• 한국해양공학회지
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• 제11권1호
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• pp.49-54
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• 1997

On the precipitatiopn and ripening reaction of the precipitates from a lead nitrate and an oxalic acid dissolved in ethanol, a new crystalline phase was obtained, whose X-ray diffraction data have not previously been reported. The crystal system was determined to be monoclinic. The unit-cell parameters were refined to a =10.613(2)$\AA$, b =7.947(2))$\AA$, c =6.189(1)$\AA$, and $\beta$=104.48(2)$^{\circ}$.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.71-71
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• 2010

Copper oxide thin films were deposited on the p-type Si(100) by r.f. magnetron sputtering as a function of different substrate temperature. The deposited copper oxide thin films were investigated by atomic force microscopy (AFM), scanning electron microscopy (SEM), spectroscopic ellipsometry (SE), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). The SEM and SE data show that the thickness of the copper oxide films was about 170 nm. AFM images show that the surface roughness of copper oxide films was increased with increasing substrate temperature. As the substrate temperature increased, monoclinic CuO (111) peak appeared and the crystal size decreased while the monoclinic CuO (-111) peak was independent on the substrate temperature. The oxidation states of Cu 2p and O 1s resulted from XPS were not affected on the substrate temperature. The contact angle measurement was also studied and indicated that the surface of copper oxide thin films deposited high temperature has more hydrophobic surface than that of deposited at low temperature.

• 자원환경지질
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• 제19권1호
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• pp.57-66
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• 1986

The ore deposit of the Ohtani mine is one of representatives of plutonic tungsten-tin veins related genetically to acidic magmatism of Late Cretaceous in the Inner zone of Southwest Japan. Based on macrostructures of vein filling, three major mineralization stages are distinguished by major tectonic breaks. The constituents of ore minerals are scheelite, cassiterite, chalcopyrite, pyrrhotite, sphalerite, with small amounts of cubanite, stannite, galena, native bismuth, bismuthinite, arsenopyrite and pyrite. The relationship between the polymorphic variations of pyrrhotite and the kinds of the associated characteristic of ore mineral, in relation with hypogene mineralization, has been demonstrated. Pyrrhotite of stage I is predominantly of the hexagonal phase (Hpo>Mpo). Pyrrhotite of stage II is mainly of the monoclinic phase ($Hpo{\ll}Mpo$). Pyrrhotite of stage III is a single monoclinic phase ($Hpo{\ll}Mpo$). The compositions of the hexagonal pyrrhotite decrease in Fe content ranging from 47.44 atom % Fe in stage I to 46.88 atom % Fe in stage III.

• 한국세라믹학회지
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• 제20권3호
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• pp.217-226
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• 1983

Adquate amount of calcia was added to the regent-grade Zirconia body. Here the amount and the form of calcia were 7-21 mol% and regent-grade calcium cabonate respectively. The specimens were fired at 175$0^{\circ}C$ for 0, 3, 5 and 7 hours respectively. The phase Strength X-ray diffraction analysis and Scaning electron microscopy. The results were as follows (1) As the additive amount of calcia was increased the firing linear shrinkage apparent density compressive strength and modulus of rupture decreased but the apparent porosity increased. (2) The specimens soaked and containing calcia displayed the grain growth. (3) Monoclinic and cubic zirconia were seen in the sepcimens containing 7 mol% calcia. When without soaking the specimens containing 7-10 mol% calcia had the volume change by monoclinic$\rightleftharpoons$tetragonal transformation. (4) The lattice parameter increased according as the calcia additive was increased. The specimens containing above 19mol% calcia had the costant lattice parameter. The value of that was from 5.1264 to 5.1396 $\AA$ in the case of 7 hours soaking.

• 한국세라믹학회지
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• 제36권12호
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• pp.1390-1395
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• 1999

Zr(Y,Ce)O2 TZP ceramics were prepared by sintering compacts of 3 mol% Y2O3-TZP(3Y-TZP) powders with different amount of 12 mol% CeO2-TZP(12Ce-TZP) in air at 140$0^{\circ}C$ for 2 h. The phase changes microstructure and mechanical properties of Zr(Y. Ce)O2 TZP after hydrothermal aging(20$0^{\circ}C$ 5h) were investigated. Although an addition of 12Ce-TZP accelerated the grain growth of Zr(Y, Ce)O2 TZP it restrained the transformation of tetragonal to the monoclinic phase during aging. The degradation in mechanical properties of sintered bodies was governed by the formed monoclinic phase and chemical composition. Induced Vickers indentation crack was propagated intergranually. From SEM observation of the fracture surfaces the pull-out of individual grain was confirmed.

• 대한치과기공학회지
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• 제32권2호
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• pp.57-63
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• 2010

Purpose : This study aimed to find out the effects of treatments on the surface of Zirconia. Methods : To this end, we selected six treatments that have been used widely: steam cleaning, 2bar & 6bar sand blasting, grinding by green stone point, grinding by diamond bur, and grinding by diamond bur with water spray. Results : The results of our study showed that monoclinic rate increased from all six treatments. Monoclinic rate varied by treatments, ranged from 0.6% (steam cleaning) to 6.5% (6bar sand blasting). These values from all six treatments were below ISO 13356 standard, which is 25%. Also, we found that two treatments (green stone point and diamond bur) increased roughness of surface of Zirconia. Conclusion : This study concluded that phase changes of Zirconia were not significant by using six treatments we employed.

• 한국전기전자재료학회논문지
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• 제11권9호
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• pp.693-699
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• 1998

In this work $Cd_4GeS_6:Co^{2+}$(0.5mole%) single crystals were grown by the chemical transporting reactiov(CTR) method using high purity(6N) elements. The grown single crystals crystallized in a monoclinic structure(space group Cc). The direct optical energy gap of this single crystals was found to be 2.445eV at 300K and the temperature dependence of optical energy gap was fitted well to Varshni equation. But at temperatures lower than 70K an anomalous temperature dependence of the optical energy gap was obtained. This anomalous temperature dependence accored well with the anomalous temperature dependence of the unit cell volume. Also, the entropy, enthalpy and heat capacity were deduced from the temperature dependence of optical energy gaps.

• 한국전기전자재료학회논문지
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• 제16권4호
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• pp.272-279
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• 2003

In this work Zn$_4$GeSe$_{6}$ :CO$^{2+}$ single crystals were grown by the chemical transport reaction method in which the iodine was used as the transporting agent. The Zn$_4$GeSe$_{6}$ :CO$^{2+}$ single crystal was found to have a monoclinic structure. The optical absorption spectra of grown crystals were investigated using a temperature-controlled UV-VIS -NIR spectrophotometer. The temperature dependence of band-edge absorption was in a good agreement with the Varshni equation. The observed impurity absorption peaks could be explained as arising from the electron transition between energy levels of Co$^{2+}$ ion sited at the T$_{d}$ symmetry point.

• Bulletin of the Korean Chemical Society
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• 제30권11호
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• pp.2608-2612
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• 2009

The unequivocal solid-state structure and stereochemistry of the hetaryl leuco-TAM dye, 2,2’-(2-phenyl propane- 1,3-diylidene) bis(1,3,3- trimethylindoline) derivatives were established using X-ray single crystal analysis. The X-ray crystal analysis showed that the (Z, E)-isomers only formed stereoselectively, with a so-called “threebladed propeller” conformation, from the reaction of a Fischer base and benzaldehyde derivatives. These isomers were stacked in a juxtaposition to form a dimer or a double dimer, adopting either a triclinic, with P-1, or monoclinic crystal system with a space group P21/n in the unit cell of the crystal.

• 한국세라믹학회지
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• 제32권5호
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• pp.575-581
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• 1995

Zr0.94Y0.06O1.97 powder was synthesized by the ultrasonic spray pyrolysis with various concentrations of starting solution and the influence of powder characteristics on sintering behavior was investigated. Powders prepared at 75$0^{\circ}C$ were characterized as narrowly distributed submicron spherical particles, which were crystalline, nonagglomerated, and compositionally homogeneous. The changes in concentration from 0.01 to 01. mol/ι increased mean particle size from 0.24 to 0.38${\mu}{\textrm}{m}$ and decreased the specific surface area from 14.2 to 2.9$m^2$/g. The relative density of the specimen from the powders, prepared with the solution concentration of 0.01 mol/ι, was 98% after sintering for 2 hr at 1,45$0^{\circ}C$ and the monoclinic phase was observed after sintering at 1,55$0^{\circ}C$. As the concentration of starting solution was increased, the formation temperature of monoclinic phase was lowered.