• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.616-624
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• 2011

Hydrogen storage and release of Fe/Zr/Mo mixed oxide mediums were investigated by hydrogen reduction and water splitting oxidation($Fe_3O_4+4H_2{\rightleftharpoons}3Fe+4H_2O$). As the results of TPR/O, Mo was an additive to enhance the reactivity of water splitting oxidation as well as the stability of the medium. On the other hand, it seemed that $ZrO_2$ additive provided the passway for the diffusion of gaseous chemicals on the medium in repeated redox cycles. Among the Fe/Zr/Mo mediums, a FeZrMo-7 medium (Fe/Zr/Mo=80/13/7mol%) exhibited the best performance with good durability during five repeated redox cycles. The amount of hydrogen evolved on the medium was maintained at ca. 10.7mmol-$H_2$/g-medium corresponding to the hydrogen storage amount of ca. 2.2wt%.

• 한국윤활학회:학술대회논문집
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• 한국윤활학회 1997년도 제26회 추계학술대회
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• pp.93-99
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• 1997

High Temperature wear behavior of plasma sprayed ZrO$_2$ and MoS$_2$, $Fe_2O_3$ coatings were investigated for high temperature wear resistance applications. The MoS$_2$, $Fe_2O_3$ added powders containing 2.5, 5.0, 7.5, 10.0 mol% of $MoS_2$, $Fe_2O_3$ for plasma spray were made by spray drying method. Wear test were performed at temperature ranges from room temperature to 600$\circ$C. The microstructural change of coatings and the worn. surface were examined by SEM and XRD. In ZrO$_2$ coating, the coefficient of friction and wear amount of room temperature to 400$\circ$C was increased with temperature and decreased with temperature over 400$\circ$C. The coefficient of friction and wear amount of MoS$_2$ added coatings were increased with temperature, but those of $Fe_2O_3$ added coatings had lower coefficient of friction and higher wear resistance than ZrO$_2$ coating.

• 한국결정성장학회지
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• 제18권1호
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• pp.5-9
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• 2008

코디어라이트는 낮은 열팽창계수를 가지나, 디젤 배기가스 담체로써 사용하기에는 기계적 강도가 낮고, 황에 대한 내산성이 취약한 문제를 가지고 있다. 본 연구에서는 $SiO_2,\;Al_2O_3$, MoOx, $Cr_2O_3$ 및 $Nb_2O_5$가 첨가된 $ZrTiO_4$의 물성을 XRD, SEM, UTM 및 열팽창계수 측정 장치를 사용하여 측정하고 분석하였다. $ZrTiO_4$은 $TiO_2$와 $ZrO_2$를 출발원료로 볼빌에서 혼합한 후 $1240^{\circ}C$ 이상의 온도에서 3시간 하소함으로써 monoclinic 구조로 합성되었다. 꺽임강도 및 열팽창계수 측정용 시편은 $ZrTiO_4$와 첨가제를 혼합 성형하고, $1300^{\circ}C$에서 3 시간 소성함으로써 얻어졌다. 소결된 시편의 기공율은 첨가제의 함량이 5%로 증가함에 따라 첨가제의 종류에 관계없이 감소하였으나, 첨가제의 함량이 10% 로 증가하면 기공율은 포화되었다. 꺾임강도는 $Al_2O_3$를 5, 10 wt% 첨가 시 큰 폭으로 증가하였으나, 나머지 첨가제에 대해서는 꺾임강도가 감소하였다. $ZrTiO_4$의 열팽창계수 $(1000^{\circ}C)$는 $Nb_2O_5$를 제외하고는 첨가제가 증가할수록 계속적으로 감소하였으며, 특히, $SiO_2$가 첨가된 경우 가장 낮은 열팽창계수를 나타내었다.

• 한국수소및신에너지학회논문집
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• 제25권2호
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• pp.105-113
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• 2014

Performance tests on $Ni/Ce-ZrO_2/Al_2O_3$ catalysts with additives (MgO, $La_2O_3$) were investigated in the combined reforming processes (SCR, ATR, TRM) in order to produce hydrogen and carbon monoxide (it is called "syngas".). The catalyst characterization was conducted using the BET surface analyzer, X-ray diffraction (XRD), SEM, TPR and TGA. The combined reforming process was developed to adjust the syngas ratio depending on the synthetic fuel (methanol, DME and GTL) manufacturing processes. Ni-based catalysts supported on alumina has been generally recommended as a combined reforming reaction catalyst. It was found that both free NiO and complexed NiO species were responsible for the catalytic activity in the combined reforming of methane conversion, and the $Ce-ZrO_2$ binary support employed had improved the oxygen storage capacity and thermal stability. The additives, MgO and $La_2O_3$, also seemed to play an important role to prevent the formation of the carbon deposition over the catalysts. The experimental results were compared with the equilibrium data using a commercial simulation tool (PRO/II).