• Title/Summary/Keyword: Mixture Gases

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Microstructure and Nano-hardness of SiC/C Multi-coated Layers on a Particulate Nuclear Fuel (입자 핵연료의 SiC/C 다층 도포층의 미세조직 및 극미세 경도 평가)

  • Choi, Young
    • Journal of the Korean institute of surface engineering
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    • v.52 no.6
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    • pp.321-325
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    • 2019
  • Triso-type coating layers of silicon carbide and graphite on UO2 paticulate nuclear fuel were prepared by using fluidized bed type chemical vapor deposition and self-propagating high temperature synthesis methods to make a coated nuclear fuel of a power plant for hydrogen mass-production. The source and carrier gases were the mixture of methyltrichlorosilane and propane, and inert argon. Chemical analysis and microstructure observation showed that the coated layers were inner graphite, middle silicon carbide and outer graphite. The elastic modulus and nano-hardness of the silicon carbide layer were 503 [GPa] and 36 [GPa], respectively.

Production of Nanosized WC Powder by Vapor Phase Reaction

  • Cho, Gi-Chul;Lee, Gil-Geun;Ha, Gook-Hyun;Kim, Byung-Kee
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.625-626
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    • 2006
  • In the present study, the focus is on the synthesis of nanosized WC powder by the chemical vapor condensation proces. The synthesized W-C system powder by the CVC process shows W2C, W, WO3 phases and can not shows WC phase. After recarburization heat treatment under mixture gas atmosphere of argon and hydrogen gases, the synthesized W-C system powder fully transformed to the pure WC. The synthesized WC powder after recarburization heat treatment has an average particle size of 20 nm. The nano-sized WC powder can be prepared by the combination of the CVC process and heat treatment methods.

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Study on Mobile Broadband Coherent Anti-Stokes Raman Spectrometer For Combustion Diagnostics (연소진단용 이동형 광대역 코헤런트 반 스톡스 라만 분광기에 관한 연구)

  • Park, Chul-Woung;Park, Seung-Nam;Hahn, Jae-Won;Lee, Jong-Ung
    • Journal of the Korean Society of Combustion
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    • v.1 no.2
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    • pp.9-20
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    • 1996
  • We construct a mobile broadband coherent anti-Stokes Raman spectroscopy system to measure the temperature of combustion gases. To improve the accuracy of CARS temperatures due to Stokes lasers, a modeless dye laser is constructed. A monochromator to disperse CARS spectra is also constructed in the spectrometer for easy portability. The accuracy of CARS temperature, measured in graphite tube furnace in reference to a radiation pyrometer, is better than 2 % from 1000 K to 2400 K. The CARS temperature error due to the variation of the spectral distribution of the modeless laser is measured to be less than 1.5 % during five hours operation. As a demonstration of combustion diagnosis, we applied the spectrometer to measure the temperature distribution of the propane air premixed flame.

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Discharge Characteristics of SF6 Mixture Gases in Non-Uniform Fields (불평등전계하에서의 SF6 혼합가스의 방전 특성)

  • Ko, Yeon-Sung;Seo, Ho-Joon;Rhie, Dong-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.523-524
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    • 2006
  • 본 논문에서는 질소와 이산화탄소를 완충기체로 사용하는 경우의 혼합가스에 대해 가스절연설비 내부의 이물질에 의한 절연파괴특성을 모의하기 위한 침-평판 전극구조에서의 침전극 재질을 연철, 고탄소강, 스테인레스강 등으로 구성한 경우 혼합가스의 절연파괴 특성에서 나타나는 전극 재질에 의한 영향을 실험적으로 검토해 보았다. 실험 결과 연철제 전극과 고탄소강제 전극의경우에는 혼합가스의 절연파괴특성에서 유사한 N-특성이 나타남을 확인할 수 있었으나 스테인레스 강제 전극의 경우에는 다소 상이한 양상이 나타났다. $SF_6$계 혼합가스의 경우에는 순 $SF_6$의 경우와 동일하게 코로나 안정화작용에 의한 N-특성이 발현됨이 일반적인 특성으로 알려져 있으나 본 실험 결과에 의하면 침전극 재질에 따라 다소 상이한 양상이 나타날 수 있음을 관측하였다.

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Comparison of Thermodynamic Properties of Alternative Fire Extinguishing Agent (대체 소화제의 열역학적 물성 비교)

  • 김재덕;여미순;이광진;이윤우;장윤호;노경호
    • Fire Science and Engineering
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    • v.18 no.1
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    • pp.7-12
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    • 2004
  • For CFCs and Halons regulated by Montreal Protocol and their alternatives of HFC-23, HFC-125 HFC-227ea, HFC-236fa and the mixtures of inert gases of $Ar, N_2 and CO_2$, the thermodynamic properties of saturated pressure, density, enthalpy and viscosity were compared. In this study, the data from literature were expressed as a function of temperature. Thermodynamic properties of HFC compounds were similar to those of Halon-1301. Inert gas was mainly used as a mixture, but the physical properties of the inert gas does not have the favorable advantages over those of Halon-1301.

Current State and Future of Refrigerants for Refrigeration and Air Conditioning

  • Kagawa, Noboru
    • International Journal of Air-Conditioning and Refrigeration
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    • v.15 no.4
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    • pp.182-190
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    • 2007
  • Refrigeration and air-conditioning equipments are indispensable products in this civilized society. However, discharged refrigerants used in the equipments and exhausted carbon dioxide to drive the refrigeration and air-conditioning equipments are related to serious environmental problems and energy problems. Especially, the destroyed ozonosphere by the discharged refrigerants and the increased normal temperature by carbon dioxide and fluorocarbon refrigerants (green house gases) are sounded as serious global problems. For alleviating these problems, environmental-friendly refrigeration and air-conditioning equipments must be developed and will spread soon. To develop new equipment, a suitable refrigerant for each usage must be presented. In this paper, the current state of refrigerants was introduced. And, thermophysical properties of the refrigerants were introduced briefly. From the properties, the refrigerants and refrigeration cycles are promising to be used in the future, were proposed

Application of the WSGGM for arbitrary gas mixtures of water vapor and carbon dioxide (임의 성분비로 구성된 수증기-이산화탄소 혼합가스에 대한 회색가스가중합법의 적용 연구)

  • Park, Won-Hee;Kim, Tae-Kuk
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.6
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    • pp.88-95
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    • 2003
  • The weighted sum of gray gas model(WSGGM) is applied to arbitrary mixtures of CO$_2$ and H$_2$0 gases. To evaluate this model, the spectral and total intensities are obtained for two different problem types. One has uniform, parabolic and boundary layer type temperature profiles with uniform partial pressure, and the other has nonuniform partial pressure and temperature profile. The results obtained from the two different problem types show fairly good agreements with the results obtained by the statistical narrow band model(SNB model) which is regarded as the reference solutions. The WSGGM and its data base provided by this study can be used for analysis of radiative transfer by combustion gases with different thermal loadings and chemical compositions.

Experimental study on the applicability of liquid air as the refrigerant in artificial ground freezing for subsea tunnels (해저터널을 위한 동결공법 냉매로서의 액화공기 적용성에 대한 실험적 연구)

  • Son, Young-Jin;Choi, Hyeungchul;Moon, Hung-Man;Choi, Hangseok;Ko, Tae Young
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.18 no.2
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    • pp.175-181
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    • 2016
  • In this paper, the liquid air was selected as the refrigerant in artificial ground freezing to be used for rapid ground freezing and to reduce the risk of suffocation and the applicability of liquid air was verified. In order to evaluate the stability of the liquid air, the oxygen concentration of mixtures with liquid nitrogen and liquid oxygen was experimentally examined to meet the oxygen concentration criteria in the Occupational Safety and Health Act. In addition, the effects of the mixture ratio of liquid nitrogen and liquid oxygen, pressure and flow rate change in the storage vessel on the oxygen concentration in the liquid air were investigated. As a result, the ratio of liquid nitrogen and liquid oxygen 8: 2 was shown to meet the oxygen concentration standards. Pressure and flow rate change in the storage vessel did not have significant effects on the oxygen concentration in the liquid air.

Sensitivity Characteristics on the Composition Change of the Gas Sensing Materials based on $In_2O_3$ Semiconductor. ($In_2O_3$계 반도성 가스감지재료의 조성변화에 따른 감도특성)

  • 정형진;유광수
    • Journal of the Korean Ceramic Society
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    • v.22 no.4
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    • pp.54-60
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    • 1985
  • Gas sensing materials for detecting flammable gases such as $CH_4$, $C_3H_8$ and n-$C_4H_{10}$ were developed by util-izing $In_2O_3$ as the principal sensing material. The sensing materials were formulated by mixing $In_2O_3$ powder with one or two other chemicals such as $SnO_2$, $Y_2O_3$ and $Al_2O_3$ with a small addition of $PdCl_2$ as a catalyst. Sample of sensor were fabricated by coating each of the mixtures on a ceramic tube impregnating ethylsili-cate and firing at 75$0^{\circ}C$ Each material mixture was evaluated by measuring and comparing gas sensitivity(resistance in air/resistance with gas) to flammable gases such as $CH_4$, $C_3H-8$ and n-$C_4H_{10}$. It was found that among fifteen compositions tested three compositions as follows show the highest gas sensitivity and thus are very feasible for commercialization as the gas sensors ; o49.5 $In_2O_3$+50 Al2O3_0.5 PdCl2(wt%) o $20In_2O_3+29$ $SnO_2+50$ $Al_2O_3+1$ $PdCl_2$(wt%) o40 $In_2O_3$+9 $Y_2O_3+50$ $Al_2O_3+1$ $PdCl_2$(wt%)

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FBAR devices employing the ZnO:N films (질소 주입된 산화아연 박막을 사용한 박막 음향 공진 소자 연구)

  • Lee, Eun-Ju;Zhang, Ruirui;Yoon, Gi-Wan
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2011.05a
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    • pp.696-698
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    • 2011
  • We present a new method for the fabrication of film bulk acoustic wave resonator (FBAR) devices that exploits the thin piezoelectric ZnO films particularly sputter-deposited in a mixture of N2O and Ar gases as the reactive and sputtering gases, respectively. Some thermal annealing treatments were performed on the as-deposited ZnO films and also their effects on the resonance characteristics of the FBAR devices were investigated. It was found that with an optimized process, the resonance characteristics of the fabricated FBAR devices could be further improved.

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