• 제목/요약/키워드: Mixture Gases

검색결과 313건 처리시간 0.031초

반응성 직류 스퍼터법에 의한 질화 인듐 박막의 제막 특성 (Deposition Characteristic of InNx Films by Reactive DC Magnetron Sputtering)

  • 송풍근;류봉기;김광호
    • 한국세라믹학회지
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    • 제40권8호
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    • pp.739-745
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    • 2003
  • In $N_{x}$ films were deposited on soda-lime glass without substrate heating by reactive dc magnetron sputtering using indium (In) metal target. Depositions were carried out under various total gas pressures ( $P_{tot}$) of mixture gases (Ar+$N_2$ or He+$N_2$). He gas was introduced to $N_2$ gas in order to enhance the reactivity of nitrogen on film surface by the "penning ionization". Plasma impedance decreased greatly when 20% or more introduced the $N_2$ gas. This is due to the In $N_{x}$ layers formed on target surface because a secondary electron emission rate of InN is small compared with In metal. XRD patterns of the films revealed that <001> preferred oriented polycrystalline In $N_{x}$ films, where the crystallinity of the films was improved with decrease of $P_{tot}$ and with increase of $N_2$ flow ratio. The improvement of the crystallinity and stoichimetry of the In $N_{x}$ films were considered to be caused by an increase in the activated nitrogen radicals and also by an increase in the kinetic energy of sputtered In atoms arriving at growing film surface, which should enhance the chemical reaction and surface migration on the growing film surface, respectively. Furthermore, the films deposited using mixture gases of He+$N_2$ showed higher crystallinity compared with the film deposited by the mixture gases of Ar+$N_2$.$.EX>.

CO와 CH4, C2H4 혼합 가스 폭발에 대한 TNT 등가량 계산 (Calculation of the TNT Equivalent Mass of the Possible Explosion of CO, CH4, and C2H4)

  • 김민주;권상기
    • 화약ㆍ발파
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    • 제38권1호
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    • pp.1-13
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    • 2020
  • 국내외에서 가스 소비량 증가에 따라 가스 폭발 사고가 꾸준히 발행하고 있으며 석탄 저장소 옥내화 대책에 따른 가스 폭발 위험성이 대두되고 있다. 이러한 가스 폭발의 영향을 분석하기 위하여 TNT 등가량 산정법이 사용되고 있다. 본 연구에서는 석탄이 배출하는 가연성 가스인 CO, CH4, C2H4의 공기 내 부피 함량에 따른 폭발사례에 대한 TNT 등가량을 산정하였다. 또한 계산된 TNT 등가량을 이용하여 거리에 따른 최대 압력과 임펄스 변화량을 가스 폭발 사례별로 비교, 분석하였다. 3개 혼합 가스의 TNT 등가량 증가 양상은 C2H4의 공기 중 부피함량에 의존하는 경향을 보이고 있다. 또한 TNT 특성곡선의 인자인 최대 압력과 임펄스도 가스의 개수가 증가함에 따라 그 값이 증가하는 양상을 띠고 있다.

3성분계 인화성 혼합가스의 최소점화에너지 측정에 관한 연구 (Measurement of Minimum Ignition Energy by Electrostatic Discharge for Flammable Ternary Gas Mixtures)

  • 최상원
    • 한국안전학회지
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    • 제28권1호
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    • pp.29-34
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    • 2013
  • When flammable gases are mixed with air or oxygen in the explosion concentration range and are ignited by sufficiently large electrostatic discharge energy, they may explode causing severe disaster in workplace. The minimum ignition energy(MIE) of single gas-air mixtures has been already investigated by many research, but the MIE of mixtures of more than ternary gas mixture is not examined yet. The purpose of this study is to investigate the MIE of a ternary gas(methane, ethylene, hydrogen, propane) mixtures experimentally. The results of our experiment show that the ignition of a methane-ethylene-air, methane-hydrogen-air, methane-propane-air, ethylene-hydrogen-air, ethylene-propane-air and hydrogen-propane-air mixture due to electrostatic discharge energy primarily depends on that the mixture: the MIE decreases gradually with the increase of having the lower MIE than other mixture ratio in the normal atmospheric pressure.

Reforming Tar from Biomass Gasification using Limonite and Dolomite as Catalysts

  • Kim, Hee-Joon;Kunii, Hiroo;Li, Liuyun;Shimizu, Tadaaki;Kim, Lae-Hyun
    • 에너지공학
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    • 제20권4호
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    • pp.298-302
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    • 2011
  • In this study, Catalytic reforming with vapor and biomass gasification was simultaneously performed in a same fixed bed reactor at $600-800^{\circ}C$. Light gases were produced from reformation of the tar (fuel gases) in biomass gasification by using limonite and dolomite, as catalysts. Hydrogen and carbon dioxide are main components in light gases. Hydrogen yields increased with temperature increasing in the range of $650-800^{\circ}C$, because the water shift reaction was promoted by catalyst. The yield of hydrogen gas was increased about 160% under catalyst with the mixture of limonite and dolomite comparing to limonite only.

초고압 GIL을 위한 $SF_6/N_2$ 혼합가스의 절연특성 (Dielectric Characteristics of $SF_6/N_2$ Mixture Insulation Gas for HV GIL)

  • 장용무;김철호;김정태;구자윤
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.49-49
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    • 2010
  • In this paper, a full scaled gas discharge chamber was designed and fabricated for evaluating the dielectric performance of SF6/N2 mixture gases. And it describes work on AC and lightning impulse dielectric characteristics of SF6/N2 mixture insulation gas from experiments and full scale models.

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이종절연재의 연면절연특성 (Surface Discharge Characteristics in Different Media)

  • 신성하
    • 한국산업융합학회 논문집
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    • 제15권2호
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    • pp.49-54
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    • 2012
  • With the improvement of industrial society, the high quality electrical energy, simplification of operation and maintenance, ensuring reliability and safety are being required. This paper reviews a basic data of the surface discharge characteristics for teflon resin in not only pure $N_2$, $N_2:O_2$ mixture gas and Dry-Air as being focused on environmentally friendly insulating Gas also $SF_6$. Used electrodes are Knife to Knife. With the changing distance of electrodes and pressure, we can find it, surface discharge voltages and surface dielectric strengths, respectively. Surface discharge Voltages of $N_2:O_2=80:20$ mixture gas are more higher than the $N_2:O_2$ Mixture gases.

SF6-N2 혼합가스 중 돌출 결함의 부분방전 특성 (Partial Discharge Characteristics on Protrusion Defects in SF6-N2 Mixture Gases)

  • 조향은;왕국명;김선재;박경수;길경석
    • 한국전기전자재료학회논문지
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    • 제29권1호
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    • pp.44-49
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    • 2016
  • Studies on a $SF_6$-mixture and -alternative gas has been in progress to reduce the use of $SF_6$ gas as an insulation material of GIS (gas insulated switchgears). In this paper, we dealt with PD (partial discharge) characteristics in pure $SF_6$ and $N_2$, and their mixtures on aspects of insulation design and risk assessment for GIS. A POC (protrusion on conductor) and a POE (protrusion on enclosure) as the major defects were fabricated to simulate PD. We analyzed the DIV (discharge inception voltage), DEV (discharge extinction voltage), pulse magnitude, counts and phase distribution of PD pulse in $SF_6-N_2$ mixtures ($SF_6$ 100%, $SF_6$ 80%-$N_2$ 20%, $SF_6$ 50%-$N_2$ 50%, $SF_6$ 20%-$N_2$ 80%, and $N_2$ 100%) according to the IEC60270. The DIV, DEV as well as magnitude of PD pulse decreased on the POC as increase of $N_2$ ratio. For the POE, the DIV and DEV in $N_2$ ratio below 50% were the same voltages as those in $SF_6$ 100%. In this experiment, $SF_6$ 80%-$N_2$ 20% mixture could be considered with the equivalent insulation performance to a GIS.

고능률 GMAW의 용접성에 미치는 보호가스의 영향 (Effect of Shielding Gases on the Weldability of High Efficient GMAW Process)

  • 한기형;한종만;이민우;이은배;한용섭
    • Journal of Welding and Joining
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    • 제13권1호
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    • pp.127-137
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    • 1995
  • The possibility of new GMAW process using economic shielding gases including CO$_{2}$ gas was investigated on the effect of shielding gas on weldabilty. In the optimum welding condition using 600A power source, FCAW process showed low depositions rate, 114 g/min at 300A, but new GMAW using other mixed shielding gases exhibited high deposition rate, 208-224 g/min at 450A. TIME gas, Ar+CO$_{2}$ gas and Ar+CO$_{2}$+O$_{2}$ gas as a shielding gas were able to be used to the very high welding current(450A), moreover TIME gas and Ar+CO$_{2}$ gas showed the highest arc stability among shielding gases studied in this experiments. The weld penetration was performed by axial spray transfer mode of weld droplet. On the basis of workability, weldability and economic point of view, Ar mixture (80%Ar+20%CO$_{2}$) gas was recommended as a shielding gas for the development and application of new GMAW process. This shielding gas showed the low spatter, good weld quality, stable arc and low cost at the region of high welding current.

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가솔린 기관(機關)의 혼합기(混合氣) 성분(成分)이 출력(出力)에 미치는 영향(影響) (점화지연(点火遲延) 및 연소(燃燒) 기간(期間)에 미치는 영향(影響)) (The Effect of Mixture Component in a Gasoline Engine on Output (The Effect of Ignition Delay and Combustion Period))

  • 송재익
    • 한국분무공학회지
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    • 제3권1호
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    • pp.19-26
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    • 1998
  • The effect of mixture component makes a nelay time and a long total combustion period $\tau_{p\;max}$. The flame propagation delay $\tau_{df}$ was determined by the record of current ion. The pressure release delay $\tau_{dp}$ and $\tau_{p\;max}$ were determined by the indicated pressure diagram in constant volume of the combustion chamber. The results are as follows: 1) The ignition delay $\tau_t$ time takes the minimum value around $\Phi=1.15$. 2) $\tau_{df}$ and $\tau_t$ time increased according to the increases of the concentrated dilution gases, because the adiabatic flame temperature decreased due to the increases of the heat capacity. But dilution gases have little effect on flame nucleus formation delay 3) The relation between $\tau_t$ time and reciprocal laminar burning velocity is almost linear. 4) The increase of the propagation length is accompanied with increased ratio of the $\tau_{df},\;\tau_{dp},\;\tau_{t},\;\tau_{p\;max}$.

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