 위하여 $MoS_2$ $1{\times}1$ unit cell 위의 on-top, bridge, hollow 위치에 Au 원자를 놓고 DFT 기반 제일원리 계산을 통하여 최적화된 구조에서의 에너지를 계산, 비교하였다. 그 결과 S 원자 위에 Au 원자가 흡착 되었을 때 가장 안정한 구조를 이루는 것을 알 수 있었다.

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Strategies to Induce Metastable T' Phase of Monolayer MoS2

  • Gang, Seong-U
    • Proceeding of EDISON Challenge
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    • 2017.03a
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    • pp.417-423
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    • 2017
  • Monolayer $MoS_2$의 metastable phase인 T' phase가 stable한 H phase보다 안정해지는 조건을 모색하기 위해 substitutional doping을 했을 때와 strain을 걸어주었을 때의 에너지 차이를 DFT 방법으로 계산하였다. Doping을 했을 때와 strain이 있을 때 T' phase와 H phase의 에너지 차이가 감소함을 확인하였으나 H phase보다 T' phase가 안정해지는 조건을 찾지는 못하였다. 하지만 이 방법을 기존의 alkali adsorption 방법과 병행하여 기존 방법의 단점을 보완할 수 있을 것을 기대해 볼 수 있다. 또한 전자구조 분석 중 얻은 dopant의 주기와 족에 따른 경향성은 다른 TMD 물질의 phase engineering을 design할 때 universal한 design rule로서 응용할 수 있음을 기대해 볼 수 있다.

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MoS2 monolayer에서의 doping effect

  • Lee, Mi-So
    • Proceeding of EDISON Challenge
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    • 2015.03a
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    • pp.373-377
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    • 2015
  • 이 연구에서는 원자 궤도 함수 기반 DFT 전자구조 계산을 이용해서 최근 각광받고 있는 이차원 물질인 MoS2 monolayer의 S 자리와 Mo 자리에 각각 전자가가 다른 원자를 치환하였을 때의 도핑 특성을 Density of States (DOSs)와 밴드구조 등의 전자구조를 통해 분석해 보았다. S자리에 Cl, Si, I, B, C, Mo 자리에는 Hf, Ta, 그리고 Re을 치환해 보았으며 계산 결과 S자리에 Cl을 치환했을 때 가장 얕은 acceptor level (VBM으로부터 0.08 eV)이 형성되었으며, Mo자리에 Re를 치환했을 때에는 resonant state를 형성하였다. 또한 Mo자리에 Ta를 치환했을 ? 가장 얕은 donor level (CBM으로부터 0.02 eV)가 형성되었다.

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A study on the movement of Liquid DMPE and DLPE monolayer on a water subphase by Maxwell Displacement Currents (변위전류에 의한 DMPE, DLPE 지질막의 수면상 거동 연구)

  • ;;;;M. Iwamoto
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.191-194
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    • 1996
  • Maxwell displacement current clearly shows the onset of a first order phase transition from gaseous to gaseous-fluid phase, and polar ordering of liquid molecules in the solid phase coexisting with fluid. For further monolayer compression in the fluid/solid phase transition, the condensation of domains was suggested.

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Stimulus Current of Mixed Organic Thin Films (혼합 유기박막의 자격 전류)

  • Cho, Su-Young;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2000.11c
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    • pp.464-466
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    • 2000
  • In the study We measured the MDC across lipidazobenzene monolayer system was the substrate. We discuss the cis-trans isomerization in Langmuir-Blodgett(LB) films and examine the relationship between the structure of mixed LB films and the generation of MDCs due to photoisomerization. As results, mixed induce monolayer of view to memory and switching, it's own function by particles level think. Also, transmission results of stimulus signal it's form by current to appear.

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