• 제목/요약/키워드: Monodisperse

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서스펜션 중에서 입자의 형태와 크기가 침강특성에 미치는 영향 (The Effect of Particle Shape and Size on the Settling Characteristics in Suspension)

  • 이기종
    • 한국재료학회지
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    • 제4권8호
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    • pp.927-933
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    • 1994
  • 비구형 입자들의 크기와 형태에 따른 침강 특성의 영향을 검토하였다. 비구형입자를 포함하는 서스펜션의 침강에서 $log \mu_{c}$$log \varepsilon$로부터 얻은 기울기 지표n값은 형태와 크기가 다른 입자는 같은 부피 농도에서 흡착되는유체량이 달라져 입자크기가 감소하거나 불균일한 경우 증가하는 경향을 나타내었다. 실험결고 비구형입자를 포함하는 서스펜션의 침강에서 기울기 지표 $n_{i}$값에 대하여 $n_{i}=n(a+b/d_{v})$와 같은 식을 얻었으며 이때 a, b는 입자형태에 따른 상수이다.

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Three Dimensionally Ordered Microstructure of Polycrystalline Zirconia Ceramics with Micro-Porosity

  • Chang, Myung Chul
    • 한국세라믹학회지
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    • 제53권1호
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    • pp.50-55
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    • 2016
  • In order to make a highly ordered three-dimensionally macro-porous structure of zirconia ceramics, porogen precursors PMMA beads were prepared by emulsion polymerization using acrylic monomer. The monodisperse PMMA latex beads were closely packed by centrifugation as a porogen template for the infiltration of zirconium acetate solution. The mixed compound of PMMA and zirconium acetate was dried. According to the firing schedule, dry compacts of PMMA and zirconium acetate were calcined at $475^{\circ}C$ to obtain micro-, macro-, and meso- structures of polycrystalline zirconia with monodispersed porosity. Inorganic frameworks composed of $ZrO_2$ were formed and showed a three Dimensionally Ordered Microstructure [3DOM] of $ZrO_2$ ceramics. The obtained $ZrO_2$ skeleton was calcined at $710^{\circ}C$. The 3DOM $ZrO_2$ skeleton showed color tuning in solutions such as deionized [DI] $H_2O$ and/or methanol. The monodispersed crystalline micro-structure with micro/meso porosity was observed by FE-SEM.

Dye-sensitized solar cells using size dependent SBM binder

  • 박경희;김은미;조홍관;왕교;홍창국;구할본
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 추계학술대회 논문집
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    • pp.116-116
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    • 2009
  • $TiO_2$ pastes was synthesized to obtained of high efficiency dye-sensitized solar cells using size dependent co-polymer. SBM co-polymer binder is consist of styrene, n-butyl acrylate, and methacrylic acid (SBM) monodisperse co-polymer binder materials and this $TiO_2$ pastes were applied of dye-sensitized solar cells (DSSCs). The photoanodes were characterized by ATR-Fourier Transform spectrometer, X-ray diffraction (XRD) and morphology was investigated by field emission scanning electron microscopy (FE-SEM). The photoelectrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density, AC impedance and monochromatic incident photon-to-current conversion efficiency (IPCE). DSSC based on the 100nm size co-polymer binder was obtained conversion efficiency of 8.1% under irradiation of AM 1.5(100 $mWcm^2$).

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Synthesis and Magnetic Properties of Dendron Capped Fe2O3 Nanoparticles

  • George, Sheby M.;Hong, In-Seok;Kim, Jin-Kwon
    • Bulletin of the Korean Chemical Society
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    • 제29권8호
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    • pp.1545-1553
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    • 2008
  • Using a one-pot reaction technique, monodisperse $\gamma-Fe_2O_3$ nanoparticles were prepared by thermal decomposition of Fe$(CO)_5$ in the presence of a long alkyl chain terminated dendron surfactant. The size of the particles is controlled by adjusting the concentration of the dendron ligands in the reaction solution. Spherical, 2 nm sized nanoparticles were obtained with a 3:1 ratio of dendrons to Fe$(CO)_5$, while 4.6 nm sized particles were formed with a 1:3 ratio. Superparamagetic properties of 2 nm, 4 nm, and 4.6 nm sized particles were measured using a SQUID magnetometer.

반도체 세정 공정 평가를 위한 나노입자 안착 시스템 개발 (Development of Particle Deposition System for Cleaning Process Evaluation in Semiconductor Fabrication)

  • 남경탁;김영길;김호중;김태성
    • 반도체디스플레이기술학회지
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    • 제6권4호
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    • pp.49-52
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    • 2007
  • As the minimum feature size decrease, control of contamination by nanoparticles is getting more attention in semiconductor process. Cleaning technology which removes nanoparticles is essential to increase yield. A reference wafer on which particles with known size and number are deposited is needed to evaluate the cleaning process. We simulated particle trajectories in the chamber by using FLUENT. Charged monodisperse particles are generated using SMPS (Scanning Mobility Particle Sizer) and deposited on the wafer by electrostatic force. The Experimental results agreed with the simulation results well. We calculate the particles loss in pipe flow theoretically and compare with the experimental results.

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Preparation and Surface Charge Characterization of Polystyrene Particles and Powders with Carboxyl and/or Poly(ethylene glycol) Groups

  • Kim, Bae-Joong;Kim, Seong-Hun;Park, Ki-Hong
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.94-94
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    • 2003
  • Cross-linked polystyrene (PS) particles with carboxyl and/or poly(ethylene glycol) units on surface were formed by an emulsifier-free emulsion polymerization using styrene, methacrylic acid (MA), and poly(ethylene glycol) dimethacrylate (PEG-diMMA) at pH 7, and followed by freeze-drying to give the corresponding powders. Monodisperse polymer particles could be obtained at a concentration of PEG-diMMA 1 mol% relative to styrene. Zeta potential of polymer surface was measured to be 91 mV at a polymer of PEG-diMMA 1 mol% and was dropped as the content of MA increased.

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난류선회 등온 및 분무연소 유동에 대한 수치해석 (Numerical Study of Turbulent Swirling Isothermal and Spray-Combusting Flows)

  • 김성구;안국영;김용모;이창식
    • 한국자동차공학회논문집
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    • 제4권5호
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    • pp.130-141
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    • 1996
  • Numerical study of a confined, swirling, isothermal and spray-combusting flows has been presented. The pressure-velocity coupling in the Eulerian gas-phase equation is handled by the improved PISO algorithm. The droplet dispersion by turbulence is introduced by a Stochastic Separated Flow(SSF) model. The k-$\varepsilon$ turbulence model and the eddy dissipation model are employed to account for turbulence-combustion interaction. The detailed comparison with experimental data has been made for the isothermal jet swirling flows and the nearly monodisperse spray-combusting flow in the swirl combustor.

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Synthesis and Characterization of Alternating Block Copolycarbonates Containing Constituent Groups of Polysulfone

  • Lee, Jung-Ah;Yoo, Seung-Hoo;Jho, Jae-Young;Lee, Jong-Chan
    • Macromolecular Research
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    • 제11권6호
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    • pp.437-443
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    • 2003
  • A series of alternating and alternating block copolycarbonates containing the constituent groups of polysulfone was synthesized through a multi-step solution condensation method. For the regulation of block length, monodisperse oligomers were prepared by using a large excess of the bisphenols and were subsequently incorporated into the copolymer chains. Separating the unreacted bisphenols from the oligomers by dissolution/precipitation steps took advantage of solubility differences. The structures of the monomers, oligomers, and copolymers were characterized and confirmed by GPC, NMR spectroscopy, mass spectrometry, and elemental analysis. Monodispersity of the oligomers, which is critical for control over the block length in the copolymers, was confirmed by GPC and mass spectrometry. Of the two constituent groups of the polysulfone, the sulfone linkage stiffens the polycarbonate copolymer chain, while the ether linkage softens it.

전기 수력학적 방법을 이용한 미세 입자의 하전 특성에 관한연구 (Study on the Fine Particle Charging Characteristics with the Electrohydrodynamic Atomization)

  • 안진홍;김광영;윤진욱;안강호
    • 설비공학논문집
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    • 제13권4호
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    • pp.289-294
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    • 2001
  • A well defined electro-spraying and electro-static precipitator(ESP) experiment is carried out to investigate the charging characteristics of the submicron particles and the monodisperse particles. The basic idea is that the highly charged electro-sprayed droplets will be produced into the gas when the Coulombic repulsive force on the surface is higher than the surface tension of the spraying liquid. During this process many highly charged smaller droplets or ions, if the droplets are completely dried out, will be produced in the space. These charged species will be attached ion the particles and then eventually charge the particles. These charged particles will be easily collected with ESP. The experimental results show that the atomizer generated particles with geometric mean diameter (GMD) of 62nm are charged more than 90% even at the mean face velocity of 2.5m/s at the charging zone.

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반도체 세정 공정 평가를 위한 나노입자 안착 시스템 개발

  • 남경탁;김호중;김영길;김태성
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2007년도 춘계학술대회
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    • pp.128-131
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    • 2007
  • As the minimum feature size decrease, control of contamination by nanoparticles is getting more attention in semiconductor process. Cleaning technology which removes nanoparticles is essential to increase yield. A reference wafer on which particles with known size and number are deposited is needed to evaluate the cleaning process. We simulated particle trajectories in the chamber by using FLUENT. Charged monodisperse particles are generated using scanning mobility particle sizer (SMPS) and deposited on the wafer by electrostatic force. The experimental results agreed with the simulation results well. We calculate the particles loss in pipe flow theoretically and compare with the experimental results.

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