• 제목/요약/키워드: Mo alloys

검색결과 236건 처리시간 0.022초

고온 용융염에서 Fe기 및 Ni기 초합금의 부식거동 및 합금원소의 영향 (Corrosion Behavior and Effect of Alloying Elements of Fe-base and Ni-base Superalloys on Hot Molten Salt)

  • 조수행;장준선;정명수;오승철;신영준
    • 한국재료학회지
    • /
    • 제9권10호
    • /
    • pp.985-991
    • /
    • 1999
  • Incoloy 800H, KSA (Kaeri Superalloy)-6, Inconel 600 및 Hastelloy C-276 합금의 용융염에서의 부식거동을 650~85$0^{\circ}C$ 온도범위에서 조사하였다. LiCl-Li$_2$O혼합용융염에서의 부식은 Li$_2$O에 의한 염기성 용해 기구에 의해 진행되며, 부식속도가 LiCl에서보다 훨씬 빠르게 나타났다. 혼합용융염 LiCl-Li$_2$O에서는 Ni기 합금의 부식속도가 Fe기 합금보다 빠르고, Mo와 W의 함량이 높은 Hastelloy C-276이 가장 빠른 부식속도를 나타내었다. 용융염 LiCl에서는 LiCrO$_2$의 단일 부식층이 형성되고, LiCl-Li$_2$O 혼합용융염에서는 산화물과 Ni의 2상구조의 다공성 부식층이 형성되었다.

  • PDF

Fe-P-(Mo,Mn)계 소결분말 합금에서 Si 첨가에 따른 기계적 특성 변화에 대한 연구 (Mechanical Properties of Fe-P-(Mo,Mn) Sintered Alloy Related with Si Contents)

  • 정우영;박동규;고병현;박진우;안인섭
    • 한국분말재료학회지
    • /
    • 제23권5호
    • /
    • pp.397-401
    • /
    • 2016
  • A lean alloy is defined as a low alloy steel with a minimum amount of the alloying element that maintains the characteristics of the sintered alloy. It is well known that the addition of elements such as Cr, P, Si, or Mn improves the mechanical characteristics of the alloy, but decreases the sinterability. The mother alloy is used to avoid an oxidation reaction with the alloying elements of Cr, P, Si or Mn. The purpose of this study is to determine the change in the mechanical properties of Fe-P-Mo and Fe-P-Mn alloys as a result of the addition of Si. In this article, the Fe-P-Mo and Fe-P-Mn alloys to which Si is added are compacted at $7.0g/cm^3$ and then sintered in $H_2-N_2$ at $1120^{\circ}C$. The P around the macropores and large grains reduces due to the formation of $SiO_2$ as the Si content increases. This is caused by the increase in strength owing to reducing intergranular fracture by suppressing the reaction with oxygen.

Effect of Alloying Elements on the Thermal Creep of Zirconium Alloys

  • Cheol Nam;Kim, Kyeong-Ho;Lee, Myung-Ho;Jeong, Yong-Hwan
    • Nuclear Engineering and Technology
    • /
    • 제32권4호
    • /
    • pp.372-378
    • /
    • 2000
  • The effect of alloying elements on the creep resistance of Zr alloys was investigated using thermal creep tests that were performed as a part of advanced fuel cladding development. The creep tests were conducted at 40$0^{\circ}C$ and 150 MPa for 240 hr. A statistical model was derived from the relationship between the steady-state creep rate and the content of individual alloying elements. The creep strengthening effect decreased in the following sequence : Nb, Sn, Mn, Cr, Mo, Fe and Cu. The high creep resistance of Sn and the opposite effect of Fe on zirconium alloys seem to be associated with their lowering and enhancing, respectively, the self-diffusivity of the zirconium matrix.

  • PDF

마찰교반접합된 알루미늄 합금의 내식 특성에 관한 연구 동향 (Researches in Corrosion Resistance of Friction Stir Welded Aluminum alloys)

  • 안병욱;최돈현;연윤모;정승부
    • Journal of Welding and Joining
    • /
    • 제31권2호
    • /
    • pp.21-25
    • /
    • 2013
  • Aluminum alloys have been considered for substantial use in these industries. This ensues from their attractive strength to weight ratio, superb formability, apposite weldability and acceptable corrosion resistance. Depending on the specific application, corrosion behavior is a significant factor of a welded joint. In this study, recent researches in the view of corrosion resistance of friction stir welded aluminum alloys are briefly reviewed.

Stress Corrosion Cracking of Alloys 600, 690, and 800 in a Tetrathionate Solution at $340^{\circ}C$

  • Lee, Eun-Hee;Kim, Kyung-Mo
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
    • /
    • pp.587-588
    • /
    • 2006
  • The stress corrosion cracking (SCC) susceptibility of Alloy 600 MA, Alloy 600 TT, Alloy 800, and Alloy 690 TT were investigated in a deaerated 0.01 M solution of sodium tetrathionate using reverse u-bend test samples at $340^{\circ}C$. The results showed that SCC occurred in all alloys, excluding Alloy 690 TT. The SCC susceptibility decreased with an increase in the chromium content of the alloys. The results of the deposits and spectra taken from an energy dispersive X-ray system confirmed the existence of a reduced sulfur causing SCC.

  • PDF

펄스전류 가열에 의한 나노구조의 (Ti,Mo)C 합성과 동시 급속소결 및 기계적 성질 (Simultaneous Synthesis and Rapid Consolidation of Nanostructured (Ti,Mo)C and Its Mechanical Properties)

  • 조형곤;권한중;손인진
    • 한국재료학회지
    • /
    • 제23권11호
    • /
    • pp.620-624
    • /
    • 2013
  • Nanocrystalline materials have recently received significant attention in the area of advanced materials engineering due to their improved physical and mechanical properties. A solid-solution nanocrystalline powder, (Ti,Mo)C, was prepared via high-energy milling of Ti-Mo alloys with graphite. Using XRD data, the synthesis process was investigated in terms of the phase evolution. Rapid sintering of nanostuctured (Ti,Mo)C hard materials was performed using a pulsed current activated sintering process (PCAS). This process allows quick densification to near theoretical density and inhibits grain growth. A dense, nanostructured (Ti,Mo)C hard material with a relative density of up to 96 % was produced by simultaneous application of 80 MPa and a pulsed current for 2 min. The average grain size of the (Ti,Mo)C was lower than 150 nm. The hardness and fracture toughness of the dense (Ti,Mo)C produced by PCAS were also evaluated. The fracture toughness of the (Ti,Mo)C was higher than that of TiC.

방전 플라즈마 소결법으로 제작한 Mo-Cu 합금의 열적, 전기적 특성 (A Study on the Thermal and Electrical Properties of Fabricated Mo-Cu Alloy by Spark Plasma Sintering Method)

  • 이한찬;이붕주
    • 전기학회논문지
    • /
    • 제66권11호
    • /
    • pp.1600-1604
    • /
    • 2017
  • Mo-Cu alloys have been widely used for heat sink materials, vacuum technology, automobile and many other applications due to their excellent physical and electronic properties. Especially, Mo-Cu composites with 5~20 wt% copper are widely used for the heavy duty service contacts due to their excellent properties like low coefficient of thermal expansion, wear resistance, high temperature strength and prominent electrical and thermal conductivity. In most of the applications, high dense Mo-Cu materials with homogeneous microstructure are required for high performance, which has led in turn to attempts to prepare ultra-fine and well-dispersed Mo-Cu powders in different ways, such as spray drying and reduction process, electroless plating technique, mechanical alloying process and gelatification-reduction process. However, most of these methods were accomplished at high temperature (typically degree), resulting in undesirable growth of large Cu phases; furthermore, these methods usually require complicated experimental facilities and procedure. In this study, Mo-Cu alloying were prepared by planetary ball milling (PBM) and spark plasma sintering (SPS) and the effect of Cu with contents of 5~20 wt% on the microstructure and properties of Mo-Cu alloy has been investigated.

Ti(C, N)계 써메트의 유심구조 형성거동 (Formation of a Core/Rim Structure in Ti(C, N)-based Cermets)

  • 김석환
    • 한국분말재료학회지
    • /
    • 제13권1호
    • /
    • pp.10-17
    • /
    • 2006
  • Model experiment was introduced to obtain the formation of a core/rim structure by only liquid phase reaction in Ti(C, N)-based cermet alloys. Infiltrated Ti(C, N)-Ni, $MO_2C-Ni$, and TaC-Ni cermets were bonded to sandwiched specimen by heat treatment $1450^{\circ}C$ for 5hr. With nitrogen addition, both (Ti, Mo) (C, N) and (Ti, Ta) (C, N) rim structure was nucleated around comer of cuboidal Ti(C, N) core. However, equilibrium shapes of(Ti, Mo) (C, N) and (Ti, Ta) (C, N) rim were different possibly due to the effect of interface energy. The core/rim and rim! binder interfaces were parallel to each other with TaC addition, while rotated to each other with $MO_2C$ addition.

페라이트계 스테인레스 주강의 고온강도에 관한 연구 (A Study on the High Temperature Strength of Ferritic Stainless Cast Steels)

  • 안수정;강미리;서도수;김용현;이광학;김흥식
    • 한국주조공학회지
    • /
    • 제18권6호
    • /
    • pp.563-569
    • /
    • 1998
  • A Study on microstructure and elevated temperature strength of 18Cr-2Mo ferritic stainless steel castings strengthened by alloying small amounts of titanium and carbon, has been conducted. The morphology of titanium carbides showed spherical in shape and their distribution depended on the amount of alloying elements. Maximum density ($7{\times}10^5/cm^2$) of titanium carbides has been formed in the alloy containing 2.0 wt.% titanium and 0.5 wt.% carbon as alloying elements and the size of carbide particles is in the range of 0.5 to $3.0\;{\mu}m$. High temperature tensile and fatigue strength of this alloy were the highest among the alloys tested in this research. The fracture mode of the alloys containing alloying elements less that 2.0 wt.% titanium and 0.5 wt.% carbon showed intercrystalline fracture at room temperature, while the alloys containing higher amounts of alloying elements showed transcrystalline fracture. All of the alloys showed creep or ductile rupture mode at elevated temperature.

  • PDF

Degassing 조건이 Ni-Cr 합금의 도재결합력에 미치는 영향 (EFFECT OF DEGASSING CONDITION ON CERAMIC BOND STRENGTH OF Ni-Cr ALLOYS)

  • 이은화;전영찬;정창모;임장섭
    • 대한치과보철학회지
    • /
    • 제38권4호
    • /
    • pp.461-471
    • /
    • 2000
  • This study evaluated the effect of degassing on the ceramic bond strength of two Ni-Cr alloys under varying holding time at the upper limit temperature and atmospheric conditions. Metal specimens were divided into 5 groups for each alloy according to degassing conditions prior to porcelain application no degassing, degassing under vacuum without hold, degassing under vacuum with hold for 5 min. and 10 min. respectively at the upper limit temperature and degassing in air. Total number of metal ceramic specimens was eighty and each group had eight specimens. The ceramic bond strength was measured by four-point flexural test using Instron and the fractured surface was examined under SEM. The results obtained were as follows. 1. Degassing in air improved the ceramic bond strength of Ni-Cr alloys. 2. In degassing under vacuum, hold at the upper limit temperature was advantageous to the ceramic bonding of Ni-Cr alloys. 3. After ceramic metal bond test, metal surfaces were partially covered with the thin porcelain layer, and the cohesive failures in porcelain were predominant in groups showing higher ceramic bond strength.

  • PDF