• Title/Summary/Keyword: Mole Fraction

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Analysis of the Seasonal Change in Attached Algae and Microbial Community Structure in Sediment Basin Trough of Water Treatment Plant By Using Quinone Profile and PCR-DGGE (Quinone profile과 PCR-DGGE를 이용한 정수장 침전지에서의 부착조류 및 미생물군집의 계절적 변화해석)

  • Yu, Hyun-Sun;Lim, Byung-Ran;Ahn, Kyu-Hong
    • Journal of Korean Society of Water and Wastewater
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    • v.20 no.3
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    • pp.461-467
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    • 2006
  • The seasonal change in attached algae and microbial community structure at sedimentation basin of water treatment plant was investigated by using quinone profiles and denaturing gel gradient electrophoresis (DGGE). The photosynthetic bacteria and algae contains PQ-9 and VK-1 as major quinone are major component of the total quinone fraction in attached algae and microorganisms on sedimentation basin trough. The microorganisms containing menaquinones appear to be sensitivity to the change in temperature than those containing ubiquinones. The plot of the mole fraction of dominant quinone species ($f_d$) to the DQ values showed higher sensitivity to the seasonal change in the microbial community structure. The results indicated that quinone and DGGE are useful tool for the evaluation of the changes in the microbial community structure.

A Direct Detection of $CO_2$ in Sealed-off $CO_2$ Discharge Tube by Optoacoustic Effect

  • Kim Sung-Ho;Choi Joong-Gill;Cho Ung-In
    • Bulletin of the Korean Chemical Society
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    • v.15 no.1
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    • pp.23-25
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    • 1994
  • A simple analytical method that allows direct monitoring of small amount of CO$_2$ in a CO$_2$ discharge tube which utilizes the optoacoustic detection technique is described. The dependence of the optoacoustic signal on the mole fraction of CO$_2$ was shown that the system responded linearly to the amount of CO$_2$ present in the miniature discharge cavity equipped with Cu electrodes. It was also found that fraction of dissociated CO$_2$ varied from 14 to 37% of the initial concentration which depended on the current and the pressure in the tube. This simple and easy detection method has proven to possess the practical advantages over the conventional systems for the study of CO$_2$ laser electrodes.

Transient behavior of cryogenic thermosiphon working with R14 and nitrogen mixture (R14와 질소 혼합유체를 사용하는 극저온 열사이펀의 과도상태 거동)

  • Lee, Ji-Sung;Jeong, Sang-Kwon
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.1
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    • pp.66-70
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    • 2010
  • The operational temperature range of thermosiphon is generally limited from the critical point to the triple point of the working fluid to maintain two-phase state. Thermosiphon with mixed working fluid has a potential to widen the operational temperature range. In this study, the physical behavior of mixed working fluid during the transient operation of thermosiphon was analyzed with temperature-mole fraction diagram. The condenser and the evaporator temperature variations were explained by the dew line and the bubble line of the mixture. It is encouraging that the thermosiphon operation commences early with larger fraction of high boiling point component, but the temperature gap between the condenser and the evaporator due to the separation of two components has a negative effect on the officient cool down process.

Excess Enthalpies and Activity Coefficients for the Binary Nonionic Amphiphile 2-Butoxyethanol/Water System (양친매성 2-butoxyethanol과 물 혼합계에서의 과잉 엔탈피 및 활동도 계수)

  • Lim, Kyung-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.2
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    • pp.132-138
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    • 2000
  • Excess enthalpies ($H^{E}$) were measured by isothermal flow calorimetry for the nonionic amphiphile 2-butoxyethanol/water mixtures at 10 different temperatures (48.5 to $70^{\circ}C$) around and above the lower consolute solution temperature, $T_{lc}$. $H^{E}$ exhibits U-shape for the binary mixtures, and is large and negative which reflects substantial interaction between two chemical species. When the commonly used, semi-empirical Redlich-Kister (RK) polynomials were fitted to the measured $H^{E}$, plots of $H^{E}$ vs. weight fraction provided more accurate fitting with fewer parameters than conventionally drawn $H^{E}$ vs. mole fraction plots. This was due to the enhanced symmetry of $H^{E}$ vs. weight fraction plots. Using the fitted Redlich-Kister polynomials and the Gibbs-Helmholtz relation, temperature dependence of the activity coefficients were found and compared to the values determined from vapor-liquid equilibria. The activity coefficients were in the range of one to three, indicating that the binary system deviates from ideality but not substantially. They slightly depended on temperature and the temperature effect was equivalent to 10 % change in the activity coefficients.

Combustion Characteristics and Soot Formation in a Jet Diffusion Flame (제트 확산화염의 연소특성과 매연생성에 관한 연구)

  • 이교우;백승욱
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.10
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    • pp.2712-2723
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    • 1994
  • Numerical simulation of an axisymmetric ethylene-air jet diffusion flame has been carried out in order to investigate flame dynamics and soot formation. The model solves the time-dependent Navier-Stokes equations and includes models for soot formation, chemical reaction, molecular diffusion, thermal conduction, and radiation. Numerically FCT(Flux Corrected Transport) and DOM(Discrete Ordinate Method) methos are used for convection and radiation trasport respectively. Simulation was conducted for a 5 cm/sec fuel jet flowing into a coflowing air stream. The maximum flame temperature was found to be approximately 2100 K, and was located at an axial position of approximately 5 cm from the base of the flame. The maximum soot volume fraction was about $7{\times}10^{-7}$, and was located within the high temperature region where the fuel mole fraction ranges from 0.01 to 0.1. The buoyancy-driven low-frequency(12~13 Hz) structures convected along the outer region of the flame were captured. In case without radiation trasport, the maximum temperature was higher by 150 K than in case with radiation. Also the maximum soot volume fraction reached about $8{\times}10^{-6}$. As the the hydrocarbon fuel forms many soot particles, the radiation transport becomes to play a more important role.

Anti-lipid Peroxidative Principles from the Stem Bark of Kalopanax pictus Nakai

  • Choi, Jong-won;Han, Youn-Nam;Lee, Kyung-Tae;Park, Kun-Yong;Kwak, Tae-Soon;Kwon, Sang-Hyuk;Park, Hee-Juhn
    • Archives of Pharmacal Research
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    • v.24 no.6
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    • pp.536-540
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    • 2001
  • Hepatic lipid peroxide contents were examined in bromobenzene-treated rats firstly after the oral administration of MeOH extract of Kalopanax pictus stem bark its n-BuOH fraction, EtOAc fraction and an alkaline hydrolysate of the n-BuOH fraction, and secondly after the intraperitoneal administration of hederagenin monodesmosides and bisdesmosides. Two hederagenin monodesmosides, kalopanaxsaponin A (KPS-A) and sapindoside C, exhibited significant anti-lipid peroxidation effects after intraperitoneal administration at doses of $10-30{\;}{\mu}mole/kg$, whereas their bisdesmosides did not exhibit any significant activity. These results suggest that it is the hederagenin monodesmosides that are responsible for anti-lipid peroxidation in vivo. The activity of KPS-A was established by the observation of decreased aminopyrine N-demethylase activity and increased epoxide hydrolase activity.

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A Study on the Magneto-optical Properties and Application of Diluted Magnetic Semiconductor Cd1-xMnxTe (묽은 자성 반도체 Cd1-xMnxTe의 자기 광학적 특성과 응용성 연구)

  • Hwang, Young-Hun;Um, Young-Ho;Cho, Sung-Lae
    • Journal of the Korean Magnetics Society
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    • v.19 no.5
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    • pp.186-190
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    • 2009
  • We investigated the magneto-optical properties and application of diluted magnetic semiconductors Cd$_{1-x}$Mn$_x$Te crystals with various Mn contents grown using a vertical Bridgman method. This material crystallizes in the zinc-blende structure for values of x < 0.82. The band-gap energy was depended on Mn mole fraction x linearly and increased with decreasing temperature. The Faraday rotation was increased as the photon energy increased near to that of the fundamental band gap and its increased with increasing Mn mole fraction. Optical isolator using the Cd$_{0.62}$Mn$_{0.38}$Te crystal shows that the isolation and insertion loss are 45 dB and 0.35 dB at 650 nm, respectively.

A Model-Analysis for Removal of Fire Fumes in a Road Tunnel during a Fire Disaster (도로터널내 화재 발생시 매연 제거를 위한 모델 해석)

  • 윤성욱;이희근
    • Tunnel and Underground Space
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    • v.7 no.2
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    • pp.100-107
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    • 1997
  • In case of a fire outbreak in a uni-directional road tunnel, the flow of traffic immediately behind the fire disaster will be stalled all the way back to the entrance of the tunnel. Furthermore, when the vehicle passengers try to flee away from the fire toward the entrance of the tunnel, the extremely hot fume that propagates in the same direction will be fatal to the multitudes evacuating, but may also cause damage to the ventilation equipments and the vehicles, compounding the evacuation process. This paper will present the 3-dimensional modelling analysis of the preventive measures of such a fume propagation in the same direction as the evacuating passengers. For the analysis, the fire hazard was assumed to be a perfect combustion of methane gas injected through the 1 m X 2 m nozzle in the middle of the tunnel, and the product of $CO_2$ as the indicator of the fume propagation. From the research results, when the fire hazard occurred in middle of the 400 m road tunnel, the air density decreased around the fire point, and the maximum temperatures were 996 K and 499 K at 210 m and 350 m locations, respectively, 60 seconds after fire disaster occurred, when the fumes were driven out only towards the exit-direction of the tunnel. By tracing the increase of $CO_2$ level over 1% mole fraction, the minimum longitudinal ventilation velocity was found to be 2.40 m/sec. Furthermore, through Analysis of the temperature distribution graphs, and observation of the cross-sectional distribution of $CO_2$ over 1% mole fraction, it was found that the fume did not mix with the air, but rather moved far in a laminar flow towards exit of the tunnel.

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Synthesis of ion Exchange Fiber Containing Amidoxime and Phosphoric Acid Groups and Its Uranium Adsorption Properties (아미드옥심기와 인산기가 함유된 이온 교환 섬유의 합성 및 우라늄 흡착 특성)

  • 황택성;박진원
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.242-248
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    • 2003
  • PP-g-(AN/Sty) was synthesized by grafting with acrylonitrile (AN) and styrene (Sty) onto PP staple fiber using an electron beam accelerator and followed by amidoximination and phosphorylation. Mole fraction of AN in the graft chain increased with the increase of the AN content in the monomer mixture. The highest AN grafting yield of 45% was obtained at a monomer ratio of 40 vol% AN/60 vol% Sty. Mole fraction of AN in the graft chain decreased with the increase of methanol amount used its solvent. As reaction temperature increased, the grafting yield of copolymer increased and reached equilibrium at 50$^{\circ}C$. Amount of amidoxime group in fibrous ion exchanger was increased as increasing amount of hydroxylamine, and the maximum content of amidoxime group was observed at 5.8 mmol/g with the 9 wt% hydroxylamine concentration. Content of phosphorous group in fibrous ion exchanger increased up to 0.5 N phosphoric acid concentration, and then leveled off. The adsorption ability of the copolymer for uranyl ion by the chelating adsorbents was in the following order : bifunctional PP-g-(AN/sty) > amidoximated PP-g-(AN/Sty) > phosphorylated PP-g-(AN/Sty).

Synthesis and Characterization of Poly(L-lactic acid-co-glycine-L-lactic acid) and Poly - ( L-1actic acid-co-gl ycine-L-methyl 1actic acid) (생체분해성 고분자의 합성 및 물성에 관한 연구(II) -Poly (L-lactic acid-co-glycine-L-lactic acid) 와 Poly- (L-lactic acid-co-glycine-L-methyl lactic acid))

  • Sung, Yong-Kiel;Song, Dae-Kyung;Park, Kyung-Hee
    • Journal of Biomedical Engineering Research
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    • v.9 no.2
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    • pp.225-232
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    • 1988
  • Poly (L- lactic acid-co-glycine-L-lactic acid) and Poly (L-lactic acid-co-glycine-L- methyl lactic acid ) have been prepared by ring opening polymerization. The monomer 6, 6-dimethyl morpho-line-2, 5-dione was synthesized by the bromoisobutylation of 2-bromoisobutyryl bromide with glycin e. L-lactide, 6-methyl morpholine-2, 5-diode. and 6, 6-dimethyl morpholine-2, 5-diode have been used as starting materials for polydepsipeptides. The synthesized monomers and copolymers have been identified by NMR and FT-lR spa- ctrophotometer. The thermal propert ies and glass transition temperature(Tg) of the copolymers have been measured by differential scanning calorimetry. The Tg values of poly(L-lactic acid co-glycine-L-lactic acid) system are increased from $53^{\circ}C\; to\; 107^{\circ}C$ with increasing the mole fraction of 6-methyl morpholine-2, 5-diode. And the Tg values of poly(L-lactic acid co-glycine-L-methyl lactic acid) system are increased from $53^{\circ}C\;to\;138^{\circ}C$ with increasing the mole fraction of 6. 6-dimethyl morpholine-2, 5-diode The thermal stability of poly (L-lactic acid-co-glycine-L-methyl lactic acid) is slightly greta text than that of poly(L-lactic acid-co-glycine-L-lactic acid) due to the methyl group.

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