• Journal of Welding and Joining
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• v.23 no.2
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• pp.47-51
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• 2005

Rapid Prototyping (RP) technology has helped successfully to reduce time and costs since first emerged in 1986. Recently, RP using functional materials like as metal have been researched. However RP using molten metal and brazing material have been struggling to resolve several drawbacks, such as dimensional inaccuracy, poor surface finish and post finishing because occurring shrinkage and warpage at cooling. So, the purpose of this study is to develop a new RP technique using sheet metal and projection welding for reducing several drawbacks in occurring RP using molten metal. And optimum process variables were determined using desist of experiment(DOE).

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.604-605
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• 2006

Recently the Marangoni convention is supposed to be an important phenomenon that significantly affects the solidification. For understanding the Marangoni convection mechanism, visualizing the convention phenomenon of molten tin with ultrasonic has been conducted. This paper reports developing a tracer material of micro metal balloon that is used in the molten system. We have succeeded in coating the surface of Shirasu-ballons with nickel by plating process. The obtained metal balloon is spherical and some characterizations were conducted.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2019.05a
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• pp.63-64
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• 2019

• Bulletin of the Korean Chemical Society
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• v.33 no.3
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• pp.881-884
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• 2012

We report a quantum chemical study of an extremely efficient nucleophilic aromatic fluorination in molten salts. We describe that the mechanism involves solvent anion interacting with the ion pair nucleophile $M^+F^-$(M = Na, K, Rb, Cs) to accelerate the reaction. We show that our proposed mechanism may well explain the excellent efficiency of molten salts for SNAr reactions, the relative efficacy of the metal cations, and also the observed large difference in rate constants in two molten salts $(n-C_4H_9)_4N^+\;CX_3SO_3^-$, (X=H, F) with slightly different sidechain ($-CH_3$ vs. $-CF_3$).

• Journal of the Korean institute of surface engineering
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• v.31 no.6
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• pp.371-378
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• 1998

The zind bate contaminated in the hot dip galvannealed operation was successfully by appling the dross formation mechanism ; the Fe content was lowered from 0.028% to 0.011% and the dress size was decreased from 15~20$\mu\textrm{m}$ to under 3$\mu\textrm{m}$. The cooled metal from CGL zinc bath during operation of the galvannealed steel strip was remelted in graphite crucible at the lab and agitated after increasing Al content from 0.14% to 0.16% with decreasing the molten metal temperature from $470^{\circ}C$to $445^{\circ}C$. The agitating was done by agitator and nitrogen. The molten was analyed by SEM and EDS. It was considered that the Fe and the bottom dross($FeZN_7$) could react with aluminium to from the float dress($Fe_2Al_5$) according to the molten metal temperature down and the float dress rise to the surface of the zine bath. So the Fe and dross in the bath could be romoved out of the bath. It was confirmed that the proper purication conditions of GA zine bath is 0.02% of Al increasing, bath temperature down from $460^{\circ}C$ to $450^{\circ}C$and agitator and nitrogen.

• Journal of Sensor Science and Technology
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• v.9 no.2
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• pp.141-145
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• 2000

In order to measure the thickness of the slag layer on the molten metal in the melting vessels for steel making foundaries, we manufactured the slag-thickness measuring system consisting of the probe and its driving system, which is based on the principle of detecting the change in the electrical resistivity. Experimental results show that there is a very wide difference of the electrical resistivity by the order of about $10^3$ between the molten metal and the hot slag and, hence, the air/slag and slag/molten metal interface can be exactly detected with the use of the probe which can be moved toward the melt. Therefore, it can be concluded that the proposed scheme of the slag measurement system in this study is Proven to be excellent in its efficiency and accuracy.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.3 no.2
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• pp.85-93
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• 2005

Isotopes of alkali and alkaline earth metals (AM and AEM) are the main contributors to the heat load and the radiotoxicity of spent fuel (SF) . These components are separated from the SF and dissolved in a molten LiCl in an electrolytic reduction process. A mass transfer model is developed to describe the diffusion behavior of Cs, Sr, and Ba in the SF into the molten salt. The model is an analytical solution of Fick's second law of diffusion for a cylinder which is the shape of a cathode in the electrolytic reduction process. And the model is also applied to depict the concentration profile of the oxygen ion which is produced by the electrolysis of Li$_{2}$O. The regressed diffusion coefficients of the model correlating the experimentally measured data are evaluated to be greater in the order of Ba, Cs, and Sr for the metal ions and the diffusion of the oxygen ion is slower than the metal ions which implies that different mechanisms govern the diffusion of the metal ions and the oxygen ions in a molten LiCl.

• Journal of Korea Foundry Society
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• v.31 no.3
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• pp.124-129
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• 2011

We applied two numerical schemes to improve accuracy of the solution in the flow simulation of molten metal. One method is Piecewise Linear Interface Calculation (PLIC) method and the other is Donor-Acceptor (D-A) method. In the present work, we have tested simple problems to verify the module of the interface reconstruction algorithms. After validations, accuracy and efficiency of these two methods have compared by simulating various real products. On the numerical simulation of free surface flow, it is possible for PLIC method to track very accurately the interface between phases. PLIC method, however, has the weak point where a lot of computational time hangs, though it shows the more accurate interface reconstruction. Donor-Acceptor method has enough effectiveness in the macro observation of mold filling sequence though it shows the inferior accuracy.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.11b
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• pp.39-50
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• 2005

Electrolytic reduction of uranium oxide to uranium metal was studied in a $LiCl-Li_{2}O$ molten salt system. The reduction mechanism of the uranium oxide to a uranium metal has been studied by means of a cyclic voltammetry. Effects of the layer thickness of the uranium oxide and the thickness of the MgO on the overpotential of the cathode and the anode were investigated by means of a chronopotentiometry. From the cyclic voltamograms, the decomposition potentials of the metal oxides are the determining factors for the mechanism of the reduction of the uranium oxide in a $LiCl-3\;wt{\%} Li_{2}O$ molten salt and the two mechanisms of the electrolytic reduction were considered with regards to the applied cathode potential. In the chronopotentiograms, the exchange current and the transfer coefficient based on the Tafel behavior were obtained with regard to the layer thickness of the uranium oxide which is loaded into the porous MgO membrane and the thickness of the porous MgO membrane. The maximum allowable currents for the changes of the layer thickness of the uranium oxide and the thickness of the MgO membrane were also obtained from the limiting potential which is the decomposition potential of LiCl.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.279-284
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• 2005

The casting defects that are caused by molten metal were cold shut formation, entrapment of air, gas, and inclusion. But the control of casting defects has been based on the experience of the foundry engineers. In this thesis, the computer simulation analyzed the flow of molten metal. The quantitative analyses which proposed the effective mold design was executed Flow patterns of 0.15-0.16m/s molten metal in 15 mm thin plate casting were investigated in order to optimize die-casting process. As increasing ingate velocity in thin plate casting, cold shot was decreased. The parameters of runner shape that affected on the optimized conditions that was calculated with simple equation were investigated. These die casting process control techniques of automobile valve body mid-plate have achieved good agreement with the experimental data of tensile strength, hardness test, and material structure photographies satisfactory results.