• Title/Summary/Keyword: Mn-Mo-Ni

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Exchange Bias Field and Coercivity of [NiFe/NiFeCuMo/NiFe]/FeMn Multilayers ([NiFe/NiFeCuMo/NiFe]/FeMn 다층박막의 교환결합력과 보자력에 관한 특성 연구)

  • Choi, Jong-Gu;Lee, Sang-Suk
    • Journal of the Korean Magnetics Society
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    • v.21 no.4
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    • pp.132-135
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    • 2011
  • The exchange bias field ($H_{EX}$) and the coercivity ($H_C$) variation and change depending on the thickness of intermediately super-soft magnetic NiFeCuMo layer with different thickness of the bottom NiFe layer were investigated. The $H_{EX}$ of triple pinned NiFe(4 nm)/NiFeCuMo($t_{NiFeCuMo}$= 1 nm)/NiFe(4 nm)/FeMn multilayer has the maximum value more less than one of single pinned NiFe(8 nm)/FeMn layer. If NiFeCuMo layer is inserted each into between the pinned and free NiFe layers, we can be used as GMR-SV device for a bio-sensor that has improved magnetic sensitivity.

Effects of Long-term Heat treatment on Mechanical Softening of Mn-Mo-Ni Low-Alloy Steel (Mn-Mo-Ni 저합금강의 기계적 연화에 미치는 장시간 열처리 영향)

  • Kim, Minsuk;Kim, Chungseok
    • Journal of the Korean Society for Heat Treatment
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    • v.34 no.6
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    • pp.294-301
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    • 2021
  • In the present study, we investigate the effects of long-term heat treatment at elevated temperatures on the mechanical softening of the Mn-Mo-Ni low-alloy steel. The influence of long-term heat treatment on microstructure and mechanical strength was evaluated. To simulate the long-term material degradation, heat treatment test was interrupted at several stages up to 10,000 hours in an electric furnace. The Mn-Mo-Ni low-alloy steel shows a typical bainitic phase, which consists of a well-developed lath substructure with fine precipitates along the lath boundaries. However, these fine precipitates were redissolved into the matrix with long-term heat treatment, and then the lath substructures were recovered. Consequently, ultimate tensile strength and yield strength decreased during long-term heat treatment showing a mechanical softening phenomenon.

Comparison of Microstructure & Mechanical Properties between Mn-Mo-Ni and Ni-Mo-Cr Low Alloy Steels for Reactor Pressure Vessels (원자로 압력용기용 Mn-Mo-Ni계 및 Ni-Mo-Cr계 저합금강의 미세조직과 기계적 특성 비교)

  • Kim, Min-Chul;Park, Sang Gyu;Lee, Bong-Sang
    • Korean Journal of Metals and Materials
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    • v.48 no.3
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    • pp.194-202
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    • 2010
  • Application of a stronger and more durable material for reactor pressure vessels (RPVs) might be an effective way to insure the integrity and increase the efficiency of nuclear power plants. A series of research projects to apply the SA508 Gr.4 steel in ASME code to RPVs are in progress because of its excellent strength and durability compared to commercial RPV steel (SA508 Gr.3 steel). In this study, the microstructural characteristics and mechanical properties of SA508 Gr.3 Mn-Mo-Ni low alloy steel and SA508 Gr.4N Ni-Mo-Cr low alloy steel were investigated. The differences in the stable phases between these two low alloy steels were evaluated by means of a thermodynamic calculation using ThermoCalc. They were then compared to microstructural features and correlated with mechanical properties. Mn-Mo-Ni low alloy steel shows the upper bainite structure that has coarse cementite in the lath boundaries. However, Ni-Mo-Cr low alloy steel shows the mixture of lower bainite and tempered martensite structure that homogeneously precipitates the small carbides such as $M_{23}C_6$ and $M_7C_3$ due to an increase of hardenability and Cr addition. In the mechanical properties, Ni-Mo-Cr low alloy steel has higher strength and toughness than Mn-Mo-Ni low alloy steel. Ni and Cr additions increase the strength by solid solution hardening. In addition, microstructural changes from upper bainite to tempered martensite improve the strength of the low alloy steel by grain refining effect, and the changes in the precipitation behavior by Cr addition improve the ductile-brittle transition behavior along with a toughening effect of Ni addition.

Improved Cycle Life and Storage Performance in High-Voltage Operated Li2MnO3-LiMO2(M=Ni, Co, Mn)/Graphite Cell System by Fluorine Compounds as Main Electrolyte Solvent (고전압 구동 Li2MnO3-LiMO2(M=Ni, Co, Mn)/graphite 시스템에서의 전지 수명 및 고온 방치 특성 향상에 효과적인 플루오로 화합물계 전해액에 대한 연구)

  • Yu, Jung-Yi;Shin, Woocheol;Lee, Byong-Gon
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.162-168
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    • 2013
  • $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) nano-composite is a promising cathode material for xEV application due to its high theoretic capacity. However high voltage operating system of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) has worked as a hurdle in its application because of the inherent demerits, such as cycle life degradation and gas evolution. In order to enhance cell performance of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn)/graphite cell, we examined electrolyte mainly composed of FEC, fluroalkyl ether and $LiPF_6$ (F-based EL). F-based EL showed much better discharging retention ratio than 1.3 M $LiPF_6$ EC/EMC/DMC (3/4/3, v/v/v) (STD). Furthermore gas evolution, especially CO and $CO_2$ during $60^{\circ}C$ storage for 30 days was dramatically reduced owing to thermal stable SEI formation effect of F-based EL.

Effect of Sulfur on the High-temperature Oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si Alloys (Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si 합금의 고온 산화에 미치는 S의 영향)

  • Lee, Dong Bok;Lee, Kyong-Hwan;Bae, Geun Soo;Cho, Gyu Chul;Jung, Jae Ok;Kim, Min Jung
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.386-391
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    • 2017
  • Two kinds of steels whose compositions were Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) were centrifugally cast, and oxidized at $900^{\circ}C$ for 50-350 h in order to find the effect of sulfur on the high-temperature oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) alloys. These alloys formed oxide scales that consisted primarily of $Cr_2O_3$ as the major oxide and $Cr_2MnO_4$ as the minor one through preferential oxidation of Cr and Mn. They additionally formed $SiO_2$ particles around the scale/alloy interface as well as inside the matrices. The high affinity of Mn with S led to the formation of scattered MnS inclusions particularly in the 0.35S-containing cast alloy. Sulfur was harmful to the oxidation resistance, because it deteriorated the scale/alloy adherence so as to accerelate the adherence and compactness of the formed scales.

The Effects of Partial Substitution of Mo and Heat Treatment on the Electrode Characteristics of ZrV0.1Mn0.7Ni1.2 Hydrogen Storage alloy (Ni-MH 2차 전지용 ZrV0.1Mn0.7Ni1.2 수소저장합금의 전극특성에 미치는 Mo의 부분치환과 열처리의 영향)

  • Han, Dongsoo;Oh, Myunghark;Jeong, Chigyu;Chung, Wonsub;Kim, Ingon
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.1
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    • pp.16-24
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    • 1998
  • Recently Zr-based $AB_2$ type hydrogen absorbing alloy has received much attention as a negative electrode material for the Ni-MH batteries because of its high capacity. In this study $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ alloy was chosen and the effects of heat treatment and a partial substitution of the Mo in Mn site on the various electrode properties were investigated. The alloys was prepared by arc melting (as-cast sample). Some of them were heat treated at $1,100^{\circ}C$ for 4 hours. After this they were differentiated by the different cooling rates of slow cooling and quenching. Various electrode characteristics such as activation process, high rate dischargeability and self discharge characteristic were investigated with the three types of electrodes. It was found that heat treated alloys resulted in an increase in plateau flatness of P-C isotherms however both discharge capacity and high rate capability were decreased. And the partial substitution of Mo for Mn in $ZrV_{0.1}Mn_{0.7}Ni_{1.2}$ alloy improved the self-discharge characteristic without the loss of discharge capacity (300mAh/g).

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Atmospheric Oxidation of Fe-16Cr-6Ni-6Mn-1.7Mo Stainless Steel between 700 and 900℃ (Fe-16Cr-6Ni-6Mn-1.7Mo 스테인리스 합금의 700~900℃에서의 대기중 산화)

  • Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.153-160
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    • 2011
  • The AISI 216L stainless steel with a composition of Fe-16Cr-6Ni-6Mn-1.7Mo (wt.%) was oxidized at $700{\sim}900^{\circ}C$ in air for 100 h. At $700^{\circ}C$, a thin $Mn_{1.5}Cr_{1.5}O_4$ oxide layer with a thickness of $0.4{\mu}m$ formed. At $800^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $FeCr_2O_4$ oxide layer with a total thickness of $30{\mu}m$ formed. The non-adherent scale formed at $800^{\circ}C$ was susceptible to cracking. At $900^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $Mn_{1.5}Cr_{1.5}O_4$ oxide layer formed, whose total thickness was $10{\sim}15{\mu}m$. The scales formed at $900^{\circ}C$ were non-adherent and susceptible to cracking. 216 L stainless steel oxidized faster than 316 L stainless steel, owing to the increment of the Mn content and the decrement of Ni content.