• Proceedings of the Korean Vacuum Society Conference
• /
• 2011.02a
• /
• pp.255-255
• /
• 2011

Zinc oxide based thin films have been extensively studied in recent several years because they have very interesting properties and zinc oxide is non-poisonous, abundant and cheap material. ZnO films are employed in different applications like transparent conductive layers in solar cells, protective coatings and so on. Wide industrial application of the ZnO films requires of development of cheap, effective and scalable technology. Typically used technologies don't completely satisfy the industrial requirements. In the present work, we studied effect of the deposition parameters on the structure and properties of ZnO films deposited by DC arc plasmatron. The varied parameters were gas flow rates, precursor composition, substrate temperature and post-deposition annealing temperature. Vapor of Zinc acetylacetone was used as source materials, oxygen was used as working gas and argon was used as the cathode protective gas and a transport gas for the vapor. The plasmatron power was varied in the range of 700-1500 watts. Flow rate of the gases and substrate temperature rate were varied in the wide range to optimize the properties of the deposited coatings. After deposition films were annealed in the hydrogen atmosphere in the wide range of temperatures. Structure of coatings was investigated using XRD and SEM. Chemical composition was analyzed using x-ray photoelectron spectroscopy. Sheet conductivity was measured by 4-point probe method. Optical properties of the transparent ZnO-based coatings were studied by the spectroscopy. It was shown that deposition by a DC Arc plasmatron can be used for low-cost production of zinc oxide films with good optical and electrical properties. Increasing of the oxygen content in the gas mixture during deposition allow to obtain high-resistive protective and insulation coatings with high adhesion to the metallic surface.

• Journal of Sensor Science and Technology
• /
• v.6 no.6
• /
• pp.445-450
• /
• 1997

An ammonia gas sensor with high sensitivity using thick-film technology were fabricated and examined. The material for sensing the ammonia gas was the mixture of oxide semiconductor, $FeO_{x}-WO_{3}-SnO_{2}$. The sensor exhibits resistance increase upon exposure to low concentration of ammonia gas. The resistance of the sensor is decreased, on the other hand, for exposure to reducing gases such as ethyl alcohol, methane, propane and carbon monoxide. A novel method for detecting ammonia gas quite selectively utilizing a sensor array consisting of an ammonia gas sensor and a compensation element were proposed and developed. The compensation element is a Pt-doped $WO_{3}-SnO_{2}$ gas sensor which shows opposite direction of resistance change in comparison with that of the ammonia gas sensor upon exposure to ammonia gas. Excellent selectivity has been achieved using the sensor array having two sensing elements.

• Fire Science and Engineering
• /
• v.23 no.5
• /
• pp.72-77
• /
• 2009

In the recycling procedure of the refrigerator, the fire frequently breaks out. In this study, to clarify the exact cause of the fire, the components and concentration of the materials produced in the process are analysed as well as the problems in the process system, and the protective measure to prevent the fire and the explosion fundamentally is proposed. In this procedure, the preventive measures of fire by removing the combustible materials such as polyurethane and inflammable gases, by removing the ignition sources and by reducing the oxygen concentration to the minimum are proposed along with the protective measures to reduce the damage in the fire. In the crushing procedure where the fire or explosion can break out in diverse ways, the forced ventilation or exhaust system applied to the small partial ventilation facility are installed to reduce the concentration of inflammable gas mixture to lower than the inflammable limit by injecting and exhausting the air forcibly.

• Journal of the Korean Chemical Society
• /
• v.20 no.5
• /
• pp.431-437
• /
• 1976

On the condition of adequate air supply, complete removal of carbon monoxide,occurred above $650^{\circ}C$. Using catalysts, the oxidation of carbon monoxide occurred at lower temperatures; on both $MnO_2 \;and\;30%\;MnO_2-70%\;CuO\;at\;250{\circ}C,\;on\;CuO\;at\;450{\circ}C,\;on\;50%\;MnO_2-50%\;CuO\;at\;200{\circ}C,\;and\;on\;70%\;MnO_2-30%\;CuO\;at\;180{\circ}C$. Manganese dioxide (p-type) showed higher activity than cupric oxide (n-type) and a catalyst consisting of 60% $MnO_2-40%$ CuO had the highest activity of all the $MnO_2$-CuO mixture. Over the range of transitional temperature, carbon monoxide removal efficiency decreased linearly with increasing inlet carbon monoxide concentration while temperature was fixed. Residence time of gases in the catalytic reactor, in the range of 0.9 to 1.8 seconds, gave no effect on carbon monoxide conversion.

• Journal of the Korean Chemical Society
• /
• v.46 no.2
• /
• pp.164-168
• /
• 2002

SrGa$_2$S$_4$ : Eu is a green emitting phosphor which is applied for field emission display, and cathodoluminescence. Conventionally, SrGa$_2$S$_4$ : Eu is synthesized by solid state reaction, in which a mixture of SrCO$_3$, Ga$_2$O$_3$, and Eu$_2$O$_3$ is fired at high temperatures under flowing H$_2$S and Ar gases. In this study,SrGa$_2$S$_4$ : Eu phosphor is synthesized by using a decomposition method, where SrS, Eu complex, and Ga com-plex are used. The advantage of this method is that toxic H$_2$S gas and Ar gas are not used. The synthetic con-ditions and luminescent properties of SrGa$_2$S$_4$ : Eu phosphor are also investigated.

• Journal of Electrochemical Science and Technology
• /
• v.8 no.1
• /
• pp.61-68
• /
• 2017

Electrochemical conversion of $CO_2$ and production of $H_2$ were attempted on a three-dimensionally ordered, porous metal organic framework (MOF-74) in which transition metals (Co, Ni, and Zn) were impregnated. A lab-scale proton exchange membrane-based electrolyzer was fabricated and used for the reduction of $CO_2$. Real-time gas chromatography enabled the instantaneous measurement of the amount of carbon monoxide and hydrogen produced. Comprehensive calculations, based on electrochemical measurements and gaseous product analysis, presented a time-dependent selectivity of the produced gases. M-MOF-74 samples with different central metals were successfully obtained because of the simple synthetic process. It was revealed that Co- and Ni-MOF-74 selectively produce hydrogen gas, while Zn-MOF-74 successfully generates a mixture of carbon monoxide and hydrogen. The results indicated that M-MOF-74 can be used as an electrocatalyst to selectively convert $CO_2$ into useful chemicals.

• Journal of the Korean Institute of Intelligent Systems
• /
• v.21 no.1
• /
• pp.49-54
• /
• 2011

In this paper, we represent a mobile robot which can recognize chemical odor, measure concentration, and track its source indoors. The mobile robot has the function of smell that can sort several gases in experiment such as ammonia, ethanol, and their mixture with neural network algorithm and measure each gas concentration with fuzzy rules. In addition, it can not only navigate to the desired position with vision system by avoiding obstacles but also transmit odor information and warning messages earned from its own operations to other nodes by multi-hop communication in wireless sensor network. We suggest the way of odor sorting, concentration measurement, and source tracking for a mobile robot in wireless sensor network using a hybrid algorithm with vision system and gas sensors. The experimental studies prove that the efficiency of the proposed algorithm for odor recognition, concentration measurement, and source tracking.

• Proceedings of the KSME Conference
• /
• 2008.11b
• /
• pp.3049-3052
• /
• 2008

MCFC(molten carbonate fuel cell) power generation system is prime candidate for the utilization of fossil based fuels to generate ultra clean power with a high efficiency. In the MCFC power plant system, a combustor performs a role to supply high temperature mixture gases for cathode and heat for reformer by using the stack off-gas of the anode which includes a high concentration of $H_2O$ and $CO_2$. Since a combustor needs to be operated in a very lean condition and to avoid excessive local heating, catalytic combustor is usually used. The catalytic combustion is accomplished by the catalytic chemical reaction between fuel and oxidizer at catalyst surface, different from conventional combustion. In this study, a mathematical model for the prediction of internal flow and catalytic combustion characteristics in the catalytic combustor adopted in the MCFC power plant system is suggested by using the numerical methods. The numerical simulation models are then implemented into the commercial CFD code. After verifying result by comparing with the experimental data and calibrated kinetic parameters of catalytic combustion reaction, a numerical simulation is performed to investigate the variation of flow and combustion characteristics by changing such various parameters as inlet configuration and inlet temperature. The result show that the catalytic combustion can be effectively improved for most of the case by using the perforated plate and subsequent stable catalytic combustion is expected.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.2 no.3
• /
• pp.54-61
• /
• 1998

A numerical simulation is attempted for the regenerative cooling heat transfer processes of the liquid propellant rocket engine. The heat transfer from the combustion gases to the thrust chamber wall is called gas side heat transfer. This heat is conducted radially to the coolant through the carbon deposit and metallic wall of thrust chamber Finally, this heat is convected away by the coolant flowing along the passages in the thrust chamber. The equivalence of these three heat fluxes of the above processes is utilized to determine the coolant side wall temperature, gas side wall temperature and the heat flux. When the number and shape(width, height) of coolant passages, the shape(size) of thrust chamber, oxidant and fuel properties, coolant properties, oxidant/fuel mixture ratio, coolant inlet temperature, the thickness of carbon deposit formed along the thrust chamber wall during combustion are given, reasonable radial direction temperature distributions and heat fluxes along the thrust chamber axis are obtained.

• Korean Chemical Engineering Research
• /
• v.48 no.2
• /
• pp.232-243
• /
• 2010

Gas hydrates are crystalline solids composed of water and gas molecules. Water molecules are linked through hydrogen bonding and create cavities(host lattice) that can capture a large variety of guest molecules under appropriate conditions, generally high pressure and low temperature. Recently, many researchers try to apply gas hydrates to industrial processes to capture greenhouse gases due to the facts that the process is eco-friendly and target gas molecules can be preferentially captured. In this paper, we introduced recent studies on $CO_2$ and $CO_2-N_2$ mixture hydrates to evaluate the feasibility of industrial application of gas hydrate technology to $CO_2$ capture process. Specifically, we put emphasis on the technical feasibility of $CO_2$ separation in steel industry using gas hydrate formation principles.