• Title/Summary/Keyword: Molecular electronic device

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Electrical Properties of IMI-O Polymeric LB Films Using logic Concentration (이온농도에 의한 IMI-O고분자 LB막의 전기특성)

  • 정상범;유승엽;박재철;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.418-420
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    • 1997
  • We synthesized the polymer that can have function group and improvement of mechnical strength and then confirmed the possibility of molecular device made by LB method. In this paper, the $\pi$-A isotherm has been investigated as to the kinds and various concentrations of the metal ions complexed with imidazole group. The experimental results for the electrical properties of MIM fabricated has been obtained as following. There is no change in limiting area as to the kinds of the metal ions, also the shift of conductivity as to the metal ions couldn't be observed, which was 10$\^$-14/[S/cm]. There are some changes in limiting area as to the concentration of the metal ions, the conductivity shift was increased with the occupied molecular area.

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Electronic Properties of MIM Structure for application in Communication Device (통신소자 응용을 위한 MIM 구조 유기박막의 전자특성)

  • Choi, Young-Il;Song, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the IEEK Conference
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    • 2005.11a
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    • pp.1279-1282
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    • 2005
  • Maxwell displacement current (MDC) measurement has been employed to study the dielectric property of Langmuir-films. MDC flowing across monolayers is analyzed using a rod-like molecular model. LB layers of Arachidic acid deposited by LB method were deposited onto slide glass as Y-type film. The structure of manufactured device is Au/Arachidic acid/Al, the number of accumulated layers are $3{\sim}9$. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from -3 to +3[V].

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A Study on Electroluminescence Device with Polymer (고분자를 이용한 전계발광소자에 관한 연구)

  • Lee, Jong-Chan;Lee, Cheong-Hak;Park, Su-Gil;Lim, Kee-Joe;Park, Dae-Hee
    • Proceedings of the KIEE Conference
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    • 1997.07d
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    • pp.1219-1221
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    • 1997
  • Poly(1,4-phenylene(1-methoxyenthylene)), organic water soluble PPV precursor was synthesized for polymer electroluminescence(EL) device. To control the molecular array, deposition method of emitter was Langmuir-Blodgett(LB). PPV precursor layer was treated thermally to conversion of PPV. Optical, electrical and EL properties of PPV LB thin film was estimated. Homogeneous light emission of greenish-yellow in PPV LB thin film can be easily confirmed under normal lighting even at low driving voltage. Polymer EL device using PPV LB thin film as emitter materials had a possibility to apply to next generation display device.

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A Study on the Electrical Physical Properties of Organic Thin Films for Manufacture in Power Device (전력용 소자 제작을 위한 유기박막 전기물성에 관한 연구)

  • Cho, Su-Young;Kim, Young-Keun;Choi, Young-Il;Song, Jin-Won;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.05c
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    • pp.37-41
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    • 2004
  • In this paper, evaluation of physical properties about dielectric relaxation phenomena by the detection of the surface pressures and displacements current on the monolayer films of phospolipid monomolecular DLPC, DMPC using pressure stimulus. As a result, the changed surface pressure, displacement current and the transition forms of dipole moment of phospolipid monomolecular in area per molecular by pressure stimulus were conformed well. It was known that the monolayers by linear relationship for decision of dielectric relaxation time between compressure speed and molecule area By according to the linear relationship relation get that frictional constant, DLPC was $1.89{\times}10^{-19}$ [Js] and DMPC was $0.722{\times}10^{-19}$[Js]. lt is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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A Study on the Electrical Properties of DLPC LB films (DLPC LB박막의 전계자격 응답특성)

  • Cho, S.Y.;Oh, J.H.;Lee, K.S.;Kim, H.J.;Kim, H.G.;Kim, B.C.
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.810-812
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    • 1998
  • We studied on the $\pi$-A isotherm of the L-$\alpha$-DLPC was measured at the air-water interface varying with the compressing speed and amounts of solutions for spreading. The molecular arrangement of deposited films were evaluated by measuring the absorption with the UVspectrometer. We made structures of metal(Au)/organic thin films (L-$\alpha$-DLPC)/Metal(Au), the number of accumulated layers are 3. And I-V characteristic of the device examined.

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Application of Graphene Nanoribbon Trench for C60 Fullerene Shuttle Device: Molecular Dynamics Simulations (풀러렌 셔틀 소자로 그래핀 나노리본 트렌치 응용에 관한 분자동력학 시뮬레이션 연구)

  • Kwon, Oh-Kuem;Kang, Jeong Won
    • Asia-pacific Journal of Multimedia Services Convergent with Art, Humanities, and Sociology
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    • v.8 no.1
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    • pp.887-894
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    • 2018
  • We investigated the position controlling C60 fullerene encapsulated into a graphene-nanoribbon trench via classical molecular dynamics simulations. The graphene-nanoribbon trench can provide nanoscale empty spaces, and a C60 encapsulated therein can be considered as media for a nanoelectromechanical shuttle device. The classical molecular dynamics simulations presented here provide information on the potential application of a graphene-nanoribbon trench in a C60 shuttle device. Driving forces applied to C60 resulted in its motion toward the edges of the graphene-nanoribbon trench, the suction forces induced at both edges were balanced with the driving forces, and finally, the C60 fullerene gradually settled on the edges of the graphene-nanoribbon trench after several oscillations. The results of the present simulation suggest the importance of graphene-nanoribbon trenches encapsulating fullerenes in a wide range of applications in the field of nanotechnology.

A Study on the Microstructure of Organic Ultra Thin Films and Phase Transition of Langmuir Films in BAM (BAM을 이용한 L막의 상전이 현상과 유기초박막의 미세구조에 관한 연구)

  • Kim, Byung-Geun;Chon, Dong-Kue;Kim, Young-Keun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.938-941
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    • 2003
  • It is well known that the state of existence of molecules on the surface of water changes during compression of the molecules. Electric methods, such as measurement of the surface potential or displacement current are also useful for investigating dynamic changes of molecular state on the water surface during compression and Transformation of molecular film occurs only usually in air-water interface, 2 dimensions domain's growth and crash are achieved. Organic thin film that consist of growth of domain can understand correct special quality of accumulation film supplying information about fine structure and properties of matter of device observing information and so on that is surface forward player and optic enemy using AFM one of SPM application by nano electronics. In this paper Langmuir (L) that is one of basis technology to manufacture of organic matter device using biology material PBDG that is kind of polypeptide that have biology adaptedness. The Experiment method used ${\pi}-A$ isotherm and BAM(Brewster Angle Microscopy), using the BAM, we can to the molecular orientation of monolayer on the water surface and directly see the morphology of the films on water subphase as well as that of the films.

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Fabrication and Electrical Characteristics of Ferredoxin Self-Assembled Layer for Biomolecular Electronic Device Application

  • NAM YUN SUK;CHOI JEONG-WOO
    • Journal of Microbiology and Biotechnology
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    • v.16 no.1
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    • pp.15-19
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    • 2006
  • A ferredoxin adsorbed hetero self-assembled layer was fabricated on chemically modified Au substrate, 4-Aminothiophenol (4-ATP) was deposited onto Au substrate and then N-succinimidyl-3-[2-pyridyldithio] propionate (SPDP) was adsorbed on the 4-ATP layer, since SPDP was used as a bridging molecule for ferredoxin adsorption, Ferredoxin/SPDP/4-ATP structured hetero layer was constructed because of strong chemical binding of ferredoxin, SPDP, and 4-ATP, The surface of the ferredoxin-adsorbed SPDP/4-ATP layer was observed by scanning tunneling microscopy, The hetero film formation was verified by surface plasmon resonance measurement. The current flow and rectifying property based on the scanning tunneling spectroscopy I-V characteristics was achieved in the proposed hetero layer. Thus, the hetero layer structure of ferredoxin functioned as a molecular diode with rectifying property, The proposed molecular diode can be usefully applied for the development of molecular scale electronic devices.

Physical Properties of the Langmuir-Blodgett Films Layered with Octadecylviologen-TCNQ (Octadecylviologen-TCNQ LB 막의 물리적 특성)

  • 신동명;박제상;강도열
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.77-80
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    • 1995
  • Enhancing the electrical conductivity of the ultrathin organic films using Langmuir-Blodget technique is important step for the developement of molecular electronic device. The Octadecylviologen-TCNQ was synthesized with Octadecylviologen-Bromide an Lithium TCNQ Sine Octadecylviologen-TCNQ has two TCNQ snion radicals, the conductivity of LB film is expected to increase. The $\pi$-A isotherm showed that the limiting area was 150${\AA}$$\^$2/ molecule and the silid-like transition surface pressure was 25 mN/m. The electronic transition of the TNCNQ anion radical was observed at 400 nm. Intermolecular charge transfer absorption was observed at 600nm and 850~1050 nm which ay resulted from the TCNQ anion radical dimer formation. The electrical conductivity of the viologen -TCNQ LB film was 10$\^$-6/cm This values was 100 times higher than that of the quinolinium-TCNQ and pyridinium-TCNQ LB films.

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A Study on the Current-Voltage Measurement of Self-Assembled Organic molecular onto Au Electrode (Au기판에 자기조립화된 유기 단분자의 전압-전류 측정 연구)

  • Kim, Seung-Un;Park, Sang-Hyun;Park, Jae-Chul;Shin, Hoon-Kyu;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1730-1733
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    • 2004
  • Device miniaturization and high integrated circuit design is of major interest for the development of electronic devices. Various studies have been conducted to develop new material and processing technique[1]. Negative Differential Resistance(NDR) is the defining behavior in several electronic components, including the Esaki diode and most notably, resonant tunneling diodes(RTD)[2]. We made a comparison of electrical properties between 4,4-Di(ethynylphenyl)-2'-nitro-1-(thioacetyl)benzene and 4-[2,5-dimethoxy-4-(p henylethynyl)phenyl]ethynylphenylethanethioate, which have been well known as a conducting molecule having possible application to molecular level NDR devices. As a result, we measured current-voltage curves using Scanning Tunneling microscopy(STM), I-V curves also showed several current peaks between negative and positive bias region.

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