• 한국정보디스플레이학회:학술대회논문집
• /
• 2008.10a
• /
• pp.588-590
• /
• 2008

Yellow-emitting $Y_3Al_5O_{12}$:Ce nanocrystalline phosphor and orange-emitting CdS:Mn/ZnS core/shell quantum dots were prepared by a modified polyol and a reverse micelle chemistry, respectively. To compensate a poor color rendering index of YAG:Ce nanocrystalline phosphor due to the lack of red spectral component, CdS:Mn/ZnS quantum dots were blended into YAG:Ce. Based on spectral evolutions in the blended systems, hybrid white light emitting diodes are fabricated and characterized.

• Journal of Magnetics
• /
• v.12 no.4
• /
• pp.141-143
• /
• 2007

We have fabricated (0001) oriented hexagonal $HoMnO_3$ thin films with thickness of 300 nm using Pulsed Laser Deposition (PLD) technique on $Pt(111)/Ti/SiO_2/Si$ substrates. The XRD $\theta-2\theta$ pattern shows only (0002), (0004), and (0008) reflection of a hexagonal phase, and the full width at half maximum (FWHM) of (0004) peak is under $1.6^{\circ}$. The chemical state of Mn from XPS spectra of the films reveals the presence of $Mn^{3+}$ only. The temperature dependence of dielectric constant shows a weak anomaly at magnetic $N\acute{e}el$ temperature $(T_N)$, which is about 70 K.

• Resources Recycling
• /
• v.9 no.6
• /
• pp.3-8
• /
• 2000

A reaction between the depolarizing mixture in the spent manganese batteries and ($NH_4$)$_2$$SO_4$was carried out to find a new process for the extraction of Mn component from the spent manganese batteries. The optimum conditions were as follows : the reaction temperature $425^{\circ}C$, ($NH_4$)$_2$$SO_4$weight ratio to the depolarizing mixture in the spent manganese batteries 12.0, reaction time 60 min. Under above conditions manganese was extracted 93.5%.

• Applied Chemistry for Engineering
• /
• v.9 no.2
• /
• pp.220-225
• /
• 1998

The spinel structured $LiMn_2O_4$ was prepared from $Li_2CO_3$ and $MnO_2$ by calcination at various temperatures in the range of $750{\sim}900^{\circ}C$. It was found that the most suitable cubic structure of $LiMn_2O_4$ was obtained by heating at $850^{\circ}C$ for 12 hrs. However, in the calcination at $900^{\circ}C$, $Mn^{4+}$ of 0.06M was changed to $Mn^{+3}$ by the oxygen loss, so that it has been shown that the formula has changed to $LiMn_2O_{3.97}$. This phenomena were in agreement with the Jahn-Teller distortion by the increment of $Mn^{+3}$ ion on the octahedral sites of the spinel structured $LiMn_2O_4$. The results showed that after 15 charge/discharge cycles in the voltage range from 3.5V to 4.3V versus Li/$Li^+$ with a current density of $0.25mA/cm^2$, the spinel structured $LiMn_2O_4$ that was prepared at $900^{\circ}C$ showed a lower discharge capacity, 82~50 mAh/g, while the $LiMn_2O_4$, prepared at $850^{\circ}C$, showed the discharge capacity of 102~64 mAh/g.

• Transactions of the Korean hydrogen and new energy society
• /
• v.16 no.1
• /
• pp.25-30
• /
• 2005

수소 분위기에서 10wt.%MnO와 기계적인 분쇄(반응성 기계적 분쇄)에 의해 Mg의 수소 저장 성질을 향상시켰다. 회전 속도는 250 rpm, 밀링시간은 2 h, 그리고 시료 대 볼 중량비는 1/45이었다. 준비한 Mg-10wt.%MnO 시료는 활성화를 위한 수소화물 형성 분해 싸이클링이 필요없었으며, 첫 번째 싸이클 593k 12 bar $H_2$에서, 10분 동안에 3.12wt.%, 60분 동안에 3.95wt.%의 수소를 흡수하였다. 또한 Mg-10wt.%MnO는 593k 0.8 bar $H_2$에서 60분 동안에 2.12wt.%의 수소를 방출하였다. MnO와 Mg의 방응성 분쇄는, 핵생성을 용이케하고 (Mg 입자의 표면에 결함 형성과 첨가물에 의해), Mg 입자의 표면에 crack을 만들어 Mg의 입자 크기를 줄여 그 결과 수소 원자의 확산 거리를 작게 함으로써 수소 흡수 방출 속도를 증가시킨다. 수소화물 형성 분해 싸이클링은 Mg 입자의 표면에 crack을 만들고 Mg의 입자 크기를 줄여 수소 흡수 방출 속도를 증가시킨다.

• Journal of the Korean Magnetics Society
• /
• v.12 no.4
• /
• pp.132-136
• /
• 2002

Enhancement of crystallinity and exchange bias characteristics for NiFe/FeMn/NiFe trilayer with Si buffer layer fabricated by ion-beam deposition were examined. A Si buffer layer promoted (111) texture of fcc crystallities in the initial growth region of NiFe layer deposited on it. FeMn layers deposited on Si/NiFe bilayer exhibited excellent (111) crystal texture. The antiferromagnetic FeMn layer between top and bottom NiFe films with the buffer Si 50 ${\AA}$-thick induced a large exchange coupling field Hex with a different dependence. It was found that H$\sub$ex/ of the bottom and top NiFe films with Si buffer layer revealed large value of about 110 Oe and 300 Oe, respectively. In the comparison of two Ta and Si buffer layers, the NiFe/FeMn/NiFe trilayer with Si could possess larger exchange coupling field and higher crystallinity.

• Korean Journal of Materials Research
• /
• v.12 no.7
• /
• pp.550-554
• /
• 2002

The effect of Mn on cavitation erosion resistance and the sliding wear resistance of Fe-base hardfacing NewAlloy was investigated. Mn is known to decrease stacking fault energy and enhance the formation of $\varepsilon$-martensite. Cavitation erosion resistance for 50 hours and sliding wear resistance for 100 cycles were evaluated by weight loss. Fe-base hardfacing NewAlloy showed more excellent cavitation erosion resistance than Mn-added NewAlloys. $\Upsilon-\alpha$' phase transformation that can enhance erosion resistance by matrix hardening occurred in every specimens. But, only in Mn free Fe-base hardfacing NewAlloy, the hardened matrix could repress the propagation of cracks that was initialed at the matrix-carbides interfaces more effectively than Mn-added NewAlloy The Mn free Fe-base hardfacing NewAlloy showed better sliding wear resistance than Mn-added alloys. Mn-addition up to 5wt.% couldn't increase the sliding wear and cavitation erosion resistance of Fe-base hardfacing alloy because it didn't make $\Upsilon\to\varepsilon$ martensite phase transformation. Therefore, it is considered that the cavitation erosion and the sliding wear resistance can be improved due to $\Upsilon\to\varepsilon$ martensite phase transformation when Mn is added more than 5wt.% in Fe-base hardfacing alloys.

• Bulletin of the Korean Chemical Society
• /
• v.15 no.12
• /
• pp.1058-1064
• /
• 1994

Mn/In$_2O_3$ systems with a variety of Mn mol${\%}$ were prepared to investigate the effect of Mn-addition on the catalytic activity of Mn/In$_2O_3$ in the oxidative coupling of methane. The oxidative coupling of methane was examined on pure In$_2O_3$ and Mn/In$_2O_3$ catalysts by cofeeding gaseous methane and oxygen under atmospheric pressure between 650 and 830 $^{\circ}C$. Although pure In$_2O_3$ showed no C$_2$ selectivity, both the C$_2$ yield and the C$_2$ selectivity were increased by Mn-doping. The 5.1 mol${\%}$ Mn-doped In$_2O_3$ catalyst showed the best C$_2$ yield of 2.6${\%}$ with a selectivity of 19.1${\%}$. The electrical conductivities of pure and Mn-doped In$_2O_3$ systems were measured in the temperature range of 25 to 100 $^{\circ}C$ at PO$_2$'S of 1 ${\times}$ 10$^{-7}$ to 1 ${\times}$ 10 $^{-1}$ atm. The electrical conductivities were decreased with increasing Mn mol${\%}$ and PO$_2$, indicating the specimens to be n-type semiconductors. Electrons serve as the carriers and manganese can act as an electron acceptor in the specimens. Manganese ions doped in In$_2O_3$ inhibit the ionization of neutral interstitial indium or the transfer of lattice indium to interstitial sites and increase the formation of oxygen vacancy, giving rise to the increase of the concentration of active oxygen ion on the surface. It is suggested that the active oxygen species adsorbed on oxygen vacancies are responsible for the activation of methane.

• Journal of the Korean Ceramic Society
• /
• v.27 no.1
• /
• pp.7-12
• /
• 1990

The influence of MnO2 on the sintering property and PTCR behavior of(Ba0.8Sr0.2)TiO2 has been investigated. And the densities, grain sizes and electrical resitivities of specimens were measured as a function of doping with Mn ion of varying concentration. The density and grain size of the sintered specimens were almost the same regardless of MnO2 addition up to 0.2mol% MnO2. But in the case of 0.25mol% MnO2 addition, abnormal grain growth was appeared. So the grain size distribution was wide and density decreased greatly. The room-temperature resistivity increased as Mn content increased and the temperature coefficient of resistivity was highest in the case of 0.15mol% MnO2 addition.

• Journal of the Korean Ceramic Society
• /
• v.38 no.2
• /
• pp.173-178
• /
• 2001

본 연구에서는 PDP용 녹색 형광체의 대안인 $Ba_{1.3}$A $l_{12}$ $O_{19}$:$Mn^{2+}$ 분말을 초음파 분무 열분해법으로 합성하였으며 활성제인 $Mn^{2+}$의 첨가량과 모체를 구성하는 바륨 및 알루미늄의 전구체 물질들의 조합을 변화시킴으로써 형광체 분말의 형태 및 발광특성을 조절하였다. 최적의 발광 휘도를 나타내는 $Mn^{2+}$의 농도는 0.25몰을 첨가하였을 때이며 녹색 발광 영역인 517nm에서 최대 발광 효율을 나타내었다. 바륨의 전구체 물질로는 초산염, 질산염, 염화물 및 수산화물을 사용하였으며 알루미늄 전구체 물질로는 질산염 및 염화물을 사용하였다. 전구체는 합성된 분말의 형상에 영향을 미치는데 구형을 유지하거나 혹은 뭉치거나 구형이 깨지는 등 전구체 조합에 따라 얻어지는 분말의 형태가 달라졌다. 합성된 형광체 분말들은 일반적인 고상 반응의 온도보다 낮은 열처리 온도인 140$0^{\circ}C$, 5시간 유지에서는 좋은 VUV 발광 특성을 가졌다. 또한 전구체의 조합은 형광체 발광 효율에도 영향을 미치는데 바륨과 알루미늄은 염화물을, 망간은 질산염을 사용하였을 때 가장 좋은 발광 휘도를 나타내었다.다.다.다.