• Title/Summary/Keyword: Molten Lead

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Molten Metal Inkjet System (용융 메탈 잉크젯 시스템)

  • Lee Taik-Min;Kang Tae-Goo;Yang Jeong-Soon;Jo Jeong-Dai;Kim Kwang-Young;Kim Dong-Soo
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2006.05a
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    • pp.585-586
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    • 2006
  • In this paper, we present a design, analysis, fabrication and performance test of the novel DoD metal-jet system for application to the high-density and high-temperature-melting materials. Based on the theoretical analysis, we design the metal-jet print head system and fabricate the metal-jet system, which can eject the droplet of lead-free metal solder in the high-temperature. In the experimental test, we set up the test apparatus for visualization of the droplet ejection and measure the Ejected droplet volume and velocity. As a result, the diameter, volume and the velocity of the ejected droplet are about $65-70{\mu}m$, 145-180 pl and 4m/sec. We also fabricate vertical and inclined 3D micro column structures using the present molten metal inkjet system. The measured geometries of the micro column structures are about height of $2,100{\mu}m$, diameter of $200{\mu}m$ and aspect ratio of 10.5 for vertical micro column and $1,400{\mu}m$ of height and $150{\mu}m$ of diameter for $65^{\circ}$-inclined micro column, respectively.

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Evaluation of Corrosion Resistance on Al-Cr Coated Stainless Steel Separator for MCFC at Anode Side (MCFC 양극측에서 Al-Cr피복 스테인레스강 분리판의 내식성평가)

  • Lee, M.H.;Yoon, J.S.;Bae, I.S.;Yoon, D.J.;Kim, B.I.;Park, H.H.
    • Korean Journal of Materials Research
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    • v.13 no.2
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    • pp.126-132
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    • 2003
  • In order to evaluate the corrosion resistance at the anode side separator for molten carbonate fuel cell, STS316 and SACC-STS316 (chromium and aluminum were simultaneously deposited by diffusion into STS316 authentic stainless steel substrate by pack-cementation process) were applied as the separator material. In case of STS316, corrosion proceeded via three steps ; a formation step of corrosion product until stable corrosion product, a protection step against corrosion until breakaway occurs, a advance step of corrosion after breakaway. Especially, STS316 would be impossible to use the separator without suitable surface modification because of rapid corrosion rate after formation of corrosion product, occurs the severe problem on stability of cell during long-time operation. Whereas, SACC-STS316 was showed more effective corrosion resistance than the present separator, STS316 due to the intermetallic compound layer such as NiAl, Ni3Al formed on the surface of STS316 specimen. And it is anticipated that, in order to use SACC-STS316 alternative separator at the anode side, coating process, which can lead to dense coating layer, has to be developed, and by suitable pre-treatment before using it, very effective corrosion resistance will be achieved.

Investigation of Gas Evolution in Shell Cores during Casting Processes of Aluminum Alloys (알루미늄 합금 주조공정의 쉘 코아 가스 발생 전산모사 연구)

  • In-Sung Cho;Jeong-Ho Nam;Hee-Soo Kim
    • Journal of Korea Foundry Society
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    • v.43 no.4
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    • pp.187-193
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    • 2023
  • Shell core making is an excellent process in terms of formability and desanding, but when the molten aluminum comes into con- tact with the shell core, gas generation by pyrolysis of the resin is inevitable. In addition, when the ventilation is inadequate, pores will remain inside the casting, which can directly lead to defects of the casting. While studies on the gas generation behavior of shell core making have been reported, the modeling of gas generation has not been extensively investigated. We will develop a gas evolution analysis method that considers the relationship between temperature and gas quantity for the core to be developed. We then use the developed method to analyze the flow and solidification behavior of metal molten metal during core mold design and low-pressure casting of cylinder head products, and predict the occurrence of casting defects to derive a casting method that min- imizes the occurrence of defects.

A Study of Iron Pot Casting and Bellows Technology (토제 거푸집 무쇠솥 주조와 불미기술 연구)

  • Yun, Yonghyun;Doh, Jungmann;Jeong, Yeongsang
    • Korean Journal of Heritage: History & Science
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    • v.53 no.2
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    • pp.4-23
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    • 2020
  • The purpose of this study was to explore the diversity of Korea's iron casting technology and to examine various casting methods. The study involved a literature review, analysis of artifacts, local investigation of production tools and technology, and scientific analysis of casting and cast materials. Bellows technology, or Bulmi technology, is a form of iron casting technology that uses bellows to melt cast iron before the molten iron is poured into a clay cast. This technology, handed down only in Jeju Island, relies on use of a clay cast instead of the sand cast that is more common in mainland Korea. Casting methods for cast iron pots can be broadly divided into two: sand mold casting and porcelain casting. The former uses a sand cast made from mixing seokbire (clay mixed with soft stones), sand and clay, while the latter uses a clay cast, formed by mixing clay with rice straw and reed. The five steps in the sand mold casting method for iron pot are cast making, filling, melting iron into molten iron, pouring the molten iron into the cast mold, and refining the final product. The six steps in the porcelain clay casting method are cast making, cast firing, spreading jilmeok, melting iron into molten iron, pouring the molten iron, and refining the final product. The two casting methods differ in terms of materials, cast firing, and spreading of jilmeok. This study provided insight into Korea's unique iron casting technology by examining the scientific principles behind the materials and tools used in each stage of iron pot casting: collecting and kneading mud, producing a cast, biscuit firing, hwajeokmosal (building sand on the heated cast) and spreading jilmeok, drying and biyaljil (spreading jilmeok evenly on the cast), hapjang (combining two half-sized casts to make one complete cast), producing a smelting furnace, roasting twice, smelting, pouring molten iron into a cast, and refining the final product. Scientific analysis of the final product and materials involved in porcelain clay casting showed that the main components were mud and sand (SiO2, Al2O3, and Fe2O3). The release agent was found to be graphite, containing SiO2, Al2O3, Fe2O3, and K2O. The completed cast iron pot had the structure of white cast iron, comprised of cementite (Fe3C) and pearlite (a layered structure of ferrite and cementite).

Experimental Studies on Lead Toxicity in Domestic II. Histopathology (고양이의 납중독에 관한 실험적 연구 2. 조직병리학적 소견)

  • Hong Soon-Ho;Han Hong Ryul
    • Journal of Veterinary Clinics
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    • v.11 no.1
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    • pp.485-505
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    • 1994
  • Lead toxicity was evaluated in forty-five cats on a balanced diet, treated with 0(control), 10, 100(low), 1, 000, 2, 000 and 4, 000(high)ppm of lead acetate orally on a body weight basis. The objectives were to describe the gross and histopathologic changes and to demonstrate what tissue lead concentrations correlate with the known dosages of lead. In subclinical lead toxicity, greater than 80% of the absorbed lead was deposited in the bone, whereas in more acute lead toxicity, 42% of absorbed lead was deposited in the bone and 36% and 20% of absorbed lead was deposited in the kidneys and in the liver, respectively. No gross lesions were found in the nervous system. Yellow-brown colored livers appear to be associated with lead toxicity. Neuronal necrosis in the cerebrum was the most predominant histopathologic finding. Astrocytic proliferation in the cerebral gray matter was observed in 1 high dose cat. Gliosis was noted in the cerebral cortex of 6 high dose cats. Two high dose cats had demyelination in the deepest layer of the cortical gray matter of the cerebrum. Extravasation of red cells and cavitation around the vessels were found in the cerebrum of 1 high dose cat. Six high dose cats had degeneration of Purkinje cells in the cerebellum. The microscopic findings in the peripheral nerves were ambiguous. In more acute toxicity, the cats had lead inclusions in the epithelial cells of proximal tubules of the kidneys of 7 cats and hepatocytes of the liver of S cats. These inclusions could be seen wlth H&E, but were more prominent with orcein staining. Two high dose cats had granulomas and connective tissue hyperplasia between tubules of the kidneys. Periportal hepatocyte vacuolization was observed in the liver of 22 cats. Vacuolization of seminiferous tubules and a reduced number of spermatogonia(indicative of reduced spermatogenesis) were found in the testis of 5 treated cats. Cystic ovaries were observed in 3 high dose cats and poor development of oogonia was found in 2 cats. The diagnosis of lead toxicity in cats can be suspected on the basis of the histopathologic lesions described, and can be of value in contributing to a diagnosis. A reliable diagnosis of lead poisoning can be helped utilizing tissue lead analysis(post molten)

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Growth of RIG Single Crystals by Flux Technique (융제법에 의한 RIG 단결정 육성)

  • 김성현;이석희;정수진
    • Journal of the Korean Ceramic Society
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    • v.26 no.4
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    • pp.459-470
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    • 1989
  • Single crystals of rare-earth iron garnets were grown from solutions of molten lead oxide, lead fluoride, baric oxide, iron oxide, and the oxides of yttrium, samarium orgadolinium. The crystals were grown by slow cooling technique. A convenient composition was 41.8mol% PbO, 20.59mol% PbF2, 8.23mol% B2O3, 20.00mol% Fe2O3 and 10.00mol% R2O3 where R is Y, Sm or Gd. For this experiment, platinum crucibles of size 20, 30cc and a vertical siliconit tube furnace were used. The precipitation temperature of YIG was observed in the range of 115$0^{\circ}C$-112$0^{\circ}C$ and the optimum growth conditions in this experiment were determined. The nucleation rate was controlled by the holding time after the fast colling, the growth rate by the slow cooling conditiions. The form of the grown YIG crystals showed a combination of {110} and {211}, and the size of the crystals grown in this experiment was up to about 9mm under the conditions of holding time 16hour, cooling rate 2$^{\circ}C$/hr. and temperature range 115$0^{\circ}C$-90$0^{\circ}C$. The precipitatin temperature of SmIG was observed in the range of 105$0^{\circ}C$-98$0^{\circ}C$ and the size of the crystals grown in this experiment was up to about 5mm under the conditiions of holding time 16hours, cooling rate 2$^{\circ}C$/hr. and temperature range 100$0^{\circ}C$-80$0^{\circ}C$.

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An Investigation of Debris Configuration and Melt-Water Interaction in Steam Explosion Experiments using $ZrO_2$ (원자로 물질의 $ZrO_2$를 이용한 증기폭발 실험에서 용융물 거동 및 데브리의 분포)

  • Song, J.H.;Kim, H.D.;Hong, S.W.;Park, I.K.;Shin, Y.S.;Min, B.T.;Chang, Y.J.
    • Proceedings of the KSME Conference
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    • 2001.06e
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    • pp.57-62
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    • 2001
  • Korea Atomic Energy Research Institute (KAERI) launched an intermediate scale steam explosion experiment named Test for Real cOrium Interaction with water (TROI) using reactor material to investigate whether the corium would lead to energetic steam explosion when interacted with cold water at low pressure. The melt-water interaction is confined in a pressure vessel with the multi-dimensional fuel and water pool geometry. The cold crucible technology, where the mixture of powder in a water-cooled cage is heated by high frequency induction, is employed. In this paper, results of the first series of tests ($TROI-1{\sim}5$) were discussed. The ZrO2 jets with 5kg mass and 5cm diameter were poured into the 67cm deep water pool at $30{\sim}95^{\circ}C$. Either spontaneous steam explosions or quenching was observed. The morphology of debris and pressure wave profiles clearly indicates the each case.

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Study on the Fire Investigation by Damaged Pattern Analysis of Incandescent Lamps (백열전구의 소손 패턴 분석을 통한 화재조사 연구)

  • Kim, Hyang-Kon;Kim, Dong-Woo;Moon, Hyun-Wook;Choi, Chung-Seog;Choi, Hyo-Sang
    • Fire Science and Engineering
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    • v.22 no.5
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    • pp.22-28
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    • 2008
  • In this paper, we conducted experiments on damaged patterns of incandescent lamps by external stress, such as external flame or external impact. Glass bulbs were melted and filaments were evaporated by external flame when the bulbs were lit, and finally molten marks were recognized at the filaments. Also, there were some differences in absorption patterns of evaporated filament elements according to set-up directions, and evaporated filament elements were absorbed in lead-in wires, support, inside of glass. In case the bulbs were lit and they were damaged by external impacts, filament burned out. Filaments were not evaporated but melted. We expect that this results could be used to judge whether electric current flew through incandescent lamps or not in fire site.

THERMAL AND STRUCTURAL ANALYSIS OF CALANDRIA VESSEL OF A PHWR DURING A SEVERE ACCIDENT

  • Kulkarni, P.P.;Prasad, S.V.;Nayak, A.K.;Vijayan, P.K.
    • Nuclear Engineering and Technology
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    • v.45 no.4
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    • pp.469-476
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    • 2013
  • In a postulated severe core damage accident in a PHWR, multiple failures of core cooling systems may lead to the collapse of pressure tubes and calandria tubes, which may ultimately relocate inside the calandria vessel forming a terminal debris bed. The debris bed, which may reach high temperatures due to the decay heat, is cooled by the moderator in the calandria. With time, the moderator is evaporated and after some time, a hot dry debris bed is formed. The debris bed transfers heat to the calandria vault water which acts as the ultimate heat sink. However, the questions remain: how long would the vault water be an ultimate heat sink, and what would be the failure mode of the calandria vessel if the heat sink capability of the reactor vault water is lost? In the present study, a numerical analysis is performed to evaluate the thermal loads and the stresses in the calandria vessel following the above accident scenario. The heat transfer from the molten corium pool to the surrounding is assumed to be by a combination of radiation, conduction, and convection from the calandria vessel wall to the vault water. From the temperature distribution in the vessel wall, the transient thermal loads have been evaluated. The strain rate and the vessel failure have been evaluated for the above scenario.

Evaluation of MCCI Behaviors in the Calandria Vault of CANDU-6 Plants Using CORQUENCH Code (CORQUENCH 코드를 활용한 중수로 calandria vault에서의 MCCI 거동 분석)

  • Seon Oh YU
    • Transactions of the Korean Society of Pressure Vessels and Piping
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    • v.17 no.2
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    • pp.90-100
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    • 2021
  • Molten corium-concrete interaction (MCCI) is one of the most important phenomena that can lead to the potential hazard of late containment failure due to basemat penetration during a severe accident. In this study, MCCI analytical models of the CORQUENCH code were prepared through verification calculations of several experiments, which had been performed using concrete types similar to those of the calandria vault floor in CANDU-6 plants. The behaviors of thermal-hydraulic variables related to MCCI phenomena were analyzed under the conditions of dry floor and water flooding during the severe accident stemming from a hypothetic station blackout. Uncertainty analyses on the ablation depth were also carried out. It was estimated that the concrete ablation was not interrupted due to the continuous MCCI process under the dry condition but was terminated within 24 hours under the water flooding condition. It was confirmed that the water flooding as a mitigating action was effective to achieve the quenching and thermal stabilization of the melt discharged from the calandria vessel, showing that the present models are capable of reasonably simulating MCCI phenomena in CANDU-6 plants. This study is expected to provide the technical bases to the accident management strategy during the late-phase severe accidents.