• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2423-2426
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• 2012

• Bulletin of the Korean Chemical Society
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• 제26권5호
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• pp.755-762
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• 2005

A series of catalysts, NiO/$CeO_2-ZrO_2/WO_3$, for ethylene dimerization was prepared by the precipitation and impregnation methods. For NiO/$CeO_2-ZrO_2/WO_3$ sample, no diffraction line of nickel oxide was observed up to 40 wt%, indicating good dispersion of nickel oxide on the surface of catalyst. The hexagonal and monoclinic phases of $WO_3$ up to the calcination temperature of 500 ${^{\circ}C}$ were observed, whereas the hexagonal phase of WO3 completely was transformed into monoclinic phase of $WO_3$ at 600 ${^{\circ}C}$ and above. The role of $CeO_2$ in the catalysts was to form a thermally stable solid solution with zirconia and consequently to give high surface area and acidity. The catalytic activities for ethylene dimerization were correlated with the acidity of catalysts measured by the ammonia chemisorption method. 25-NiO/5-$CeO_2-ZrO_2/15-WO_3$ containing 25 wt% NiO, 15 wt% $WO_3$ and 5 mol% $CeO_2$, and calcined at 400 ${^{\circ}C}$ exhibited a maximum catalytic activity due to the effects of $WO_3$ modifying and $CeO_2$ doping.

• 한국결정학회지
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• 제18권1_2호
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• pp.1-6
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• 2007

유기금속 화합물 $C_{16}H_{35}B_{10}IrS_2Si$를 o-carborane으로 출발하여 $Cp^*Ir(S_2C_2B{10}H_{10})$을 합성하고, $Me_3SiCHN_2$를 가하여 합성하였다. X-선 회절법을 이용하여 $C_{16}H_{35}B_{10}IrS_2Si$ 화합물의 분자구조를 규명하였다. 이 화합물의 결정학적 자료는 monoclinic, space group $P2_1/n$, $a=10.1986(12)\;{\AA}$, $b=14.834(5)\;{\AA}$, $c=17.139\;{\AA}$, ${\beta}=92.24(2)^{\circ}$, Z=4, $V=2591.0(14)\;{\AA}^3$이다. 결정 구조는 직접법으로 해석하였으며, 완전행렬최소자승법을 정밀화 하였으며 5080개의 회절 반점에 대하여 최종 신뢰도 인자 R=0.053인 분자모형을 구하였다.

• 산업기술연구
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• 제20권A호
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• pp.247-256
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• 2000

Precursor gels with the composition of $xZrO_2{\cdot}(100-x)SiO_2$ systems (x=10, 20 and 30 mol%) were prepared by the sol-gel method. Kinetic parameters, such as activation energy, Avrami's exponent, n, and dimensionality crystal growth value, m, have been simultaneously calculated from the DTA data using Kissinger and Matusita equations. The crystallite size dependence on tetragonal to monoclinic transformation of $ZrO_2$ was investigated using XRD, in relation to the fracture toughness. The crystallization of tetragonal $ZrO_2$ occurred through 3-dimensional diffusion controlled growth(n=m=2) and the activation energy for crystallization was calculated using Kissinger and Matusita equations, as about $310{\sim}325{\pm}10kJ/mol$. The growth of $t-ZrO_2$, in proportion to the cube of radius, increased with increasing heating temperature and heat-treatment time. It was suggested that the diffusion of Zr4+ions by Ostwald ripening was rate-limiting process for the growth of $t-ZrO_2$ crystallite size. The fracture toughness of $xZrO_2{\cdot}(100-x)SiO_2$ systems glass ceramics increased with increasing crystallite size of $t-ZrO_2$. The fracture toughness of $30ZrO_2{\cdot}70SiO_2$ system glass ceramics heated at $1,100^{\circ}C$ for 5 h was $4.84Mpam^{1/2}$ at a critical crystaliite size of 40 nm.

• Molecules and Cells
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• 제19권2호
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• pp.219-222
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• 2005

The a-subunit of Escherichia coli tryptophan synthase (${\alpha}TS$), a component of the tryptophan synthase ${\alpha}_2{\beta}_2$ complex, is a monomeric 268-residues protein (Mr = 28,600). ${\alpha}TS$ by itself catalyzes the cleavage of indole-3-glycerol phosphate to glyceraldehyde-3-phosphate and indole, which is converted to tryptophan in tryptophan biosynthesis. Wild-type and P28L/Y173F double mutant ${\alpha}$-subunits were overexpressed in E. coli and crystallized at 298 K by the hanging-drop vapor-diffusion method. X-ray diffraction data were collected to $2.5{\AA}$ resolution from the wild-type crystals and to $1.8{\AA}$ from the crystals of the double mutant, since the latter produced better quality diffraction data. The wild-type crystals belonged to the monoclinic space group C2 ($a=155.64{\AA}$, $b=44.54{\AA}$, $c=71.53{\AA}$ and ${\beta}=96.39^{\circ}$) and the P28L/Y173F crystals to the monoclinic space group $P2_1$ ($a=71.09{\AA}$, b=52.70, $c=71.52{\AA}$ and ${\beta}=91.49^{\circ}$). The asymmetric unit of both structures contained two molecules of ${\alpha}TS$. Crystal volume per protein mass ($V_m$) and solvent content were $2.15{\AA}^3\;Da^{-1}$ and 42.95% for the wild-type and $2.34{\AA}^3\;Da^{-1}$ and 47.52% for the double mutant.

• 한국재료학회지
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• 제4권6호
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• pp.704-709
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• 1994

Crystal Structure and Magnetic Properties of $(LaS)_xCrS_2(x \approx 1.20$)가 1273K에서 $La_S_3$ , Cr, S의 혼합물의 반응으로부터 합성되었다. $(LaS)_xCrS_2( x\approx 1.20$)의 XRD회절 pattern은 monoclinic의 LaS-부격자, triclinic의 $CrS_{2}$-부격자와 그들의 초격자로서 해석되었다. 부격자의 온도의존성을 저온에서 X-선 회절분석으로 조사하였다. 77K~실온의 온도역에서 $(LaS)_xCrS_2(x \approx 1.20$)의 자기자화율을 Faraday balance법으로 측정하였다. $(LaS)_xCrS_2(x \approx 1.20$)은 실온 $\sigma$ -H plot에서 paramagnetic한 거동을 나타내었다. 관측된 유효자기 moment($\mu_{eff}$)는 $Cr^{3+}$을 spin-only에 의한 것과 $La^{3+}$을 spin-only와 orbital에 의한 것으로 계산할 경우 잘 일치되었다.

• 보존과학회지
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• 제32권2호
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• pp.109-121
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• 2016

나전대모칠기는 나전, 대모, 금속선 등을 사용하여 가식한 것으로 금속분을 기물 전체에 뿌려 전체적으로 밝은 색조로 표현한 특징을 가진다. 본 연구는 칠도막 단면을 광학현미경과 SEM-EDS 분석을 통하여 칠도막 단면에 나타나는 재료와 특성을 밝히고자 하였다. 그 결과, 목탄분과 토분을 섞은 바탕칠 위에 진사와 석황이 섞인 칠을 바르고, 그 위에 황동분을 뿌린 것으로 나타났다. 칠층에 섞여 있는 안료의 양은 소량으로 종래의 문양 표현에 쓰인 색칠과는 구별된다. 특히, 나전대모칠기의 칠층에서 진사와 석황의 두 가지 안료를 혼합하여 사용한 예를 확인할 수 있었다.

• 한국재료학회:학술대회논문집
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• 한국재료학회 2011년도 춘계학술발표대회
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• pp.241.1-241.1
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• 2011

Numerous possible applications for $ZrO_2$ nanotubes exist such as for catalyst support structures, for sensing or for applications as a solid state electrolyte. Especially, because of a large specific surface area, high efficiency for solid oxide fuel cell (SOFC) application at low temperature can be expected for nanotublar structures in even small size. A zirconium precursor, Tetrakis (ethylmethylamino) zirconium, TEMAZr and $H_2O$ oxidant were used to deposit$ZrO_2$ thin films on an anodized aluminum oxide (AAO) templates having sub-100nm cylindrical pores by atomic layer deposition (ALD) in the temperature range of 150~250$^{\circ}C$. The crystalline structures of as-prepared and post-annealed $ZrO_2$ nanotubes were characterized by x-ray diffraction and high-resolution transmission electron microscopy. The as-prepared samples at $150^{\circ}C$ and $200^{\circ}C$ were showed amorphous, whereas a mixed phase of tetragonal, monoclinic and amorphous polymorph was observed at $250^{\circ}C$. In the bulk, zirconia remains monoclinic phase up to $1,175^{\circ}C$, however, $ZrO_2$ nanotubes were showed tetragonal phase upon post thermal treatments merely at $400^{\circ}C$. This trend may be indicative of high-curvature surfaces of nanotubes and thereby the presence of intrinsic compressive strain. The amount of amorphous structures in the mixed phase as well as as-grown $ZrO_2$ nanotubes were also gradually decreased by subsequent heat treatment.

• 대한화학회지
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• 제62권1호
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• pp.14-18
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• 2018

The complexes $[Zn(L)(H_2O)_2]{\cdot}2NO_2$ (1) and $[Zn(L)(NO_3)_2]$ (2) (L = 3,14-dimethyl-2,6,13,17-tetraazatricyclo $[14,4,0^{1.18},0^{7.12}]$docosane) have been synthesized and structurally characterized. The compound 1 crystallizes in the monoclinic system $P2_1/c$ with a = 8.74650(10), b = 18.6880(3), c = $7.96680(10){\AA}$, ${\beta}=109.1920(10)^{\circ}$, $V=1229.84(3){\AA}^3$, Z = 2. The compound 2 crystallizes in the monoclinic system P1 with a = 8.1292(5), b = 8.9244(5), c = $9.1398(5){\AA}$, ${\alpha}=68.035(2)$, ${\beta}=70.109(2)$, ${\gamma}=75.649(3)^{\circ}$, $V=572.70(6){\AA}^3$, Z = 1. The crystal structures of the compounds 1 and 2 show a distorted octahedral coordination geometry around the zinc(II) ion, with four secondary amines and two oxygen atoms of the two water and two nitrate ligands at the axial position. The TGA behaviors of the complexes are significantly affected by the nature of the tetraaza macrocycle and the axial ligands.

• 한국결정학회지
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• 제15권1호
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• pp.24-28
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• 2004

X-선 회절법을 이용하여 $C_{12}H_{15}N_3O_3$의 분자 및 결정구조를 해석하였다. 이 결정의 결정계는 Monoclinic이고 공간군은 $P2_1/c$이며, 단위포 상수는 a = 12.9955(9) ${\AA}$, b = 7.7137(5) ${\AA}$, c = 13.4699(11) ${\AA}$, ${\beta}$ = 107.86(1)$^{\circ}$, V = 1285.2(1) ${\AA}^3$, T = 296 K, Z = 4, $D_c$ = 1.350 $Mgm^{-3}$이다. 회절반점들의 세기는 Enraf-Nonius CAD-4 Diffractometer로 얻었으며 Mo $K{\alpha}$선(${\lambda}$ = 1.71073 ${\AA}$)을 사용하였다. 분자구조는 Direct method로 풀었으며, $F_0\;>\;4{\sigma}(F_0)$인 1644개의 독립 회절 데이터에 대하여 최소자승법으로 193개의 변수를 정밀화하여 최종 신뢰도 값 R = 4.19%을 얻었다.