• Proceedings of the Korean Vacuum Society Conference
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• 2011.08a
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• pp.222-222
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• 2011

Titanium dioxide (TiO2) has a number of applications in optics and electronics due to its superior properties, such as physical and chemical stability, high refractive index, good transmission in vis and NIR regions, and high dielectric constant. Atomic layer deposition (ALD), also called atomic layer epitaxy, can be regarded as a special modification of the chemical vapor deposition method. ALD is a pulsed method in which the reactant vapors are alternately supplied onto the substrate. During each pulse, the precursors chemisorb or react with the surface groups. When the process conditions are suitably chosen, the film growth proceeds by alternate saturative surface reactions and is thus self-limiting. This makes it possible to cover even complex shaped objects with a uniform film. It is also possible to control the film thickness accurately simply by controlling the number of pulsing cycles repeated. We have investigated the ALD of TiO2 at 100$^{\circ}C$ using precursors titanium tetra-isopropoxide (TTIP) and H2O on -O, -OH terminated Si surface by in situ X-ray photoemission spectroscopy. ALD reactions with TTIP were performed on the H2O-dosed Si substrate at 100$^{\circ}C$, where one cycle was completed. The number of ALD cycles was increased by repeated deposition of H2O and TTIP at 100$^{\circ}C$. After precursor exposure, the samples were transferred under vacuum from the reaction chamber to the UHV chamber at room temperature for in situ XPS analysis. The XPS instrument included a hemispherical analyzer (ALPHA 110) and a monochromatic X-ray source generated by exciting Al K${\alpha}$ radiation (h${\nu}$=1486.6 eV).

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.28 no.2
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• pp.142-147
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• 2015

The artificial light sources for growth of plant are usually high-pressure sodium lamp, metal haloids lamp, and fluorescent light; however, these light sources have relatively weaker Red and Blue lights that are necessary for growth of plants. Especially the effect of Photosynthetic Photon Flux Density (PPFD) is pointed out as the weakness. Meanwhile, LED light source can be selected by specific wavelength to greatly improve the effect of PPFD. In this regard, this paper aims to investigate the promotion of plant growth by measuring photosynthetic photon flux density (hereafter referred to as PPFD) according to changes in light quality of the LED light sources. Towards this end, LED light sources for plant growth were produced with 4 kinds of mono-chromatic lights and 6 kinds of combined lights by mixing red, blue, green and white lights. A comparative analysis was conducted to investigate the effects of optical properties and PPFD on plants (green leaf lettuce) using the produced light sources. The results monochromatic light has fastest growth rate, but plant growth conditions have poor. This being so, mixed light is suitable for the green leaf lettuce.

• Bulletin of the Korean Chemical Society
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• v.35 no.10
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• pp.3052-3058
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• 2014

In this article, we have designed and synthesized a novel donor-${\pi}$-acceptor (D-${\pi}$-A) type porphyrin-based sensitizer (denoted UI-5), in which a carboxyl anchoring group and a 9,9-dimethyl fluorene were introduced at the meso-positions of porphyrin ring via phenylethynyl and ethynyl bridging units, respectively. Long alkoxy chains in ortho-positions of the phenyls were supposed to reduce the degree of dye aggregation, which tends to affect electron injection yield in a photovoltaic cell. The cyclic voltammetry was employed to determine the band gap of UI-5 to be 1.41 eV based on the HOMO and LUMO energy levels, which were estimated by the onset oxidation and reduction potentials. The incident monochromatic photon-to-current conversion efficiency of the UI-5 DSSC assembled with double-layer (20 nm-sized $TiO_2$/400 nm-sized $TiO_2$) film electrodes appeared lower upon overall ranges of the excitation wavelengths, but exhibited a higher value over the NIR ranges (${\lambda}$ = 650-700 nm) compared to the common reference sensitizer N719. The UI-5-sensitized cell yielded a relatively poor device performance with an overall conversion efficiency of 0.74% with a short circuit photocurrent density of $3.05mA/cm^2$, an open circuit voltage of 0.54 mV and a fill factor of 0.44 under the standard global air mass (AM 1.5) solar conditions. However, our report about the synthesis and the photovoltaic characteristics of a porphyrin-based sensitizer in a D-${\pi}$-A structure demonstrated a significant complex relationship between the sensitizer structure and the cell performance.

• Restorative Dentistry and Endodontics
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• v.12 no.1
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• pp.65-76
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• 1986

Carious dentin can be classified, on the basis of their clinical characteristics, into three groups; sound, sclerotic and active carious dentin. Active carious dentin differs from sclerotic dentin by its abscence of variable bacteria within tubles and amount of chemical content. But the apatite molecules of active carious dentin are not fully studied. The purpose of this study was to observed the physico-chemical characteristics of deep carious dentin. The samples of sound, sclerotic and active carious dentin were obtained respectively from 300 freshly extracted carious teeth. Bacterial-rich zone of superficial soft dentin layer was removed with hand instruments from all samples in advance. The samples were powdered and sieved (200 mesh) before analyses. Identification and estimation of the crystallinity of the samples were carried with X-ray diffraction and infrared absorption analyses. Measurements were made on a Rigaku Denki (Rigaku, geiger flex III, Japan) X-ray diffractometer with Cu-target at 30 Kv, 30 mA and are traced on a monochromatic tracer. Infrared absorption analysis was made on FT-IR spectrophometer (Nicolet Instrument Co.) using KBr pellets containing the samples and was recorded on data process (Model IR-80. Nicolet Instrument, Co). The following conclusions were as follows; 1. The nature of the main inorganic structure of sound, sclerotic and active carious dentin proved to be hydroxyapatite. 2. It was difficult to determine the identification due to their crystallinity of sound, sclerotic and active carious dentin. But sound dentin was the highest in crystallinity among them. 3. The magnesium whitlockite was to be found in active carious dentin, but not in sound and sclerotic dentin. 4. The carbonate content was highest in sound dentin, but the lowest was in active carious dentin.

• Journal of Ginseng Research
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• v.36 no.2
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• pp.198-204
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• 2012

An light-emitting diode (LED)-based light source was used as a monochromatic light source to determine the responses of raw ginseng roots (Panax ginseng Meyer) to specific emission spectra with respect to the production of ginsenosides. The ginsenoside content in the ginseng roots changed in response to the LED light treatments at $25^{\circ}C$ relative to the levels in the control roots that were treated in the dark or at $4^{\circ}C$ for 7 d. Ginseng roots were exposed to LEDs with four different peak emission wavelengths, 380, 450, 470, and 660 nm, in closed compartments. Compared with the control $4^{\circ}C$-treated roots, roots that were treated with 450 and 470 nm light showed a significantly increased production of ginsenosides (p<0.05), with increases of 64.9% and 74.1%, respectively. The contents of the ginsenosides $Rb_2$, Rc, and $Rg_1$ were significantly higher (p<0.05) in the 450 and 470 nm-treated root samples. The ratio of protopanaxadiol ginsenosides ($Rb_1$, $Rb_2$, Rc, and Rd) to protopanaxatriol ginsenosides ($Rb_1$, $Rb_2$, Re, and Rf) was significantly higher (p<0.05) in the 450 and 470 nm-treated root samples than in the control $4^{\circ}C$-treated roots. This is the first report that demonstrates the increase and conversion of ginsenosides in raw ginseng roots in response to exposure to LED light.

• The Bulletin of The Korean Astronomical Society
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• v.38 no.1
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• pp.43.2-43.2
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• 2013

The local environmental effects on the triggering of active galactic nucleus(AGN) activity has been studied with many authors, but there still be controversy. We perform statistical analysis for nearby(0.01 < z < 0.05) volume limited(Mr < -19) samples with visual inspection based on Sloan Digital Sky Survey Data Release7. We inspect ~60,000 galaxy images visually to find peculiar objects which show not only ongoing merging features and tidal features, but also post merging features like ring or shell structures. We found that these peculiar features were shown at least 2 times more frequently among AGN host galaxies than non AGN galaxies, and this trend was still visible when galaxy properties such as color or stellar mass are fixed. Furthermore, L[OIII] and L(Ha) of peculiar galaxies are found to be more increased than those of normal galaxies. In order to ensure this results, we also checked it for a smaller subsample with ~2mag deeper monochromatic images provided from SDSS Stripe82 database, and found consistent results. At last, we perform the same work for pair(r_p<80kpc/h, delta_v<200km/s) systems. Because of some pair systems which do not interact gravitationally in actuality but fulfill the criteria for identification of pair system, the trends are found to be slightly weaker. We also found that line luminosities are increased consistently as projected distance between central and companion galaxy decreased, and as companion color gets bluer. Overall, the results of this study tell us that the local environment of galaxies affect the frequency as well as the strength of AGN activity. Local environmental effects, however, may not be the dominant triggering mechanism for AGN activity since the majority of peculiar galaxies are non AGN galaxies.

• Korean Journal of Optics and Photonics
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• v.16 no.1
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• pp.63-70
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• 2005

We propose a method for evaluating the image quality of color liquid crystal display(LCD) monitors by using the polychromatic modulation transfer function(PMTF), which is calculated from the modulation transfer function(MTF) weighted by the overall color response of the system including the test LCD monitor. We confirm that experimental results using the PMTF agree well with simulated results of the PMTF of a color LCD monitor by using three bar targets with different amplitudes and three elementary colors such as red(R), green(G), and blue(B). As a results, we should choose the PMTF instead of the white color MTF or monochromatic MTF in order to evaluate correctly the image quality of color LCD monitors.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.8 no.2
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• pp.146-150
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• 1996

The waves are most important dynamical factors for the analyses of structural stability and topographical changes on coastal engineering field. However, wind-generated waves are very irregular in shape and transformed through refraction, diffraction and shoaling when they propagate into shallow water where bottom topography and water depth vary significantly. Recently, Vincent and Briggs (1989) reported hydraulic model experiments for the transformation of monochromatic and directionally-spread irregular waves passing over a submerged elliptical mound. They concluded that for the case of combined refraction-diffraction of waves by a shoal, the propagation characteristics of the irregular and equivalent regular wave conditions can be vastly different. On the irregular wave transformation have been made theoretical and numerical studies for several years. Although theoretical and laboratory studies on wave transformation have progressed considerably, field measurement and comparison of numerical results with related theories are still necessary for the prediction of the phenomena in reality. In this study, field measurement of both incident and transformed waves in Youngil Bay were made using various kinds of equipments, and numerical computations were made on the transformed frequency spectra of large waves propagating over the shoal using Chae and Jeong's (1992) elliptic model. It is shown that this model results agree very well with field data, and thus the applicability of the model is now validated.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.27 no.6
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• pp.424-433
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• 2015

In this study, the wave force distribution acting on a semi-infinite and vertical-type long structure is investigated considering diffraction. An analytical solution of the wave force acting on long structures is also suggested in this study. The wave forces on long structures are evaluated for monochromatic, uni-directional random, and multi-directional random waves. Diffraction effects in front of the breakwater and on the lee side of the breakwater are considered. The wave force on a long structure becomes zero when the relative length of the breakwater (1/L) is zero. The diffraction effects are relatively strong when the relative length of the breakwater is less than 1.0, and the wave forces decrease greatly for long structure when the relative length of the breakwater is larger than 0.5. Therefore, it is necessary to consider diffraction effects when the relative length of the breakwater is less than 1.0, and the relative length of the breakwater must be at least 0.5 in order to obtain a reduction of wave force on long structures.

• Economic and Environmental Geology
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• v.49 no.1
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• pp.23-30
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• 2016

Powder samples of natural lawsonite (Ca-lawsonite, $CaAl_2Si_2O_7(OH)_2{\cdot}H_2O$) was studied structurally up to 8 GPa at room temperature using monochromatic synchrotron X-ray powder diffraction and a diamond anvil cell (DAC) with a methanol : ethanol : water (16 : 3 : 1 by volume) mixture solution as a penetrating pressure transmitting medium (PTM). Upon pressure increase, lawsonite does not show any apparent pressure induced expansion (PIE) or phase transition. Pressure-volume data were fitted to a second-order Birch-Murnaghan equation of state using a fixed pressure derivative of 4 leading to a bulk modulus ($B_0$) of 146(6) GPa. This compression is further characterized to be isotropic with calculated linear compressibilities of ${\beta}^a=0.0022GPa^{-1}$, ${\beta}^b=0.0024GPa^{-1}$, and ${\beta}^c=0.0020GPa^{-1}$.