• Proceedings of the KIEE Conference
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• 2005.07b
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• pp.1784-1787
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• 2005

This paper presents the development and testing of a power conditioning system(PCS) for application to a 100kW Molten Carbonate Fuel Cell(MCFC) generation system. The MCFC generation system is a part of a four year government funded research project that began in 2001. This paper presents the results of various tests and performance verification of the 100kW PCS using a DC power system that simulates the DC output of the MCFC fuel cell. Performance of the DC/DC, DC/AC converters were verified, and basic control functions such as grid connection, protection and characteristics of each components were tested. The tests were performed under light load and rated load conditions to verify the operation efficiency, power quality effects, and stability of the PCS.

• 한국전산유체공학회:학술대회논문집
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• 2003.08a
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• pp.219-224
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• 2003

An analysis procedure for the MCFC channel flow has been developed to predict the fuel cell performance. As for the electrochemical reaction, among several chemical reaction models, one that fits the data best is adopted after a comprehensive comparative study. The Wavier-Stokes, energy, and species equations are solved to obtain the velocity, temperature and concentration fields for a specified average current density. The procedure is iterative as the local current density, or the reaction rate, is allowed to vary with the gas composition. A series of calculations are then carried out to examine the effects of gas flow rate, gas composition, gas usage rate, inlet gas temperature, and average current density on the fuel cell performance. The fuel cell characteristics, such as the temperature, current density distributions, and the concentration fields, for various operating conditions are presented and discussed.

• Proceedings of the KIEE Conference
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• 1998.07a
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• pp.55-57
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• 1998

Molten carbonate fuel cell (MCFC) power plant is expected to be one of the most promising future power generation system for the electric utilities because of its high efficiency, environmental suitability and capability of using coal as fuel. To get such attractive performance, it is necessary to consider optimizing operation and gas recycling system. This paper describes the simulation results of 7 kW MCFC stack in KEPRI and the effects of the three possible gas recycling operations, i.e. cathode gas recycling, anode gas recycling, anode gas recycling with catalytic burner.

• Transactions of Materials Processing
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• v.23 no.3
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• pp.171-177
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• 2014

The current collector for the molten carbonate fuel cell (MCFC) which has sheared protrusions is manufactured by the three-stage forming process that integrates slitting, preforming and final forming. Due to the repetition of sheared protrusions, an effective simulation method is required to predict the mechanical behavior. In the current study, a sheet with sheared protrusions was assumed to be an orthotropic plate, which has the same length, width and height. FEM simulations were conducted to evaluate the homogenized properties of the current collector, which has 4 (longitudinal direction) x 4 (transverse direction) sheared protrusions. The simulation model was constructed using hexahedral mesh coarsening. From the verification examples, it was found that the proposed simulation method was efficient within reasonable accuracy. The calculated homogenized properties can be applied to the design of a stack for molten carbonate fuel cells and the prediction of mechanical behavior for other applications.

• Journal of the Korean Electrochemical Society
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• v.5 no.2
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• pp.62-67
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• 2002

The corrosion of the metallic cell components is blown to be one of the major reason f3r the performance degradation and subsequently the life-time limitation of the MCFC. To elucidate the corrosion phenomena, a corrosion study with the AISI-type 316L stainless steel, the most widely used separator material, in 621Li/38K carbonate eutectic melt was carried out. Corrosion phenomena in an MCFC were observed to differ from one location to another due to different environmental condition. The stability of passive film was found to be responsible fur the variations in corrosion phenomena. According to the potentiodynamic analysis, the passive film formed in anode-gas environment was less stable than in cathode-gas environment. The potentiostatic method combined with XRD analysis in addition to the cyclicvoltammetry was conducted to get an insight on variety corrosion reaction of AISI-type 316L stainless steel in a carbonate melt.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2003.05a
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• pp.639-642
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• 2003

용융탄산염형 연료전지(MCFC)는 고효율의 환경친화성 발전시스템으로서, 더욱이 석탄가스를 연료로 사용할 수 있다는 점에서 전력사업용 발전시스템으로서 우리나라를 포함 각국에서 개발이 진행 중에 있다. 그러나 장래 이 MCFC는 하나의 발전시스템으로서 마이크로가스터빈 등의 소형 분산전원과의 경쟁관계에 놓이게 될 것이며, 따라서 적정규모의 경제성 및 신뢰성을 요구받게 될 것이다.(중략)

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2007.10a
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• pp.296-299
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• 2007

The focus of this study is to estimate the stiffness factor of the separator plate of MCFC (Molten Carbonate Fuel Cell) at the elevated temperature. The process factors affecting the stiffness of the separator plate were chosen to determine the most important factor using the finite element analysis with the Taguchi method. The most influential factor, picked out by the ANOYA, turned out the pitch in the separator plate.

• Transactions of Materials Processing
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• v.21 no.5
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• pp.298-304
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• 2012

The shielded slot plates for a molten carbonate fuel cell(MCFC) have a sheared corrugated trapezoidal pattern. In the FEM simulations for the production of the shielded slot plate, the user material subroutine VUMAT in the commercial FEM software ABAQUS was used to implement a ductile fracture criterion. The critical damage value for the ductile fracture criterion was determined by comparing the experimental results of the shearing process with the simulation results. Using the ductile fracture criterion, the FEM simulation of the three-dimensional forming process of the shielded slot plate was conducted. The effects of the shearing process on the forming process were examined through FEM simulation and experiments. The forming simulation of nine unit cells was conducted. Using the simulation results of the forming process, the deformed shape after springback was calculated. The experimental result shows good agreement with the simulation.

• Transactions of Materials Processing
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• v.20 no.4
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• pp.273-278
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• 2011

Employing the TRIZ problem solving technique, a hybrid-type center plate for the molten carbonate fuel cell(MCFC) was developed for the purpose of improving gas sealing and maintenance. The manufacturing method of the hybrid-type center plate was divided into a trimming operation and a two-step bending process. In the latter, a modified punch shape was used to reduce springback. Using finite element(FE) simulations, bending stresses in the thickness and the in-plane directions were computed and the bending conditions were optimized. The optimized results of the two-step bending process were used as a basis for the design of the trimming process of the hybrid-type center plate. Finally, the external manifold-type center plate and the hybrid-type center plate were fabricated using a die set that accounts for the optimized conditions. It was found that the numerical simulation results were in good agreement with the experiments.

• Journal of the Korean institute of surface engineering
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• v.26 no.6
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• pp.291-298
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• 1993

In order to substitute for porous nickel anode in Molten Carbonate Fuel Cell(MCFC), porous cermet elec-trode was fabricated with Ni and Ni-P coated ceramic powder. Ni and Ni-P were coated by electroless plat-ing method in the nickel solution containing of hydrazine and sodium hypophosphate as a reducing agent. The plating solution was stirred by air and mechanical agitator. Ultrasonic irradiation was applied to the plating bath to improved the effect of agitation and coating speed. Electorde was formed by pressing method and doc-tor blade method followed by sinterd at$ 800^{\circ}C$ for 6 hours in H2 environment. Anode performance test carried out by potentiodynamic polarization technique in the MCFC operating condition and 154-161mA/$\textrm{cm}^2$ as ob-tained as a anode current density at the+100mV overpotential.