• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.11
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• pp.1000-1003
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• 2007

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the molten carbonate fuel cell which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. One of the material problems is the severe corrosion of the metallic components, such as the separator. The effect of coating and annealing treatment on the corrosion for SUS 304 and SUS 430 which are the candidate materials for molten carbonate fuel cell hardware has been investigated in molten carbonate at $650^{\circ}C$ by using steady state polarization and electrochemical impedance spectroscopy method. It was found that the corrosion current of these SUS 304 and SUS 430 decreased with coating and annealing treatment.

• Nuclear Engineering and Technology
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• v.55 no.11
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• pp.4266-4273
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• 2023

In a severe reactor accident, a crust will form on the surface of the molten material during the core melting process. The crust will have a contact melting with the internal components of the reactor. In this paper, the contact melting process of the molten material on the austenitic stainless steel plate bundles is studied. The contact melting model of parabolic molten material on the plate bundles is proposed, and the rule and main effect factors of the contact melting are analyzed. The results show that the melting velocity is proportional to the slope of the paraboloid, the heat flux and the distance between two plates D. The influence of melt gravity and the plate width on melting velocity is negligible. The thickness of the molten liquid film is proportional to the heat flux and plate width, and it is inversely proportional to the gravity. With the increase of D, the liquid film thickness decreases at first and then increases gradually. The liquid film thickness has a minimum against D. When the width of the plate is small, the width of the plate is the main factor affecting the thickness of the liquid film. The parameters are coupled with each other. In a severe reactor accident, the wider internal components of reactor, which can increase the thickness of the melting liquid film and reduce the net input heat flux from the molten material to the components, are the effective measures to delay the melting process.

• Journal of Mechanical Science and Technology
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• v.14 no.5
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• pp.553-561
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• 2000

This paper presents a numerical model of multi phase flow of the mixtures of molten material-liquid-vapor, particularly in thermal nonequilibrium. It is a two-dimensional, transient, three-fluid model in Eulerian coordinates. The equations are solved numerically using the finite difference method that implicitly couples the rates of phase changes, momentum, and energy exchange to determine the pressure, density, and velocity fields. To examine the model's ability to predict an experimental data, calculations have been performed for tests of pouring hot particles and molten material into a water pool. The predictions show good agreement with the experimental data. It appears, however, that the interfacial heat transfer and breakup of molten material need improved models that can be applied to such high temperature, high pressure, multi phase flow conditions.

• Transactions on Electrical and Electronic Materials
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• v.8 no.6
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• pp.283-285
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• 2007

The molten carbonate fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. However, the molten carbonate fuel cell which use strongly corrosive molten carbonate at $650^{\circ}C$ have many problem. Systematic investigation on corrosion behavior of stainless steels has been done 62 mole% $Li_2CO_3$ and 38 mole% $K_2CO_3$ melt at 923 K by using steady-state polarization method and electrochemical impedance spectroscopy method. It was found that SUS 310L and Al coating specimen may be the best choice among the alloys tested in this study for molten carbonate fuel cell component material.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3491-3496
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• 2007

If a molten core is released from a reactor vessel into a reactor cavity during a severe accident, an important safety issue of coolability of the molten core from top-flooding and concrete ablation due to a molten core concrete interaction (MCCI) is still unresolved. The released molten core debris would attack the concrete wall and basemat of the reactor cavity, which will lead to inevitable concrete decompositions and possible radiological releases. In a OECD/MCCI project scheduled for 4 years from 2002. 1 to 2005. 12, a series of tests were performed to secure the data for cooling the molten core spread out at the reactor cavity and for the 2-D long-term core concrete interaction (CCI). The tests included not only separate effect tests such as a melt eruption, water ingression, and crust failure tests with a prototypic material but also 2-D CCI tests with a prototypic material under dry and flooded cavity conditions. The paper deals with the transient simulations on the CCI-2 test by using a severe accident analysis code, CORQUENCH, which was developed at Argonne National Laboratory (ANL). Similar simulations had been already per for me d by using MELCOR 1.8.5 code. Unlike the MELCOR 1.8.5, the CORQUENCH includes a melt eruption mode I and a newly developed water ingression model based on the water ingression tests under the OECD/MCCI project. In order to adjust the geometrical differences between the CCI-2 test (rectangular geometry) and the simulations (cylindrical geometry), the same scaling methodology as used in the MELCOR simulation was applied. For the direct comparison of the simulation results, the same inputs for the MELCOR simulation were used. The simulation results were compared with the previous results by using MELCOR 1.8.5.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.5
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• pp.331-337
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• 2017

Thermal batteries, reserve power source, is activated by melting of molten salt at the temperature range of $350{\sim}550^{\circ}C$. To immobile the molten state electrolyte when the thermal battery is activated, the binder must be added in electrolyte. Usually, molten salts include 30~40 wt% of MgO binder to ensure electrical insulation as well as safety. However, the conventional MgO binder tends to increase ionic conductive resistance and thus the inclusion of the binder increases the total impedance of the battery. This paper mainly focused on the study of yttria stabilized zirconia (YSZ) as an alternative binder for molten salt. The chemical stability between the molten salt and YSZ is measured by XRD and DSC. And the sufficient path for ionic conduction on molten salt could be confirmed by the enhanced wetting behavior and the enlarged pore size of YSZ. The electrochemical properties were analyzed using single cell tests so that it showed the outstanding performance than that using MgO binder.

• Proceedings of the Korean Nuclear Society Conference
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• 1998.05a
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• pp.812-817
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• 1998

Experimental studies on heat transfer and solidification of the molten metal pool with overlying coolant with boiling were performed The simulant molten pool material is tin (Sn) with the melting temperature of 232$^{\circ}C$. Demineralized water and R113 are used as the working coolant. This work examines the crust formation and the heat transfer characteristics of the molten metal pool immersed in the boiling coolant. The Nusselt number and the Rayleigh number in the molten metal Pool region of this study are compared between the water coolant case and the R113 coolant case. The experimental results or the water coolant are higher than those for R113. Also, the empirical relationship of the Nusselt number and the Rayleigh number is compared with the literature correlations measure from mercury. The present experimental results are higher than the literature correlations. It is believed that this discrepancy is caused by the effect of heat loss to the environment on the natural convection heat transfer in the molten pool.

• Journal of Welding and Joining
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• v.32 no.3
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• pp.68-73
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• 2014

Among through silicon via (TSV) technologies, for replacing Cu filling method, the method of molten solder filling has been proposed to reduce filling cost and filling time. However, because Sn alloy which has a high coefficient of thermal expansion (CTE) than Cu, CTE mismatch between Si and molten solder induced higher thermal stress than Cu filling method. This thermal stress can deteriorate reliability of TSV by forming defects like void, crack and so on. Therefore, we fabricated SiC composite filling material which had a low CTE for reducing thermal stress in TSV. To add SiC nano particles to molten solder, ball-typed SiC clusters, which were formed with Sn powders and SiC nano particles by ball mill process, put into molten Sn and then, nano particle-dispersed SiC composite filling material was produced. In the case of 1 wt.% of SiC particle, the CTE showed a lowest value which was a $14.8ppm/^{\circ}C$ and this value was lower than CTE of Cu. Up to 1 wt.% of SiC particle, Young's modulus increased as wt.% of SiC particle increased. And also, we observed cross-sectioned TSV which was filled with 1 wt.% of SiC particle and we confirmed a possibility of SiC composite material as a TSV filling material.

• Journal of Welding and Joining
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• v.19 no.5
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• pp.512-519
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• 2001

Sink roll has been used in molten Zn-0.2%Al alloy bath of continuous galvanizing line in sinking and stabilizing process of the steel strip in molten metal bath. In this process, although the scraper scraps off the sink roll surface, the dross compounds is builded up on the sink roll surface and the life time of the sink roll is shorten by the dross compounds. The present study was investigated the application of the spray coating layer on sink roll body for improving durability In molten Zn-0.2%Al alloy. Through the durability tests in molten Zn-0.2%Al alloy with various ceramic and cermet coating layer, the optimum bond and top coating material was obtained. As the results, the system of STS430F base metal, WC-l7Co bond and $ZrO_2-SiO_2$ top coating was clarified to be the best quality of durability in molten Zn-0.2%Al alloy.

• Journal of the Korean Ceramic Society
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• v.35 no.1
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• pp.33-40
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• 1998

A MgO-CaO-based coating material for ferrous melt refining is applied to the tundish operation for mol-ten steel having low carbon. The changes in the total oxygen content insoluble aluminum content and the content of inclusions in molten steel during tundish operation were measured at the pouring part strand of tundish and mold. On the basis of the experimental results the interfacial reaction occurring between the coating materials and the molten steel in tundish was discussed and compared with the theoretical con-sideration. It is concluded that interfacial reaction is not active at the strand part of tundish but is active at the pouring part because of the turbulent flow in the molten steel.