• Macromolecular Research
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• 제9권2호
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• pp.122-128
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• 2001

Monodisperse composite latex particles with size of ca. 300 nm, which consist ofn-butyl acrylate as a soft phase and methyl methacrylate as a hard phase with different morphology, were synthesized by seeded multi-stage emulsion polymerization. Three types of composite latex particles including random-, core/shell-, and gradient-type particles were obtained by using different monomer feeding methods during semi-batch emulsion polymerization. Effect of poly(butyl acrylate)-poly(methyl methacrylate) rubber particle morphology on the mechanical and rheological properties of rubber toughened poly(methyl methacrylate) was investigated. Among three different rubber particles, the gradient-type rubber particle showed better toughening effect than others. No significant variation of rheological property of poly(methyl methacrylate)/rubber blends was observed for the different rubber particle morphology.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.5-6
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• 2006

Molecular motion at the surface of monodisperse polystyrene (PS) films with various chain end groups was studied by scanning probe microscopy. Surface glass transition temperature ($T_{g^s}$) of the PS films was much lower than the corresponding bulk value. And, the magnitude of $T_{g^s}$ was strongly dependent on chain end chemistry. This result can be explained in terms of the chain end concentration at the surface. Time-temperature superposition principle was applied to rheological analysis at the surface. The apparent activation energy of the surface ${\alpha}_{a}$-relaxation process was approximately a half of that for the bulk sample. This result clearly indicates that the cooperativity for the surface segmental motion was reduced in comparison with that in the bulk region.

• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.206-206
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• 2006

Polymer induced turbulent drag reduction achieved by adding minute amounts of high molecular weight DNAs in aqueous solution was investigated using a rotating disk apparatus. The DNAs in this study include ${\lambda}-DNA$ and calf-thymus (CT) DNA. By putting emphasis on effect of CT-DNA concentration, its DR characteristics were compared with that of ${\lambda}-DNA$ possessing monodisperse molecular weight characteristics based on both DR efficiency and a mechanical degradation under turbulence. The DNA chains having much higher molecular size than that of ${\lambda}-DNA$ are observed to be more susceptible to mechanical degradation in a turbulent flow. This result was verified via electrophoresis. Furthermore, the coil to globule phase transition of DNA was also investigated under a turbulent flow.

• 한국분무공학회지
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• 제13권4호
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• pp.187-192
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• 2008

In this study, the mechanisms of binary droplet collision were studied with diesel, ethanol and purified water. The droplet collisions of liquid droplet have been investigated for the same droplet diameter. In order to obtain the digital images of the droplet collision behavior, the experimental equipment was composed of the droplet generating system and the droplet visualization system. The droplets were produced by the vibrating orifice monodisperse generator. The visualization system consisted of a long distance microscope, a light source, and a high speed camera. The outcomes of binary droplet collision can be divided into four regimes, bouncing, coalescence, reflexive separation and stretching separation. The impact angle and the relative velocity of binary droplet are main parameters of collision phenomena, so the transition mechanism of droplet collision can be divided by the impact parameter.

• 한국입자에어로졸학회지
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• 제14권3호
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• pp.49-63
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• 2018

During the last decade, electrospray (ES) techniques have been used as potential methods for preparing of core-shell materials. Depending on the architecture of nozzle and design of devices, the ES techniques includes monoaxial, coaxial, multiple coaxial nozzle ES and microfluidic ES devices. ES operates based on a basic principle, in which a spray of monodisperse droplets is formed by dispensing an electrically conductive liquid through a capillary charged to a sufficiently high potential. In review of many recent research papers, we take a closer look at ES techniques and their applications for fabrication of core-shell materials. Several advantages of ES technique compared with other methods were emphasized and it may be regarded as a potential tool for fabrication of core-shell materials current and near future.

• Biotechnology and Bioprocess Engineering:BBE
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• 제11권3호
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• pp.179-186
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• 2006

End-Labeled Free-Solution Electrophoresis (ELFSE) is a new technique that is a promising bioconjugate method for DNA sequencing (or separation) and genotyping by both capillary and microfluidic device electrophoresis. Because ELFSE enables high-resolution electrophoretic separation in aqueous buffer alone (i.e., without a polymer matrix), it eliminates the need to load viscous polymer networks into electrophoresis microchannels. To achieve microchannel DNA separations with high performance, ELFSE requires monodisperse perturbing entities (i.e., drag-tags), which create a large amount of frictional drag when pulled behind DNA during free-solution electrophoresis, and which have other properties suitable for microchannel electrophoresis. In this article, the theoretical concepts of ELFSE and the required characteristics of the drag-tag molecules for the ultimate performance of ELFSE are reviewed. Additionally, the merits and limitations of current drag-tags are also discussed in the context of recent experimental data of ELFSE separation (or sequencing).

• 산업기술연구
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• 제29권B호
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• pp.229-232
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• 2009

We prepared gold nanoparticles (Au NPs) by reduction-oxidation reaction between $HAuCl_4$ and trisodium citrate and measured the size and morphology of Au NPs by TEM for various molar ratios of $HAuCl_4$ to citrate and for various concentrations of $HAuCl_4$. UV-vis spectroscopy was used to characterize the optical properties of Au NPs. Au NPs in the size range from 14.3 nm to 20.3 nm were prepared with monodisperse distribution.

• 한국분무공학회지
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• 제3권3호
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• pp.1-13
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• 1998

In this study, an experimental study was performed to investigate the breakup mechanism of vaporizing droplet. A well-controlled experimental apparatus was used to study breakup mechanisms of a monodisperse stream of drops injected into a transverse high temperature and velocity air stream. The experiments gave information$ about the microscopic structure of the liquid drop breakup process, drop breakup regimes, and drop trajectories in high temperature flow region. The breakup time, drop acceleration and wavelength of surface instability wave were measured from a high-magnification and double spark photography. The two instability theories, i.e., Kelvin-Helmholtz instability and Rayleigh-Taylor instability, were estimated by comparing the calculated data with the measurements. The results showed that the breakup time in high temperature flow condition is shortened because the surface tension is decreased by the increase of gas temperature.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2003년도 The Fifth Asian Computational Fluid Dynamics Conference
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• pp.21-22
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• 2003

We perform two kinds of computer simulations on polydisperse hard-sphere systems; a molecular-dynamics simulation on atomic systems and a Brownian-dynamics simulation on colloidal suspensions. Analyses of the mean square displacement, the radial distribution function, and the pressure suggest that there exist three phase regions, a liquid phase region, a metastable phase region, and a crystal phase region, where the freezing and melting points are shifted to the values higher than in monodisperse case. It is also shown that the long-time behavior of colloidal suspensions is exactly the same as that of atomic systems.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집B
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• pp.168-173
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• 2000

Flame aerosol synthesis technology refers to the formation of fine particles from gases in flame and is widely used in practical materials processing. In this paper, an experimental investigation was performed on growth of the silica particles that were generated in $H_2/O_2$ Diffusion Flame by the direct injection or TEOS using Electro-spraying method. in this flame aerosol synthesis, four main parameters or nos interaction (flame temperature, residence time or particle in flame, TEOS flow rate, applied voltage) for particle generation and growth was investigated along the axial direction above the burner. A fairly monodisperse non-aggregated particles were successfully obtained.