• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 B
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• pp.1784-1787
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• 2005

This paper presents the development and testing of a power conditioning system(PCS) for application to a 100kW Molten Carbonate Fuel Cell(MCFC) generation system. The MCFC generation system is a part of a four year government funded research project that began in 2001. This paper presents the results of various tests and performance verification of the 100kW PCS using a DC power system that simulates the DC output of the MCFC fuel cell. Performance of the DC/DC, DC/AC converters were verified, and basic control functions such as grid connection, protection and characteristics of each components were tested. The tests were performed under light load and rated load conditions to verify the operation efficiency, power quality effects, and stability of the PCS.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2003년도 추계 학술대회논문집
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• pp.219-224
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• 2003

An analysis procedure for the MCFC channel flow has been developed to predict the fuel cell performance. As for the electrochemical reaction, among several chemical reaction models, one that fits the data best is adopted after a comprehensive comparative study. The Wavier-Stokes, energy, and species equations are solved to obtain the velocity, temperature and concentration fields for a specified average current density. The procedure is iterative as the local current density, or the reaction rate, is allowed to vary with the gas composition. A series of calculations are then carried out to examine the effects of gas flow rate, gas composition, gas usage rate, inlet gas temperature, and average current density on the fuel cell performance. The fuel cell characteristics, such as the temperature, current density distributions, and the concentration fields, for various operating conditions are presented and discussed.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1998년도 하계학술대회 논문집 A
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• pp.55-57
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• 1998

Molten carbonate fuel cell (MCFC) power plant is expected to be one of the most promising future power generation system for the electric utilities because of its high efficiency, environmental suitability and capability of using coal as fuel. To get such attractive performance, it is necessary to consider optimizing operation and gas recycling system. This paper describes the simulation results of 7 kW MCFC stack in KEPRI and the effects of the three possible gas recycling operations, i.e. cathode gas recycling, anode gas recycling, anode gas recycling with catalytic burner.

• 소성∙가공
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• 제23권3호
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• pp.171-177
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• 2014

The current collector for the molten carbonate fuel cell (MCFC) which has sheared protrusions is manufactured by the three-stage forming process that integrates slitting, preforming and final forming. Due to the repetition of sheared protrusions, an effective simulation method is required to predict the mechanical behavior. In the current study, a sheet with sheared protrusions was assumed to be an orthotropic plate, which has the same length, width and height. FEM simulations were conducted to evaluate the homogenized properties of the current collector, which has 4 (longitudinal direction) x 4 (transverse direction) sheared protrusions. The simulation model was constructed using hexahedral mesh coarsening. From the verification examples, it was found that the proposed simulation method was efficient within reasonable accuracy. The calculated homogenized properties can be applied to the design of a stack for molten carbonate fuel cells and the prediction of mechanical behavior for other applications.

• 전기화학회지
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• 제5권2호
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• pp.62-67
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• 2002

용융탄산염 연료전지의 성능 저하와 수명 감소의 원인이 되는 부식 현상을 규명하고자 분리판 재료로 가장 널리 사용되고 있는 AISI-type 316L stainless steel을 대상으로 62Li/38K계 용융탄산염 내에서의 부식 실험을 수행하였다. 부식의 형태 및 속도는 환경에 의하여 다양하게 변화하게 되며, 용융탄산염 내에서 AISI-type 316L stainless steel의 부식 속도는 부식 반응에 의하여 형성되는 부동태 산화막의 안정성에 의하여 크게 영향을 받는다. 전기화학적 분극 거동을 분석한 결과 용융탄산염 연료전지의 anode가슨 분위기에서는 안정한 부동태 산화막이 형성되지 않았다. 순환 전압전류법과 정전위법을 이용한 부식 생성물의 X-ray분석을 통하여 특정한 전기화학적 전위 영역에서 반응기구와의 인과관계를 규명하고 다양한 형태의 부식 반응들을 분리해 내었다.

• 한국에너지공학회:학술대회논문집
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• 한국에너지공학회 2003년도 춘계 학술발표회 논문집
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• pp.639-642
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• 2003

용융탄산염형 연료전지(MCFC)는 고효율의 환경친화성 발전시스템으로서, 더욱이 석탄가스를 연료로 사용할 수 있다는 점에서 전력사업용 발전시스템으로서 우리나라를 포함 각국에서 개발이 진행 중에 있다. 그러나 장래 이 MCFC는 하나의 발전시스템으로서 마이크로가스터빈 등의 소형 분산전원과의 경쟁관계에 놓이게 될 것이며, 따라서 적정규모의 경제성 및 신뢰성을 요구받게 될 것이다.(중략)

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2007년도 추계학술대회 논문집
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• pp.296-299
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• 2007

The focus of this study is to estimate the stiffness factor of the separator plate of MCFC (Molten Carbonate Fuel Cell) at the elevated temperature. The process factors affecting the stiffness of the separator plate were chosen to determine the most important factor using the finite element analysis with the Taguchi method. The most influential factor, picked out by the ANOYA, turned out the pitch in the separator plate.

• 소성∙가공
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• 제21권5호
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• pp.298-304
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• 2012

The shielded slot plates for a molten carbonate fuel cell(MCFC) have a sheared corrugated trapezoidal pattern. In the FEM simulations for the production of the shielded slot plate, the user material subroutine VUMAT in the commercial FEM software ABAQUS was used to implement a ductile fracture criterion. The critical damage value for the ductile fracture criterion was determined by comparing the experimental results of the shearing process with the simulation results. Using the ductile fracture criterion, the FEM simulation of the three-dimensional forming process of the shielded slot plate was conducted. The effects of the shearing process on the forming process were examined through FEM simulation and experiments. The forming simulation of nine unit cells was conducted. Using the simulation results of the forming process, the deformed shape after springback was calculated. The experimental result shows good agreement with the simulation.

• 소성∙가공
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• 제20권4호
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• pp.273-278
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• 2011

Employing the TRIZ problem solving technique, a hybrid-type center plate for the molten carbonate fuel cell(MCFC) was developed for the purpose of improving gas sealing and maintenance. The manufacturing method of the hybrid-type center plate was divided into a trimming operation and a two-step bending process. In the latter, a modified punch shape was used to reduce springback. Using finite element(FE) simulations, bending stresses in the thickness and the in-plane directions were computed and the bending conditions were optimized. The optimized results of the two-step bending process were used as a basis for the design of the trimming process of the hybrid-type center plate. Finally, the external manifold-type center plate and the hybrid-type center plate were fabricated using a die set that accounts for the optimized conditions. It was found that the numerical simulation results were in good agreement with the experiments.

• 한국표면공학회지
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• 제26권6호
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• pp.291-298
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• 1993

In order to substitute for porous nickel anode in Molten Carbonate Fuel Cell(MCFC), porous cermet elec-trode was fabricated with Ni and Ni-P coated ceramic powder. Ni and Ni-P were coated by electroless plat-ing method in the nickel solution containing of hydrazine and sodium hypophosphate as a reducing agent. The plating solution was stirred by air and mechanical agitator. Ultrasonic irradiation was applied to the plating bath to improved the effect of agitation and coating speed. Electorde was formed by pressing method and doc-tor blade method followed by sinterd at$ 800^{\circ}C$ for 6 hours in H2 environment. Anode performance test carried out by potentiodynamic polarization technique in the MCFC operating condition and 154-161mA/$\textrm{cm}^2$ as ob-tained as a anode current density at the+100mV overpotential.