• Title/Summary/Keyword: Model gas

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Location Analysis for Developing Small Hydropower Using Geo-Spatial Information System (지형공간정보체계를 활용한 소수력 개발의 입지분석)

  • Yi, Choong-Sung;Kim, Kil-Ho;Lee, Jin-Hee;Shim, Myung-Pil
    • Journal of Korea Water Resources Association
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    • v.40 no.12
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    • pp.985-994
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    • 2007
  • Small hydropower is the one of the cleanest one among new and renewable energy with less green house gas emissions. Recently, the necessity of developing small hydropower is emerging since its remaining potential resources in this country are abundant. However, a survey or research on the small hydropower development has been hardly performed since the 1990#s. These circumstances encourages a systematic approach for the small hydropower development. The purpose of this study is to propose a methodology of the location analysis for developing small hydropower. To this end, constraint and location criteria with weights are established and quantification method of each factor is presented. Especially, the analysis procedure is established on the basis of GSIS. Also the study focus on raising the objectivity and precision of analysis by developing system model with automatic search. The proposed methodology is applied to Bochung stream in Keum Riverbasin. The result selects the four and two locations of dam type and run-of-river type respectively. This study will be beneficial to the future activation of small hydropower development as a fundamental work.

Cytotoxicity of Hyaluronic Acid Membrane Cross-linked with Lactide (락타이드로 가교시킨 히아루론산 막의 세포독성)

  • Kim, Won-Jung;Kwon, Ji-Young;Cheong, Seong-Ihl;Kim, In-Seop
    • KSBB Journal
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    • v.21 no.4
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    • pp.255-259
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    • 2006
  • The biodegradable hyaluronic acid(HA) membranes cross-linked with lactide using the crosslinking agent, 1-ethyl-3(3-dimethyl aminopropyl) carbodiimide(EDC) were prepared as a potential biocompatible material for tissue engineering. HA membranes having different mechanical properties were synthesised by varying degree of the mole ratio of lactide to HA, EDC concentration, and crosslinking temperature. HA membranes were degradable in water solution and the degradation became slower with the increasing mole ratio of lactide to HA. HA membranes were sterilized using ethylene oxide gas and extracted with cell culture medium for 24 h at $37^{\circ}C$ and 200 rpm. Cytotoxicity of the extract was tested using NIH/3T3 mouse embryo fibroblast as a model cell. Growth inhibition was not observed in the extracts of HA membranes with the mole ratios of lactide to HA, 5 or 10, and 10% EDC concentration, however 11% of growth inhibition was observed in the extract with the mole ratio of 13. Growth inhibition was not observed in the extracts of HA membranes prepared with 5% EDC or 10% EDC and the mole ratio of lactide to HA, 10, however 12% of growth inhibition was observed in the extract with 20% EDC. Cytotoxicity was not observed in the extracts of HA membranes prepared at varying crosslinking temperatures, $15^{\circ}C,\;25^{\circ}C,\;and\;28^{\circ}C$ with the mole ratio of lactide to HA, 10 and 10% EDC.

The Removal of Toluene by a Granular Activated Carbon Bioreactor using Yeast (Yeast와 입상활성탄을 이용한 미생물반응기의 휘발성유기화합물 분해 특성)

  • NamGung, Hyeong-Kyu;Shin, Seung-Kyu;Ahmed, Zubair;Song, Ji-Hyeon
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.12
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    • pp.1218-1224
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    • 2008
  • A liquid culture of yeast "Candida tropicalis" was used in a fluidized bioreactor to achieve high removal efficiencies of volatile organic compounds (VOCs). In this study, granular activated carbon (GAC) was used as a fluidized material to improve adsorptive capacity as well as mass transfer of gaseous toluene, the model VOC. The GAC fluidized bioreactor demonstrated toluene removal efficiencies ranging from 50 to 80%, when inlet toluene loading varied in a range between 13.1 and 37.4 g/m$^3$-hr. The maximum elimination capacity determined in the GAC fluidized bioreactor was 172 g/m$^3$-hr at a toluene loading of 291 g/m$^3$-hr. Transient loading experiments revealed that the removal efficiency was remained unchanged during an increased loading period, and toluene introduced to the bioreactor was first absorbed to GAC and then slowly desorbed and became available to the yeast culture. Hence the fluidized GAC helped to achieve an improved mass transfer between the gas and liquid phases, resulting in high toluene removal capacity. Consequently, the GAC fluidized bioreactor using C. tropicalis can be successfully applied for the removal of VOCs, and is a feasible alternative over conventional processes such as packed-bed biofilters.

Desorption of organic Compounds from the Simulated Soils by Soil Vapor Extraction (인공토양으로부터 토양증기추출법에 의한 유기화합물의 탈착 현상에 관한 실험 연구)

  • 이병환;이종협
    • Journal of Korea Soil Environment Society
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    • v.3 no.2
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    • pp.101-114
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    • 1998
  • Soil vapor extraction (SVE) is known to be an effective process to remove the contaminants from the soils by enhancing the vaporization of organic compounds using forced vapor flows or applying vacuum through soils. Experiments are carried out to investigate the effects of the organic contaminants, types of soils, and water contents on the removal efficiency with operating time. In the study, simulated soils include the glass bead which has no micropore, sand and molecular sieve which has a large volume of micropores. As model organic pollutants, toluene, methyl ethyl ketone, and trichloroethylene are selected. Desorption experiments are conducted by flowing nitrogen gas. Under the experimental conditions, it is found that there are linear relationships between logarithm of removal efficiency and logarithm of number of pore volumes. The number of pore volumes are defined as the total amount of air flow through the soil column divided by the pore volume of soil column. For three organic compounds studied, the removal rate is slow for no water content, while the number of pore volumes for removal of organic compounds are notably reduced for water contents up to 37%. For the removal of dense organic compound, such as trichloroethylene, a large number of pore volumes are needed. Also, the effects of the characteristics of simulated soils on the removal efficiency of organic compounds are studied. After the characterization of soil surface, porosity of soil columns and types of contaminants, the results could provide a basis for the design of SVE process.

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Effect of KOH Concentrations and Pyrolysis Temperatures for Enhancing NH4-N Adsorption Capacity of Rice Hull Activated Biochar (KOH 농도 및 탄화온도가 왕겨 활성 바이오차의 NH4-N 흡착능 향상에 미치는 영향)

  • Kim, HuiSeon;Yun, Seok-In;An, NanHee;Shin, JoungDu
    • Korean Journal of Environmental Agriculture
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    • v.39 no.3
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    • pp.171-177
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    • 2020
  • BACKGROUND: Recently, biomass conversion from agricultural wastes to carbon-rich materials such as biochar has been recognized as a promising option to maintain or increase soil productivity, reduce nutrient losses, and mitigate greenhouse gas emissions from the agro-ecosystem. This experiment was conducted to select an optimum conditions for enhancing the NH4-N adsorption capacity of rice hull activated biochar. METHODS AND RESULTS: For deciding the proper molarity of KOH for enhancing its porosity, biochars treated with different molarity of KOH (0, 1, 2, 4, 6, 8) were carbonized at 600℃ in the reactor. The maximum adsorption capacity was 1.464 mg g-1, and an optimum molarity was selected to be 6 M KOH. For the effect of adsorption capacity to different carbonized temperatures, 6 M KOH-treated biochar was carbonized at 600℃ and 800℃ under the pyrolysis system. The result has shown that the maximum adsorption capacity was 1.76 mg g-1 in the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis temperature, while its non-treated biochar was 1.17 mg g-1. The adsorption rate in the rice hull activated biochar treated with 6 M KOH at 600℃ was increased at 62.18% compared to that of the control. Adsorption of NH4-N in the rice hull activated biochar was well suited for the Langmuir model because it was observed that dimensionless constant (RL) was 0.97 and 0.66 at 600℃ and 800℃ of pyrolysis temperatures, respectively. The maximum adsorption amount (qm) and the bond strength constants (b) were 0.092 mg g-1 and 0.001 mg L-1, respectively, for the rice hull activated biochar treated with 6 M KOH at 600℃ of pyrolysis. CONCLUSION: Optimum condition of rice hull activated biochar was 6M KOH at 600℃ of pyrolysis temperature.

Adsorption of Heavy Metal onto the Extracellular Polysaccharide Produced by the Purple Nonsulfur Photosynthetic Bacteria Rhodopseudomonas sp. KH4 (홍색 비황 광합성 세균 Rhodopseudomonas sp. KH4의 Extracellular polysaccharide의 중금속 흡착)

  • Jeong, Jeong-Hwa;Seo, Pil-Soo;Kong, Sung-Ho;Lee, Jong-Yeol;Lee, Sang-Seob
    • Korean Journal of Microbiology
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    • v.42 no.4
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    • pp.326-331
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    • 2006
  • In the present study, we examined biosorption characteristics of heavy metals onto the extracellular polysaccharide (EPS) produced by the purple nonsulfur photosynthetic bacteria Rhodopseudomonas sp. KH4, which was isolated from a stream in Anyang, Kyonggi-Do. When Cd (100 mg/L) and Cu (100 mg/L) were added to EPS (1.0 g/L) in the optimal condition (Cd; pH 8, Cu; pH 5, $40^{\circ}C$), 84.2 mg/L of Cd and 70.0 mg/L of Cu were adsorbed within 30 min and 10 min, respectively. When 100 mg/L of Cd and Cu were present as mixture, 16.8 mg/L of Cd and 48.7 mg/L of Cu were adsorbed at $25^{\circ}C$, pH 5. The maximum adsorption capacity determined by fitting Langmuir isotherms model was suitable for describing the biosorption of Cd (76.9 mg/g) and Cu (67.1 mg/g) by EPS. The neutral monosaccharide in the EPS determined by GC consisted of arabinose (2.4%), glucose (7.1%) and mannose (90.5%).

The Correlation Between Deltamethrin Exposure and Urinary 3-PBA Concentrations in Rats (Deltamethrin에 노출된 흰쥐의 뇨 중 3-PBA 검출 및 노출상관성)

  • Kim, Areumnuri;Chon, Kyongmi;Park, Kyung-Hun;Moon, Byeong-Chul;Ro, Jin-Ho;Paik, Min Kyoung
    • Korean Journal of Environmental Agriculture
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    • v.36 no.4
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    • pp.293-298
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    • 2017
  • BACKGROUND: Pyrethroids (PYRs) are a widely used insecticide in agriculture and household area. In mammals, PYRs such as deltamethrin is metabolized to 3-phenoxybenzoic acid (3-PBA) in liver that is mainly excreted in urine. This study is designed to single exposure of deltamethrin to rats in a dose-dependent manner and identify the correlation between deltamethrin exposure and its metabolite (3-PBA) in urine. METHODS AND RESULTS: Exposure levels of deltamethrin were control (0 mg/kg bw), low (0.0705 mg/kg bw), medium (0.705 mg/kg bw) and high (7.05 mg/kg bw) dose. Low concentration was derived by ussing Korea predictive operator exposure model (KoPOEM). Dermal exposure persisted for 6 h, and urine specimens were collected for 24 h. The urine matrix was removed after a series of procedures and 3-PBA was analyzed by gas chromatography/mass spectrometry. CONCLUSION: There was a strong correlation ($R^2=0.83$) between the amount of oral exposure to delta me thrin and urinary levelof3-PBAexcreted. In dermal exposure groups of deltamethrin except high-dose, also there was a good correlation between urinary 3-PBA and deltamethrin exposure, but not stronger than in oral deltamethrin exposure groups. Based on these results, therefore, the amount of 3-PBA in urine can be used as a good monitoring indicator that reflexing the exposure level of deltamethrin to human body.

The Effect of Residual Water on the Adsorption Process of Carbon Tetrachloride by Activated Carbon Pellet (활성탄에 의한 사염화탄소 흡착공정에서 잔존수분의 영향)

  • Jeong, Sung Jun;Lee, Dae Lo;Kim, Tae Young;Kim, Jin Hwan;Kim, Seung Jai;Cho, Sung Young
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.694-702
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    • 2002
  • Activated carbons have been used as adsorbents in various industrial application, such as solvent recovery, gas separation, deodorization, and catalysts. In this study, the effects of residual water on the activated carbon adsorbent surface on the adsorption capacity of $CCl_4$ were investigated. Adsorption behavior in a fixed bed was studied in terms of feed concentration, flow rate, breakthrough curve and adsorption capacity for $CCl_4$. Desorption characteristics of residual water on activated carbon were also studied. The water contents of the activated carbon were varied in the range of 0-20%(w/w) and all experiments were performed at 298.15 K. The adsorption equilibrium data $CCl_4$ on the activated carbon were well expressed by Langmuir isotherm. The adsorption capacity of $CCl_4$ decreased with increasing residual water content. Desorption of residual water in activated carbon decreased expotentially with $CCl_4$ adsorption. The obtained breakthrough curves using LDF(linear driving force) model represented our experimental data.

A meta analysis of the climate change impact on rice yield in South Korea (기후변화가 국내 쌀 생산량에 미치는 영향에 대한 메타분석)

  • Shin, Deok Ha;Lee, Mun Su;Park, Ju-Hyun;Lee, Yung-Seop
    • Journal of the Korean Data and Information Science Society
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    • v.26 no.2
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    • pp.355-365
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    • 2015
  • As the global climate has dramatically changed over the past decades, there has been active research on evaluating its effects on food security, which has been recognized as one of the most important issues in the field. In this study, we analyzed the impact of the climate change on the Korean agriculture using meta-analysis methods. Especially, our research focus is on estimating the effect of CO2 concentration and two adaptations (planting-date and cultivar adjustments)on rice that accounts for a larger proportion of the Korean domestic agriculture. Unlike traditional general meta-analysis methods that use summary statistics of effects of interest, meta analysis specific to the agriculture literature was conducted by integrating the data on rice yield that were generated under various CO2 emission scenarios and general circulating models of the 6 collected individual studies. As a modeling approach, the rice yield change ratio was set as the dependent variable and the main and interaction effects of CO2 concentration and adaptation were considered as independent variables in a regression model, As a result, CO2 is estimated to have opposite effects on rice yield depending on whether any of the two adaptations is applied or not; decreasing effect without adaptation and increasing effect with adaptation. In addition, it turns out that the cultivar adjustment has a higher increasing effect on rice yield than the planting-date adjustment. The results of the study are expected to be used as basic quantitative data for establishing responsive polices to the future climate changes.

Effects of dietary forage-to-concentrate ratio on nutrient digestibility and enteric methane production in growing goats (Capra hircus hircus) and Sika deer (Cervus nippon hortulorum)

  • Na, Youngjun;Li, Dong Hua;Lee, Sang Rak
    • Asian-Australasian Journal of Animal Sciences
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    • v.30 no.7
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    • pp.967-972
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    • 2017
  • Objective: Two experiments were conducted to determine the effects of forage-to-concentrate (F:C) ratio on the nutrient digestibility and enteric methane ($CH_4$) emission in growing goats and Sika deer. Methods: Three male growing goats (body weight $[BW]=19.0{\pm}0.7kg$) and three male growing deer ($BW=19.3{\pm}1.2kg$) were respectively allotted to a $3{\times}3$ Latin square design with an adaptation period of 7 d and a data collection period of 3 d. Respiration-metabolism chambers were used for measuring the enteric $CH_4$ emission. Treatments of low (25:75), moderate (50:50), and high (73:27) F:C ratios were given to both goats and Sika deer. Results: Dry matter (DM) and organic matter (OM) digestibility decreased linearly with increasing F:C ratio in both goats and Sika deer. In both goats and Sika deer, the $CH_4$ emissions expressed as g/d, g/kg $BW^{0.75}$, % of gross energy intake, g/kg DM intake (DMI), and g/kg OM intake (OMI) decreased linearly as the F:C ratio increased, however, the $CH_4$ emissions expressed as g/kg digested DMI and OMI were not affected by the F:C ratio. Eight equations were derived for predicting the enteric $CH_4$ emission from goats and Sika deer. For goat, equation 1 was found to be of the highest accuracy: $CH_4(g/d)=3.36+4.71{\times}DMI(kg/d)-0.0036{\times}neutral$ detergent fiber concentrate (NDFC,g/kg)+$0.01563{\times}dry$ matter digestibility (DMD,g/kg)-$0.0108{\times}neutral$ detergent fiber digestibility (NDFD, g/kg). For Sika deer, equation 5 was found to be of the highest accuracy: $CH_4(g/d)=66.3+27.7{\times}DMI(kg/d)-5.91{\times}NDFC(g/kg)-7.11{\times}DMD(g/kg)+0.0809{\times}NDFD(g/kg)$. Conclusion: Digested nutrient intake could be considered when determining the $CH_4$ generation factor in goats and Sika deer. Finally, the enteric $CH_4$ prediction model for goats and Sika deer were estimated.