• Title/Summary/Keyword: Molten salts

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Study of the Al-coating on the STS 316L Stainless Steel by Pulse Plating in the Molten Salts at Room Temperature (펄스 도금법을 이용한 STS 316L 스테인리스강 상의 저온 염욕 알루미늄 코팅에 관한 연구)

  • 정세진;조계현
    • Journal of the Korean institute of surface engineering
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    • v.35 no.1
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    • pp.17-32
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    • 2002
  • Electroplating methods by molten salts and non-aqueous melts were employed for aluminium coating on STS 316L stainless steel. After coated with Ni or non-coated surface on stainless steel, Al pulse plating was carried out in two different types of electrolytes at room temperature. The Al layer from $AlCl_3$-TMPAC melts could not obtain appreciable thickness for engineering application due to chemical reactions between deposits and moisture of air. However, The Al coating by pulse plating in the Ethylbenzene-Toluene-$AlBr_3$ systems was found to be solid coating layer with a few $\mu\textrm{m}$ scale. The conductivity of Ethylbenzene-Toluene-$AlBr_3$ electrolyte was as functions of time and agitation. By seven days exposure after mixing of the electrolyte, Al-deposited layer shows uniform and near by pore-free with high current density (higher than 30mA/$\textrm{cm}^2$). The roughness and imperfection of coating layer were decreased with a increasing agitation speed. It was found that the optimum condition for the Al pulse plating on the 316L stainless steel was a 400mA peak current, duty cycle, $t_{on}$ $t_{ off}$=3ms/1ms, and a current density of 30mA/$\textrm{cm}^2$.

Interaction between UN and CdCl2 in molten LiCl-KCl eutectic. II. Experiment at 1023 K

  • Zhitkov, Alexander;Potapov, Alexei;Karimov, Kirill;Kholkina, Anna;Shishkin, Vladimir;Dedyukhin, Alexander;Zaykov, Yury
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.653-660
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    • 2022
  • The interaction between UN and CdCl2 in the LiCl-KCl molten eutectic was studied at 1023 K. The chlorination was monitored by sampling and recording the redox potential of the medium. At 1023 K the chlorination of UN with cadmium chloride in the molten LiCl-KCl eutectic proceeds completely and results in the formation of uranium chlorides. The melts of the LiCl-KCl-UCl3 or LiCl-KCl-UCl4 compositions can be obtained by the end of experiment depending on the presence of metallic cadmium in the reaction zone. The higher the concentration of the chlorinating agent, the faster the reaction rate. At [CdCl2]/[UN] = 1.65 (10% excess) the reaction proceeds to completion in about 7.5 h. At [CdCl2]/[UN] = 7 the complete chlorination takes 2.5-3 h.

Uncertainty analysis of heat transfer of TMSR-SF0 simulator

  • Jiajun Wang;Ye Dai;Yang Zou;Hongjie Xu
    • Nuclear Engineering and Technology
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    • v.56 no.2
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    • pp.762-769
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    • 2024
  • The TMSR-SF0 simulator is an integral effect thermal-hydraulic experimental system for the development of thorium molten salt reactor (TMSR) program in China. The simulator has two heat transport loops with liquid FLiNaK. In literature, the 95% level confidence uncertainties of the thermophysical properties of FLiNaK are recommended, and the uncertainties of density, heat capacity, thermal conductivity and viscosity are ±2%, ±10, ±10% and ±10% respectively. In order to investigate the effects of thermophysical properties uncertainties on the molten salt heat transport system, the uncertainty and sensitivity analysis of the heat transfer characteristics of the simulator system are carried out on a RELAP5 model. The uncertainties of thermophysical properties are incorporated in simulation model and the Monte Carlo sampling method is used to propagate the input uncertainties through the model. The simulation results indicate that the uncertainty propagated to core outlet temperature is about ±10 ℃ with a confidence level of 95% in a steady-state operation condition. The result should be noted in the design, operation and code validation of molten salt reactor. In addition, more experimental data is necessary for quantifying the uncertainty of thermophysical properties of molten salts.

Characteristics of Ceramic Separator Impregnated by Molten Salt for Thermal Batteries (열전지용 세라믹 분리막의 용융염 전해질 함침 특성)

  • Kang, Seung-Ho;Im, Chae-Nam;Park, Byung-Jun;Cho, Sung-Baek;Cheong, Hae-Won;Yi, Junsin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.7
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    • pp.467-472
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    • 2015
  • Thermal batteries are primary power sources for military applications requiring high reliability, robustness and long storage life. Conventional electrodes for thermal batteries are prepared by compacting powder mixtures into pellets. Separator is composed of halide mixture, such as LiCl-KCl eutectic salt, blended with MgO to immobilize the molten salt. In order to increase the power density and energy density, the resistance of electrolyte should be reduced because the resistance of electrolyte is predominant in thermal batteries. In this study, wetting behaviors and impregnation weight of molten salts as well as the micro structures of ceramic felt were investigated to be applicable to thin electrolyte. Discharge performances of single cell with the ceramic separator impregnated by molten salt were evaluated also. Zirconia felt with high porosity and large pore outperformed alumina felt in wetting characteristics and molten salt impregnation as well as discharge performances. Based on the results of this study, ceramic felt separator impregnated with molten salt have revealed as an alternative of conventional thick MgO based separator with no conspicuous sign of thermal runaway by short circuit.

Corrosion Behavior and Effect of Alloying Elements of Fe-base and Ni-base Superalloys on Hot Molten Salt (고온 용융염에서 Fe기 및 Ni기 초합금의 부식거동 및 합금원소의 영향)

  • Jo, Su-Haeng;Jang, Jun-Seon;Jeong, Myeong-Su;O, Seung-Cheol;Sin, Yeong-Jun
    • Korean Journal of Materials Research
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    • v.9 no.10
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    • pp.985-991
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    • 1999
  • Corrosion behaviors of Incoloy 800H, KSA(Kaeri Superalloy)-6, Inconel 600 and Hastelloy C-276 in molten salts were investigated in the temperature range of 650 ~ $850^{\circ}C$. Due to $\textrm{Li}_{2}\textrm{O}$-induced basic fluxing mechanism, the corrosion rates of the alloys in mixed molten salt of LiC1-$\textrm{Li}_{2}\textrm{O}$ were significantly higher than those in molten salt of LiCl. In the mixed molten salt, Fe-base alloys showed higher corrosion resistance than the Ni-base alloys. and Hastelloy C-276 with high Mo and W contents exhibited the highest corrosion rate among the examined alloys. The single layer of $\textrm{LiCrO}_{2}$ was formed in molten salt of LiCl and two phase structure of a scale consisted of oxides and Ni was formed in the mixed molten salt.

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