• Korean Journal of Soil Science and Fertilizer
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• v.9 no.2
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• pp.65-70
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• 1976

The effect of leaf spray ($80{\ell}$ of 100 times diluted solution per 10a) of three liquid complex fertilizers (Compresal 1 and 2. and 3P) on rice (var, Minehikari) at 10 days before and after heading and 20 days after heading in a farmer's field was investigated by yield components and flag leaf analysis. 1. Leaf spray significantly increased filled grain ratio (at 10% level) and harvest index (at 5% level) suggesting significant yeild increase in uniform field condition. 2. Phosphorus content of flag leaf was in deficient range and increased by leaf spray while iron content was decreased indicating that liquid complex fertilizer supplied phosphorus which ratards iron translocation to the upper leaves. 3. Higher manganese content in flag leaf by leaf spray (significant at 5% level) suggests that phosphorus stimulates manganese translocation to the upper leaves resulting in favorable Fe/Mn balance. 4. Nitrogen concentration in flag leaf was in the insufficient range suggesting that nitrogen in liquid complex fertilzer had to be a nitrogen supply source. 5. In flag leaf calcium concentration was increased by leaf spray but that of boron and zinc was decreased.

• Analytical Science and Technology
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• v.11 no.4
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• pp.271-280
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• 1998

Rice flour reference materials were prepared from the unpolished rice grown in Korea and certified for elemental composition. The reference materials consist of two samples containing normal and high level. The reference material at elevated level was prepared by spiking to the normal rice flour six toxic elements of As, Cd, Cu, Cr, Hg, Pb with $1.0{\mu}g/g$ on a dry weight basis. Homogeneity of the prepared materials was evaluated through the determination of Ca, Cu, Fe, Mn, Zn by instrumental neutron activation analysis (INAA) and atomic absorption spectrometry (AAS). Small variance of elemental composition among interbottled samples assured homogeneity of the prepared materials. The materials were decomposed by high pressure digestion and microwave digestion method. INAA, AAS, inductively coupled plasma-atomic absorption spectrometry (ICP-AES), ICP-mass spectrometry (MS) and vapour generation techniques were employed to analyze the reference materials. From this independent analytical results, the certified or reference values are determined for As, Ca, Cd, Cr, Cu, Fe, Hg, K, Mg, Mn, Mo, Na, P, Pb, Se, Zn.

• The Korean Journal of Pharmacology
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• v.17 no.2
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• pp.17-22
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• 1981

In the electrically stimulated guinea-pig ileum, which was incubated in the modified Krebs-Henseleit bicarbonate buffer solution containing various concentrations of electrolytes at $4^{\circ}C$ for 24 hours, the effect of naloxone on the inhibitory action of morphine was investigated. Incubation potentiated the inhibitory action of morphine. In the incubated preperation, the inhibitory action of morphine was potentiated in the $Na^+\;75mM$, and $K^+\;2.9mM$ groups, while that action of morphine was reduced in the $Ca^{++}\;3.6mM,\;Mg^{++}$ free and $Mn{++}\;0.2mM$ groups. Naloxone in incubation media potentiated in the inhibitory action of morphine. In the preparations which were incubated in various concentrations of electrolytes plus naloxone, the action of morphine was reduced in $Na^+\;75mM,\;K^+\;2.9mM$, and $Ca^{++}\;3.6mM$ groups, while that action of morphine was potentiated in $Mg^{++}$free and $Mn{++}\;0.2mM$ groups. Naloxone antagonised those actions of morphine. However, $pA_2$ values for naloxone (index for affinity for antagonist) was not changed. Thus changes in the inhitory action of morphine caused by incubation are probably not the result of changes in the affinity of receptor, but due to the alterations in the events which precede or follow the receptor binding by incubations.

• Journal of Korean Society of Environmental Engineers
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• v.38 no.9
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• pp.469-475
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• 2016

The study is the result of an practical operation analysis for the full scale fishery product wastewater treatment plant with immersed MBR (iMBR) process. Since fishery product industries show a wide range of wastewater generation by the season, design and operation of the equalization basin are very important factor. The aeration system for the equalization basin mixing can save the chemical consumption for followed system through the restriction of acid fermentation. The concentrations of wastewater primary DAF process treated were BOD 2,291 mg/L, $COD_{Mn}$ 530 mg/L, SS 256.8 mg/L, T-N 38 mg/L, T-P 13.5 mg/L respectively. It was considered that iMBR is the most efficient biological process for high salinity content wastewater since It is irrelevant to the capability of the sludge precipitation. SADp and SADm were 0.31, $26.5m^3/hr{\cdot}m^3$ respectively. In iMBR process, the critical F/M ratio was derived at 0.08~0.10 gBOD/gMLSS by analysing the correlations between MLSS, normalized TMP and temperature. The effluent concentrations were BOD 1.8 mg/L, $COD_{Mn}$ 12.4 mg/L, SS 1.0 mg/L, T-N 7.85 mg/L, T-P 0.1 mg/L and removal efficiencies were 99.9%, 97.6%, 96.3%, 95.7%, 97.8% respectively.

• Journal of Korean Society of Environmental Engineers
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• v.37 no.2
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• pp.73-80
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• 2015

An investigation on the removals of tetracycline (TTC), which is a family of antibiotics widely founded in the environment, from the aqueous solution by birnessite(${\delta}-MnO_2$)-mediated oxidative transformation was described. This study also examined the potential effect of the naturally occurring substances, humic acid (HA) on the oxidative transformation. The experiment was carried out in various conditions (reaction time, Mn oxide loadings, pH) and in the presence of HA as a batch test. The removals of TTC followed pseudo-first order reactions, and rate constants (k, $hr^{-1}$) for the removals of TTC were constantly increased with decreasing pH from 0.98 (pH 9) to 2.97 (pH 3). The rate constants also increased about 1.3 times when the birnessite loading increased from 1 to 2 g/L. Presence of HA (5 mg-C/L, at $pH{\geq}6$) caused some enhancement in the removals of TTC as compared to the control, and also showed the removal efficiencies of TTC in the birnessite mediated systems (TTC=0.25 mM, ${\delta}-MnO_2=2.0g/L$, pH 6) increased with increasing HA concentrations (1~10 mg-C/L). The results obtained from the oxidative transformation of TTC and the effect of HA were discussed in terms of reaction characteristics and mechanism.

• Journal of the Mineralogical Society of Korea
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• v.27 no.3
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• pp.125-134
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• 2014

The Janggun mine (Longitude $E129^{\circ}$ 03' 40", Latitude $N36^{\circ}$ 51' 19") was once operated as an underground mine and recently significant amount of mine and leachate water has been discharged from the mine adits and tailing dumps. Mine and leachate waters are characterized by neutral to weakly basic pH values (6.81-9.59). Major cations and anions have concentrations between 6.70-129.80 mg/L of Mg, 289.29-661.02 mg/L of Ca, 4.74-14.38 mg/L of Mn and 1205.00-2448.69 mg/L of $SO{_4}^{2-}$. Brownish yellow precipitates that found in the stream bottom consist of poorly crystallized 2-line ferrihydrite ($Fe_2O_3{\cdot}0.5H_2O$. Scanning electron microscope (SEM) photographs show that brownish yellow precipitates consisted of micro-sized granular particles of about $0.1{\mu}m$ in diameter. Semi-quantitative energy dispersive spectrometry (EDS) analyses show that these samples contained mainly Fe with minor Mn, Ca, Si and As.

• Journal of Wetlands Research
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• v.16 no.4
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• pp.413-422
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• 2014

In national water quality policy, it changed previous regulation method that focuses on concentration of pollutants in effluent water to the way that regulates total amount of pollutants. The target of water quality in watershed of each river was set up, as the government instituted Total Maximum Daily Loads(TMDL). In order to accomplish successfully TMDL, it requires that the amount of pollutant loads discharged from point and nonpoint pollutant source should be investigated. This study, therefore, conducted the monitoring of the stormwater runoff at field region in farming area. And pollutants loads and unit loads discharged from field region results is calculated. As a result, the concentration of pollutants were calculated as follows: 10.5 BOD mg/L, 19.6 $COD_{Mn}$ mg/L, 4.5 TN mg/L and 2.4 TP mg/L. The unit load of BOD, $COD_{Mn}$, TOC, TSS, TN and TP discharged from field region, also, were determined to $31.8kg/km^2/yr$, $56.7kg/km^2/yr$, $8.5kg/km^2/yr$, $560.9kg/km^2/yr$, $8.3kg/km^2/yr$ and $5.1kg/km^2/yr$, respectively. It was identified that there were some differences of unit loads between the results obtained from this study and previous one. To calculate exact unit loads, therefore, long term monitoring should be conducted.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.286-291
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• 2006

We studied possibility of mixing treatment of livestock wastewater and sewage using Phanerochaete chrysosporium PSBL-1. Our study showed that 97.6% of SS and 95% of T-P removal efficiency was achieved when 2 mL BF02(a coagulant) and 100 mL C-210EL(a cationic polymer) were added to the mixture(2:1, v/v) of livestock wastewater and sewage. We studied treatment characteristic of Phanerochaete chrysosporium PSBL-1, after were mixed pretreated wastewater and sewage by dillution ten times about livestock wastewater. The removal efficiency of NBDCOD(non-biodegradable COD), $NH_3-N$ and T-N was increased according to increase of pH. That is, T-N concentration of effluent was satisfied 60 mg/L by drain water waterqulity standard of livestock wastewater public treatment facilities with 35 mg/L from a lapse of five days at pH 6.7, 51 mg/L from a lapse of three days at pH 8 and 33 mg/L from a lapse of one day at pH 10. Moreover $COD_{Mn}$ concentration of effluent was satisfied 40 mg/L by drain water waterqulity standard of livestock wastewater public treatment facilities after a laps of one day at all pH. Organics and nitrogen concentrations of effluent were higher case with addition of V.A.(veratryl alcohol) than case without addition of V.A.(veratryl alcohol). $COD_{Mn}$ concentration of effluent satisfied drain water qulity standard of livestock wastewater public treatment facilities from a lapse of one day, when C/N rate(3:1) of influent was not controled. T-N satisfied that from a lapse of two days, when C/N rate was controled with $4{\sim}6$.

• Journal of Korean Society of Environmental Engineers
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• v.28 no.10
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• pp.1038-1045
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• 2006

A series of experiments was conducted to test the compatibilities of two different techniques to determine elemental concentrations by INAA and ICP-MS based on both the NIST SRM 2783(air particulate on filter media) and the field samples for PM10. For NIST SRM the results of INAA were more accurate and precise for all target elements than those of ICP-MS. The comparative data set for PM10 samples collected in an industrial complex area showed that mean of concentration ratio, derived for the two different methods such as C(INNA/ICP-MS), were distinguished from each other: (1) Ba, Cu, K Mg, Na, and Sb: $0.9{\sim}1.1$; (2) Al, Co, Fe, and Mn: $0.8{\sim}1.2$; and (3) Se, Ti, and Zn: >1.3. When the results obtained from both methods were evaluated in terms of regression analysis, paired t-test, and Wilcoxon signed-rank test, the results of many elements determined from PM10 samples(such as Al, Ba, Co, Cu, Fe, K, Mn, Nd, and Sb) exhibited a fairly good agreement between the two methods, despite a wide range of variation.

• Journal of Korean Society of Environmental Engineers
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• v.35 no.8
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• pp.564-570
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• 2013

Domestic treatment facilities for acid mine drainage (AMD) mostly used a passive treatment process. But some passive treatment facility discharged high manganese concentrations because it is required high pH (>9) for abiotic oxidation of Mn(II) to Mn(IV). This study was focused on the feasibility of biological manganese treatment using the manganese-oxidizing bacteria (Pseudomonas sp. MN5) from AMD and economical application method of it. To investigate the various conditions of water quality the most part of the experiments were based on batch test. And result of it showed that maximum manganese oxidation rate were $10.4mg/L{\cdot}h$ at the pH7. We also performed small column tests in which MOB were attached to the functional polyurethane (FPU) media containing alkaline chemicals. Manganese concentration decreased 42 mg/L to below 6 mg/L. But anaerobic condition formed by excessive bacterial respiration in column resulted in increasing effluent manganese concentration.