• 제목/요약/키워드: Mode shift

검색결과 444건 처리시간 0.033초

Photophysical Properties of a Conjugated Poly(1-dodecyl-2,5-pyrrylene vinylene)

  • Park, Chang-Shik;Kim, In-Tae;Lee, Sang-Woo;Lee, Ha-Hyeong;Lee, Young-Nam;Jeon, Ki-Seok;Lee, Ki-Hwan;Sung, Nack-Do;Kil, Mun-Jae
    • Macromolecular Research
    • /
    • 제12권3호
    • /
    • pp.322-324
    • /
    • 2004
  • Poly(1-dodecyl-2,5-pyrrylene vinylene) (PDPV) has an extended 1t-conjugated structure and exhibits characteristic spectroscopic features. The PDPV we prepared has an absorption maximum at 510nm and its long absorption tail at ca. 750nm in methylene chloride is due to the long 1t-conjugated system connected to vinyl group. The large red-shift of emission was 625nm upon excitation at 480nm, which suggests the existence of a low emissive state. The emission of PDPV in less-polar solvents decreased markedly relative to that in the more-polar solvents; this observation was ascribed possibly to quenching by a strong vibrational mode of the dodecyl groups of PDPV in less-polar solvents. Furthermore, the emission from the high-energy side had a single decay component (0.1㎱, 49.96%), while that from the low-energy side had two components (0.6㎱, 27.1 %; 2.7㎱, 22.87%). We characterized the redox properties of PDPV by cyclic voltammetry. Every redox peak showed irreversible behavior; the oxidation peaks appeared at 1.7,0.8, and 0.6V and the reduction peak at -0.5V.

안테나 배열을 사용하는 통신 시스템을 위한 일반화된 벡터 채널 모델과 공간 채널 시뮬레이터의 구현 (Generalized Vector Channel Model for Communication Systems Using Antenna Arrays and Implementation of the Spatial Channel Simulator)

  • 오성근;류원형
    • 한국통신학회논문지
    • /
    • 제25권3B호
    • /
    • pp.408-422
    • /
    • 2000
  • 본 논문에서는 안테나 배열을 사용하는 통신시스템을 위한 일반화된 벡터 채널 모델을 제안한다. 제안된 채널 모델에서는 실제적인 채널에서 발생할 수 있는 경로 감쇄, 전파 음영(shadowing)의 시간-공간적인 변화, 다중경로 페이딩, 도플러현상, 국지적인 산란체(scatterer)들의 공간적인 분포와 지배적인 원격 산란체들에 의한 지연 확산을 고려한다. 실제적인 채널 환경을 반영하기 위하여 이산 경로 모델을 사용하며, 각각의 이산 경로 신호는 독립적인 전파 음영과 페이딩, 도플러 영향을 받으며, 서로 다른 입사각을 가지고 안테나 배열에 수신된다. 제안된 모델을 바탕으로 수신되는 신호들에 대한 시간-공간적인 상관값에 대한 관계식을 유도하고, 공간 채널 시뮬레이터를 구성한다. 이론적인 상관값과 시뮬레이터를 통하여 얻은 결과를 비교함으로써 시뮬레이터의 유효성을 검증하고, 구성된 시뮬레이터를 사용하여 다양한 채널 환경하에서의 채널 특성의 변화를 분석한다.

  • PDF

Aluminium Distearate 첨가가 $UO_2$ 핵연료 제조에 미치는 영향 (Effect of the Addition of Aluminium Distearate on Manufacturing of $UO_2$ Nuclear Fuel)

  • 박지연;정충환;김영석
    • 한국세라믹학회지
    • /
    • 제29권8호
    • /
    • pp.609-616
    • /
    • 1992
  • This study has been investigated on the milling of Aluminium Distearate (ADS) powder and characteristics of the ADS-doped UO2 pellets. As-received ADS powder of the agglomerated particles has not shown any milling effect because of heat generated during planetary milling. But the use of coolant to effectively remove heat generated during milling has been found an effective way in breaking up the agglomerates of ADS powder. The green density of the UO2 pellet decreases with the amount of ADS powder doped. Therefore, in order to get the sintered density of 95% pellet decreases with the amount of ADS powder doped. Therefore, in order to get the sintered density of 95% theoretical density, the 200 ppm ADS-doped UO2 pellet has to be pressed under higher compacting pressure of 3500~4000 kgf/$\textrm{cm}^2$ compared with the ADS-undoped UO2 pellet pressed under around 3000 kgf/$\textrm{cm}^2$. The ADS-dpoed UO2 pellet with even relatively low sintered density of 10.27 g/㎤ exhibits open porosity of 1% while open porosity of the ADS-undoped UO2 pellet is reduced to around 1% only after its sintered density increases to 10.43g/㎤. It is, therefore, concluded that doping of ADS powder significantly contributes to the decrease in open porosity of the UO2 pellet. The dilatometry of the ADS doped UO2 pellet shows the sintering rate curve with the bimodal mode, which could be attributed to a phase reaction between UO2 and ADS. The X-ray diffraction analysis indicates that there occurs not any new phase formed but the shift of the peaks. It would be expected that a phase reaction resulting in solid solution would happen in the temperature range of 130$0^{\circ}C$ to 150$0^{\circ}C$ between UO2 and ADS.

  • PDF

다층형 결합 선로를 이용한 반송파 복원 회로 설계 제작 (Design and fabrication of PSK carrier recovery circuit using multi-layer coupled line)

  • 김영완
    • 한국정보통신학회논문지
    • /
    • 제13권10호
    • /
    • pp.2039-2044
    • /
    • 2009
  • 본 논문에서는 다층형 결합 선로를 이용한 PSK 반송파 신호 복원 회로를 해석하고 설계 제작한다. 다층형 결합 선로 구조의 coupled line으로 구성되는 반송파 복원 6단자 소자는 다층형 구조를 가지며, 수신 전처리부의 6 단자 위상 상관기 구조와 동일한 구조를 갖는 일원화된 수신 구조 구현이 가능하다. 아울러 다층 결합 선로 6 단자 위상 상관기를 이용한 RML 기반 다중 모드 동기 복조형 반송파 신호 복원이 가능한 다층형 결합 선로 반송파 복원 회로 구조를 제안한다. 설계 제작된 다층형 결합 선로 구조 반송파 복원회로에 의한 직교 위상편이 방식 신호의 반송파 신호는 일정한 위상값과 반사 소자에 의해 발생되는 ${\pm}3o$ 이내인 위상차를 갖는 양호한 PSK 반송파 신호 특성을 나타내었다.

중성점전압보상 방식을 이용한 브러시리스직류전동기의 회전자위치 추정 (A Rotor Position Estimation of Brushless DC Motors using Neutral Voltage Compensation Method)

  • 송중호
    • 전력전자학회논문지
    • /
    • 제9권5호
    • /
    • pp.491-497
    • /
    • 2004
  • 본 논문은 브러시리스직류전동기의 새로운 회전자위치추정 방법에 관한 것이다. 회전자 위치추정이 부정확하게 이루어졌을 때, 역기전력과 상전류 사이의 위상차가 나타나고 이는 다시 전동기의 토크리플을 일으킨다는 사실은 알려져 있다. 이러한 추정오차를 줄이기 위하여 인버터의 정상모드 기간 중에 나타나는 중성점전압을 기반으로 하는 새로운 방법을 제안하고 있다. 이 중성점전압이 효과적인 회전자 위치 추정오차의 한 지표임을 확인하고, 중성점전압의 발생, 획득방법, 보상방법 등을 다루고 있다. 본 알고리즘은 전동기 단자전압센서와 단일 직류링크 전류센서 만을 이용하여 실현할 수 있으며, 관련 시뮬레이션 및 실험결과는 그 타당성을 보여주고 있다.

2D 텐서 보팅에 기반 한 손상된 텍스트 영상의 복원 및 분할 (Corrupted Region Restoration based on 2D Tensor Voting)

  • 박종현;;이귀상
    • 정보처리학회논문지B
    • /
    • 제15B권3호
    • /
    • pp.205-210
    • /
    • 2008
  • 본 논문에서는 잡음에 의해 손상된 텍스트 영상으로부터 복원 및 분할을 위한 새로운 접근 방법을 제안한다. 제안된 방법은 손상된 영역의 복원을 위하여 색상 및 비색상 성분을 2차 대칭 스틱 텐서로 표현하고 보팅 기반의 손상된 영역을 복원하였으며, 마지막으로 클러스터링 방법에 의해 분할을 수행한다. 먼저 우리는 제안된 색상 선택함수에 의해 잡음에 강건한 색상과 비색상 성분을 선택한다. 두 번째 단계에서는 각각의 선택된 특징 벡터들은 스틱 텐서로 표현하였으며 제한된 보팅 커널의 필드내에서 이웃하는 보터들과 통신을 통하여 새롭게 정의된다. 따라서 2차 보팅 후 각각의 스틱 텐서는 이웃하는 텐서와 같은 특성을 가지며 손상된 영역들을 복원할 수 있다. 마지막으로 복원된 영상의 성능을 평가하기 위하여 적응적 평균 이동 알고리즘과 클러스터링 알고리즘을 이용하여 영상 분할을 수행하였다. 실험에서 제안된 방법은 전체적인 처리과정을 자동적으로 수행 가능하였으며 배경 및 객체의 영역에서 효율적인 복원 및 분할을 수행할 수 있었다.

Fabrication and Characterization of InGaN/GaN LED structures grown on selectively wet-etched porous GaN template layer

  • Beck, Seol;Cho, Yong-Hoon
    • 한국진공학회:학술대회논문집
    • /
    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
    • /
    • pp.124-124
    • /
    • 2010
  • Much interest has been focused on InGaN-based materials and their quantum structures due to their optoelectronics applications such as light emitting diode (LED) and photovoltaic devices, because of its high thermal conductivity, high optical efficiency, and direct wide band gap, in spite of their high density of threading dislocations. Build-in internal field-induced quantum-confined Stark effect in InGaN/GaN quantum well LED structures results in a spatial separation of electrons and holes, which leads to a reduction of radiative recombination rate. Therefore, many growth techniques have been developed by utilizing lateral over-growth mode or by inserting additional layers such as patterned layer and superlattices for reducing threading dislocations and internal fields. In this work, we investigated various characteristics of InGaN multiple quantum wells (MQWs) LED structures grown on selectively wet-etched porous (SWEP) GaN template layer and compared with those grown on non-porous GaN template layer over c-plane sapphire substrates. From the surface morphology measured by atomic force microscope, high resolution X-ray diffraction analysis, low temperature photoluminescence (PL) and PL excitation measurements, good structural and optical properties were observed on both LED structures. However, InGaN MQWs LED structures grown on SWEP GaN template layer show relatively low In composition, thin well width, and blue shift of PL spectra on MQW emission. These results were explained by rough surface of template layer, reduction of residual compressive stress, and less piezoelectric field on MQWs by utilizing SWEP GaN template layer. Better electrical properties were also observed for InGaN MQWs on SWEP GaN template layer, specially at reverse operating condition for I-V measurements.

  • PDF

Understanding Neurogastroenterology From Neuroimaging Perspective: A Comprehensive Review of Functional and Structural Brain Imaging in Functional Gastrointestinal Disorders

  • Kano, Michiko;Dupont, Patrick;Aziz, Qasim;Fukudo, Shin
    • Journal of Neurogastroenterology and Motility
    • /
    • 제24권4호
    • /
    • pp.512-527
    • /
    • 2018
  • This review provides a comprehensive overview of brain imaging studies of the brain-gut interaction in functional gastrointestinal disorders (FGIDs). Functional neuroimaging studies during gut stimulation have shown enhanced brain responses in regions related to sensory processing of the homeostatic condition of the gut (homeostatic afferent) and responses to salience stimuli (salience network), as well as increased and decreased brain activity in the emotional response areas and reduced activation in areas associated with the top-down modulation of visceral afferent signals. Altered central regulation of the endocrine and autonomic nervous responses, the key mediators of the brain-gut axis, has been demonstrated. Studies using resting-state functional magnetic resonance imaging reported abnormal local and global connectivity in the areas related to pain processing and the default mode network (a physiological baseline of brain activity at rest associated with self-awareness and memory) in FGIDs. Structural imaging with brain morphometry and diffusion imaging demonstrated altered gray- and white-matter structures in areas that also showed changes in functional imaging studies, although this requires replication. Molecular imaging by magnetic resonance spectroscopy and positron emission tomography in FGIDs remains relatively sparse. Progress using analytical methods such as machine learning algorithms may shift neuroimaging studies from brain mapping to predicting clinical outcomes. Because several factors contribute to the pathophysiology of FGIDs and because its population is quite heterogeneous, a new model is needed in future studies to assess the importance of the factors and brain functions that are responsible for an optimal homeostatic state.

신역사주의적 극장성의 재고(再考) -17세기 중반 뉴스북과 플레이릿 연구를 중심으로 (What's happening to theatricality after the rise of New Historicism?: A Study of Newsbooks and Playlets During the English Civil Wars and Their Significance as Textual and Theatrical Forms)

  • 최재민
    • 영어영문학
    • /
    • 제58권2호
    • /
    • pp.279-304
    • /
    • 2012
  • Since the publication of Foucault's Discipline and Punish, theatricality has become one of the key concepts in New Historicism. By defining theatricality as the most definitive feature of early modern society and culture, New Historicists have promoted the idea that theatrical practices in every day life were eventually replaced by textual practices as the western society started to undergo modernization with the advent of print culture and technologies. This paper questions this linear model of English literature, the shift of literary practices from theatricality to textuality in the event of modernization, by closely looking at the ways in which newsbooks and playlets during the English civil wars appealed to their target readers. The early print-based literary commodities during the English civil war (i.e. newsbooks and playlets) were able to win the attention of their audience not by breaking away from theatrical energy and creativity but instead by embracing and taking advantage of them through the use of dramatic conventions, dialogues, and many others. The newsbooks and the playlets during the time, however, did not simply replicate the dramatic forms and experiences of the previous generation. Instead, as the case study of Craftie Cromwell exemplifies, they went further to produce a different mode of theatricality by reshaping everyday lives into serialized drama, whose resolution is always already delayed and postponed into the ever-receding future. In conclusion, the study of the newsbook and playlets during the civil wars suggests that the textuality of modern times, materialized in print forms, have been co-evolved with the development of new theatricality, whose contents and forms are susceptible to the changes of everyday reality.

21톤급 휠 굴착기용 트랜스미션의 기어 트레인에 대한 강도 해석 (Strength Analysis of Complex Gear Train for Transmission of 21-Ton Grade Wheel Excavator)

  • 이준희;배명호;조연상
    • Tribology and Lubricants
    • /
    • 제38권5호
    • /
    • pp.179-184
    • /
    • 2022
  • The power train of transmission for 21-ton grade wheel excavator makes use of a complex gear train composed of a planetary and helical gear system to drive the wheel excavator by transmitting power to the axle. The complex gear train with a shift mode is an important part of the transmission because of strength problems in an extreme environment. To calculate the specifications of the complex gear train and analyze the gear bending and compressive stresses of the complex gear train, this study analyzes gear bending and compressive stresses accurately for the optimal design of the complex gear train with respect to cost and reliability. In this article, the gear bending and compressive stresses of the complex gear train are calculated using the Lewes and Hertz equation. Evaluating the results with the data of the allowable bending and compressive stress from the stress and number of cycles curves of the gears verified the calculated specifications of the complex gear train. A computer structure analysis is performed with the 3D model of the planetary and helical gears to analyze the structure strength of the complex gear train. The results demonstrate that the durability and strength of the complex gear train are safe, because the safety factors of the bending and compressive stresses are more than 1.0.