• Title/Summary/Keyword: Mn 농도

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CoFeB과 IrMn 자성 박막의 고밀도 반응성 이온 식각

  • Kim, Eun-Ho;So, U-Bin;Gong, Seon-Mi;Jeong, Yong-U;Jeong, Ji-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.232-232
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    • 2010
  • 정보화 산업의 발달은 DRAM, flash memory 등을 포함한 기존의 반도체 메모리 소자를 대체할 수 있는 차세대 메모리 소자에 대한 개발을 요구하고 있다. 특히 magnetic random access memory (MRAM)는 SRAM과 대등한 고속화 그리고 DRAM 보다 높은 기록 밀도가 가능하고 낮은 동작 전압과 소비전력 때문에 대표적인 차세대 비휘발성 메모리로 주목받고 있다. 또한 MRAM소자의 고집적화를 위해서 우수한 프로파일을 갖고 재증착이 없는 나노미터 크기의 magnetic tunnel junction (MTJ) stack의 건식 식각에 대한 연구가 선행되어야 한다. 본 연구에서는 고밀도 반응성 이온 식각법(Inductively coupled plasma reactive ion etching; ICPRIE)을 이용하여 재증착이 없이 우수한 식각 profile을 갖는 CoFeB과 IrMn 박막을 형성하고자 하였다. Photoresist(PR) 및 Ti 박막의 두 가지 마스크를 이용하여 HBr/Ar, HBr/$O_2$/Ar 식각 가스들의 농도를 변화시키면서 CoFeB과 IrMn 박막의 식각 특성들이 조사되었다. 자성 박막과 동일한 조건에 대하여 hard mask로서 Ti가 식각되었다. 좋은 조건을 얻기 위해 HBr/Ar 식각 가스를 이용 식각할 때 pressure, bias voltage, rf power를 변화시켰고 식각조건에서 Ti 하드마스크에 대한 자성 박막들의 selectivity를 조사하고 식각 profile을 관찰하였다. 식각 속도를 구하기 위해 alpha step(Tencor P-1)이 사용되었고 또한 field emission scanning electron microscopy(FESEM)를 이용하여 식각 profile을 관찰함으로써 최적의 식각 가스와 식각 조건을 찾고자 하였다.

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Effect of Germanium Treatment in Culture Medium on Germanium Absorption by Callus Induced from Brown Rice (배지내 게르마늄 처리가 현미 유도 캘러스의 게르마늄 흡수에 미치는 영향)

  • 권태오;남궁승박;박병우
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.6
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    • pp.729-735
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    • 1996
  • This study was carried out to investigate the effect of Germaniwn(Ge) treatment in the culture media on the Ge absorption by the callus induced from brown rice cv. Dongjinbyeo. MS medium was more effective on the growth ratio of callus and the content of Ge and some inorganic elements except K in callus than N$_{6}$ medium. The more Ge treatment in the N$_{6}$ or MS medium, the more Ge absorption by the callus, but the growth ratio of callus and the content of Ca, Mg, and K in callus were decreased. The content of Fe, Mn, Zn, and Cu was increased under treatment up to 100~200mg /$\ell$ Ge, but tended to be decreased under treatment more than that of Ge concentration. Under treatment less than 150mg /$\ell$ Ge, GeO$_2$(inorganic Ge) was more effective on the Ge absorption by callus than Ge-132(organic Ge), but Ge-132 was more effective on the Ge ab-sorption by callus and the activity of callus in case of treatment more than 150mg /$\ell$ Ge. The lower pH of culture medium, the higher Ge content in the callus. When callus was cultured on medium supplemented with Ge and 0.1~1.0mM of citric acid or myo-inositol, content of Ge and some inorganic elements in callus, as well as growth and dry weight of callus, were tend to increase in comparison to control, but myo-inositol was more effective on them than citric acid.cid.

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Quality and Physiological Characteristics of Pinus densiflora Seeds Under Different Storage Periods and Temperatures (장기 저장과 저장 온도에 따른 소나무 종자 품질과 생리적 특성)

  • Gu, Da-Eun;Ku, Ja-Jung;Han, Sim-Hee
    • Journal of Korean Society of Forest Science
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    • v.111 no.3
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    • pp.418-427
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    • 2022
  • Our aim was to evaluate the quality of pine seeds after long-term storage and to analyze the correlation between germination and physiological characteristics. Therefore, we investigated the germination and physiological characteristics of seeds stored for different periods and storage temperatures. Pine seeds lost little viability and vigor after 12 years of storage at 4℃; it is even possible to prolong the storage period at -18℃. The deterioration process operating through long-term storage was characterized by a loss of seed vigor before a loss in seed viability. Electrical conductivity of the seed leachate was significantly higher in seeds that completely lost their viability, and was also found to be significantly correlated with the germination percentage, T50, mean germination time, and germination speed. Among the minerals leaked to the leachate, K had the highest concentration, followed by Na, Ca, Cu, Mg, and Fe, while Mn and Zn were not detected. Concentrations of K, Ca, Cu, Mg, and Fe in the leachate differed significantly by treatment, and in the cases of K, Ca, Cu, Na, and Mg, we observed large differences in the leachate between the seeds that were collected in 2003 and those collected in other years.. Germination percentage was significantly negatively correlated to the concentrations of Ca, Cu, K, Mg, and Na. The coefficient of uniformity of germination was significantly negatively correlated to Cu concentration. The other germination characteristics were not significantly correlated with the mineral concentration. Therefore, the mineral concentrations of pine seed leachate were not reliable indicators of seed deterioration when the differences in quality between seed lots were small. However, electrical conductivity could be an indicator of seed viability and vigor of pine seeds under long-term storage.

Analysis of statistics and Runoff Characteristic of a Mine (기타광물질 지역의 유출특성 및 통계분석)

  • Kim, Tae-Yoo;Choi, Yong-Hun;Shin, Hyun-Jun;Won, Chul-Hee;Choi, Jung-Dae
    • Proceedings of the Korea Water Resources Association Conference
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    • 2009.05a
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    • pp.1063-1067
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    • 2009
  • 강원도 홍천군에 위치한 기타광물질 지역의 유출과 수질농도의 특성을 파악하기 위하여 연구를 수행하였다. 연구기간동안 13회의 강우사상에 대하여 모니터링을 실시하였다. 13회의 강우모니터링 기간동안 발생한 강우량은 6.5 ${\sim}$ 149.0 mm의 범위를 나타냈고, 유출계수는 0.28${\sim}$0.98의 범위를 나타냈다. 유출률은 수리, 수문,지형 및 지질학적 특성 등 여러 가지 요인에 의하여 변화할 수 있다. 어느 한 지역의 강우사상에서 강우량과 강우강도 그리고 선행무강우일수 등의 수리, 수문학적 특성은 유출량과 유출율의 크기에 큰 영향을 준다. 강우량과 선행무강우일수 그리고 강우강도와 유출율의 상관관계에서 유출률은 강우량과 강우강도가 증가할수록 선행무강우일수가 감소할수록 증가하는 경향을 나타냈다. 또한 유출율과 강우량, 선행무강우일수, 평균강우강도 그리고 최대강우강도의 Pearson 상관계수는 0.75857, -0.36346, 0.68323 그리고 0.74594로 나타났으며, 강우량, 평균강우강도, 최대강우강도는 유의수준 0.05에서 통계적으로 유의하며 유출율과 강우량의 관계가 가장 큰 것으로 나타났다. 기타광물질 지역의 수질농도들 사이의 상관관계는 $COD_{Cr}$$COD_{Mn}$에서 0.81097로 가장 큰 상관계수가 나타났으며, 유기물질인 $COD_{Cr}$, $COD_{mn}$, BOD 그리고 TOC는 통계적으로 유의한 상관 계수를 갖는 것으로 나타났다. 하지만 유기물을 제외한 다른 수질항목은 큰 관계가 없는 것으로 나타났다. 기타광물질 지역의 유출수와 수질농도의 특성을 더 신뢰성있고 과학적으로 검증하기 위한 장기적인 연구와 노력이 더욱 필요할 것으로 사료된다.

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시금치 엽록체의 광합성 전자전달 활성에 미치는 $Cd^{2+}$의 저해 효과

  • 정화숙
    • Journal of Plant Biology
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    • v.37 no.2
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    • pp.231-236
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    • 1994
  • The effect of $Cd^{2+}$ on the electron transport rate of PSI and PSII was investigated in isolated spinach chloroplasts. In photosystem II, the rate of electron transport was decreased as the concentration of $Cd^{2+}$ was increased from 1 to $100\;\mu\textrm{M}$. The inhibitory effect of $Cd^{2+}$ was reduced when diphenylcarbazide was added to the reaction medium, indicating that $Cd^{2+}$ affects primarily psn oxygen evolving complexes of thylakoid membrane. The inhibitory effect of $Cd^{2+}$ was reduced when $Mn^{2+}\;and\;Ca^{2+}$ were added to the reaction medium, but the inhibitory effect was not fully relieved. Although the activity of psn was decreased significantly by the treatment of $50\;\mu\textrm{M}\;Cd^{2+}$, Fv/Fm was decreased slightly. However, the treatment of $100\;\mu\textrm{M}\;Cd^{2+}$ resulted in the marked decrease of Fv/Fm. In photosystem I, the rate of electron transport decreased as the concentration of $Cd^{2+}$ was increased from 0.2 to 3.2 mM. The inhibitory effect of $Cd^{2+}$ was decreased when the chloroplast treated with $Cd^{2+}$ was washed by centrifugation.gation.

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Studies on the Bacterial Production of L-Glutamate from Acetate Part II. Cultural Conditon (초산을 이용한 글루타민산의 발효생산에 관한 연구 (제2보) 글루타민산 생성을 위한 발효조건)

  • 하덕모;노완섭;서동하
    • Microbiology and Biotechnology Letters
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    • v.2 no.3
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    • pp.141-147
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    • 1974
  • The cultural conditions for L-glutamate production were investigated using Brevibacterium flavum nov. sp. D2209B, the most productive strain among 5 strains reported in preceeding paper. A temperature of 3$0^{\circ}C$ and a medium volume of 30 ml per 500-flask were selected as standard culture conditions. And the following results were obtained. 1. When the concentration of acetate in the medium was below 30 g per litre, the maximum amount of L-glutamate was accumulated. 2. KH$_2$PO$_4$, MgSO$_4$, FeCI$_3$ and MnCI$_2$ were required for the L-glutamate poduction, but the concentration of those inorganic salts little effected. 3. Signifcant amount of L-glutamate was accutnulated in the limited biotin concentration less than 0.3 ug per litre. 4. The addition of malic acid or succinic acid enhanced the accumulation. 5. The L-glutamate accumulation was related to the incubation time of seed; the amount of L-glutamate accumulated was maximum by inoculating 16-20 hour incubated seed. 6. In the medium containing sufficient amount of biotin for growth, L-glutamate accumulation was stimulated by the addition of penicillin at appropreate time during incubation.

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The metallic composition of airborne particles in seven locations of Seoul city, Korea (대기 분진 중 중금속 성분의 공간적 농도분포 특성 비교: 서울시 7개 관측점을 중심으로)

  • Choi, Bae-Jin;Kim, Ki-Hyun
    • Analytical Science and Technology
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    • v.16 no.2
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    • pp.143-151
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    • 2003
  • In the present study, we made measurements of PM-bound metal concentrations from seven different urbanized locations in Seoul for the period covering March 2001 through May 2002. The measurement data were analyzed to explore the possible influences of spatial factors on metal distribution characteristics. To check for the importance of such aspects on metal distribution characteristics, the measured data were compared between different metals and between different sites by several criteria including (1) coefficient of variation (CV) values; (2) temporal variability; and (3) the abundance of strongly correlated pairs. The overall results of our study indicate strong diversity in the distribution characteristics of different metals. It is found that some metals (like Fe, Mn, and Pb) tend to exhibit strong compatibility among different study sites. However, no such compatibility appears to exist for certain metals like Cu. To account for the importance of spatial factors, complex relationships between source/sink processes and geochemical characteristics of a given metallic component may have to be examined in a systematic manner.

Remediation of Acid Mine Drainage from an Abandoned Coal Mine Using Steel Mill Slag, Cow Manure and Limestone (제강슬래그, 우분 및 석회석을 활용한 폐 석탄광의 산성광산배수 처리)

  • Jung Myung-Chae
    • Journal of Soil and Groundwater Environment
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    • v.10 no.3
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    • pp.16-23
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    • 2005
  • In order to remediate acid mine drainage (AMD) from the Jeongam coal mine, steel mill slag, cow manure and limestone were used. As a result of batch test, the proper amounts for treating 1 L of acid mine water from the mine were determined as 15 g of steel mill slag, 15 g of cow manure and 500 g of limestone. After feasibility test, remediation system was arranged in the order of steel mill slag tank combination of cow manure and limestone, precipitation tank and oxidation tank. During 54 days' operations, the pH values of the treated waters increased from 3.0 to 8.3 and 61 % of sulfate concentration in an initial water was decreased. In addition, the removal efficiencies for metals in the water were nearly 99.9% for Al, Fe, Zn and 92.6% for Mn. Thus, the combination of steel mill slag, cow manure and limestone can be used as neutralization 때d metal removal for acid mine drainage.

Hazardous Characteristics of metals in Bottom Ash from Municipal Solid Waste Combustors(MSWC) of Korea (도시폐기물 소각로에서 발생되는 바닥재중의 금속류 유해특성에 관한 연구)

  • Chung, David;Kim, Yu-Nung;Yun, Young-Ja;Kim, Yoen-Ho
    • Analytical Science and Technology
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    • v.14 no.3
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    • pp.253-258
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    • 2001
  • This is a research on hazardous characteristics and potentials of bottom ash from 9 municipal solid waste combustors(200 tons/day) of Korea by the test methods of leaching and content. The leaching method was performed by Waste Test Method of Korea. In case of the content method, mercury was determined by thermal decomposition amalgamation atomic absorption spectrometer, other 9 elemets including Pb, which were pretreated by U.S.EPA SW-846 3050B method, were determined by flame atomic absorption spectrometer(FAAS) or inductively coupled plasma atomic emission spectrometer(ICP-AES). Results of leaching test showed that Pb and Cu was main pollutants. It was interested that the distribution rate of metals' contents of each combustors was similar and the rank of concentration was Fe>Zn>Cu>Mn>Pb>Cr>As>Cd>Hg.

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Inhibitory Effect of Melanogenesis and Anti-inflammatory Effect of Elsholtzia ciliata Extract and Its Application as a Cosmeceutical Ingredient (향유의 멜라닌 생성 억제효과 및 항염효과와 화장품 원료로서의 특성)

  • Lee, Dae-Woo;Kim, Young-Jin;Kim, Young-Sil;Eom, Sang-Yong;Kim, Jong-Heon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.32 no.4 s.59
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    • pp.219-225
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    • 2006
  • In this study, we evaluated anti-oxidation, whitening and anti-inflammatory effects of Elsholtzia ciliata extract for use as the cosmeceuticals. Elsholtzia ciliata extracts (30, 70 and 100% methanol extract) exhibited a significant tree radical scavenging effect (up to 80% over 0.025% concentration of 30 and 70% methanol extract, over 0.01% concentration of 100% methanol extract) against DPPH radical generation and showed a significant inhibitory effect (up to 80% over 0.1% concentration) on melanin synthesis in B-16 Melanoma cells. We separated 4 fractions from Elsholtzia ciliata extract (70% methanol extract) by MPLC. The 1st, 2nd, and 3rd fractions showed anti-oxidation (DPPH radical scavenging activity and suppressive effect on Mn-SOD), whitening(inhibitory effect on melanin synthesis) and anti-inflammatory (suppressive effects on $IL-1{\alpha}$, IL-6, COX-2, and total NO synthesis) effects.