• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.202-202
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• 2006

With a modern size exclusion chromatography (SEC) column, molecular weight analysis of a polymer sample takes about 10 min. However, it is desirable to reduce the analysis time further, in particular, for high throughput measurements required in combinatorial analyses or 2D-HPLC analyses. We implemented the high temperature SEC for the purpose. By inserting a narrow bore tubing between the column and the detector, a sufficient backpressure can be maintained to prevent the mobile phase from boiling and the effluent is cooled down enough when it reaches the detector. Therefore, a normal SEC detector can be used without any modification. The SEC resolution is greatly improved at the elevated temperature at high flow rate which allows high speed operation.

• Journal of the Korean Chemical Society
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• v.16 no.1
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• pp.50-55
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• 1972

The mechanical degradation of $poly(\alpha-methyl$ styrene) in several mixed solvents (chlorobenzene-n-butyl alcohol, chlorobenzene-sec-butyl alcohol, chlorobenzene-Kerosene, chlorobenzene-methylketone) was studied using the capillary flow method. The velocity constant of scission reaction (K) and the limited degree of polymerization (g) were compared at the same value of [${\eta}$], which is considered as the parameter of molecular dimension of polymers in solution. As results, (K) did not change much, even if the species and the volume fraction of poor(non-) solvents changed, while the value of (g) changed according to the species of poor (non-) solvents and the value of [${\eta}$] these results were discussed.

• 유체기계공업학회:학술대회논문집
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• 2000.12a
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• pp.82-87
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• 2000

The direct simulation Monte Carlo (DSMC) method is applied to investigate the flow field of a disk-type drag pump. The pumping channels are cut on both sides of a rotating disk. The rotor has 10 Archimedes' spiral blades. In the present DSMC method, the variable hard sphere model is used as a molecular model, and the no time counter method is employed as a collision sampling technique. For simulation of diatomic gas flows, the Larsen-Borgnakke phenomenological model is adopted to redistribute the translational and internal energies.

• 제어로봇시스템학회:학술대회논문집
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• 2001.10a
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• pp.100.3-100
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• 2001

This article deals with the development of a mathematical model for the finishing polycarbonate polymerization process using a horizontal rotating disk-ring reactor with counter-current gas sweeping and the performance analysis of the reactor system by using the model. Here we intend to propose a model describing the reactor system consisting of two phases, in which by-product phenol is removed from the polymer of high molecular weight compatible with the products of commercial grades. The vapor phase is represented by a tanks-ln-series model while the polymer melt phase is regarded as a plug flow reactor.

• Proceedings of the KSME Conference
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• 2002.08a
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• pp.577-580
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• 2002

In this paper, the pumping performance of the disk-type drag pump which works in the outlet pressure range from 4 to 0.001 Torr is studied experimentally. The pumping characteristics of various drag pumps are performed. The inlet pressures are measured for various outlet pressures of the test pump. The flow-meter method is adopted to calculate the pumping speed. Compression ratios and pumping speeds for the nitrogen gas are measured. The present experimental data show the leak-limited value of the compression ratio in the molecular transition region. The rotational speed of the pump is 24,000rpm. The inlet pressures are measured for various outlet pressures of the test pump. The ultimate Pressures for zero throughput are measured for three-stage, two-stage and single-stage disk-type, respectively.

• Nuclear Medicine and Molecular Imaging
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• v.43 no.3
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• pp.207-214
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• 2009

Positron emission tomogrpahy (PET) represents the most advanced scintigraphic imaging technology. With the increase in availability of PET, the clinical use of PET has grown in medical fields. This can be employed for cardiovascular research as well as for clinical applications in patients with various cardiovascular disease. PET allows non-invasive functional assessment of myocardial perfusion, substrate metabolism and cardiac innervation and receptors as well as gene expression in vivo. PET is regarded as the gold standard for the detection of myocardial viability, and it is the only method available for the quantitative assessment of myocardial blood flow. This review focuses on the clinical applications of myocardial perfusion PET in coronary artery disease.

• Journal of ILASS-Korea
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• v.15 no.3
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• pp.109-114
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• 2010

The implementation of gelled propellants systems offers high performance, energy management of liquid propulsion, storability, and high density impulse of solid propulsion. The present study focused on the macroscopic spray characteristics of liquid sheets formed by triplet impinging jets of non-Newtonian liquids which are mixed by Carbopol 941 0.5%wt. The results are compared to experiments conducted on spray images which formed by triplet impinging jets concerning with airassist effect at center orifice. When gel propellants are injected by doublet impinging jets at low pressure and high pressure, closed rim pattern shape appeared by polymeric effect from molecular force and showed inactive atomization characteristics, because of extensional viscosity related by restriction of atomization process and breakup time delay of turbulence transition. As increasing mass flow rate of the air(increasing GAR), spray breakup level is also increased.

• Proceedings of the KSME Conference
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• 2008.11a
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• pp.1570-1574
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• 2008

Various mechanical test were conducted on conventional and crosslinked ultra-high molecular weight polyethylene(UHMWPE) all prepared from the same lot of medical grade GUR 1050 for artificial joint. The conventional materials were not irradiated and treated by heating. The cosslinked materials were irradiated with $25kGy{\sim}200kGy$ by gamma-ray andthen annealed or remelted. Gamma-ray irradiation and heat treatment process were found to significantly impact the crystallinity, and hence the mechanical behavior, of the highly crosslinked UHMWPE. The radiation dose and heating conditions were key predictors of the uniaxial yielding, plastic flow, and failure properties of conventional and highly crosslinked UHMWPE. The correlation model from experiments would be the basic information to enhance the were resistance of artificial joint liner.

• Proceedings of the KIEE Conference
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• 2002.07c
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• pp.1419-1421
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• 2002

Plasma polymerization of thiophene was carried out in a vacuum reactor with capacitively coupled electrode. This paper describes the dependence of molecular structure and electrical properties on the polymerization conditions such as plasma energy, mass flow rate and pressure. The plasma polymerized thiophene films were chracterized by FT-IR spectroscopy and SEM. The IR analysis revealed the thiophene rings are broken by the discharge energy.

• Transactions of Materials Processing
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• v.16 no.4 s.94
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• pp.229-233
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• 2007

The present work focuses on the prediction of birefringence in injection-molded part and its improvement by rapid mold heating. To calculate birefringence, flow-induced residual stress is computed through a fully three-dimensional injection molding analysis. Then the stress-optical law is applied from which the order of birefringence can be evaluated and visualized. The birefringence patterns are predicted for a rectangular plate with a variation of mold temperature, which shows that the amount of molecular orientation and birefringence level decreases with an increase of mold temperature. The effect of mold temperature on the order of birefringence is also studied for a thin-walled rectangular strip, and the relevant results are compared with experimental measurements. Both predicted and experimental patterns of birefringence are in agreements on the observation that the birefringence level diminishes significantly when the mold temperature is raised over the glass transition temperature.