• Title/Summary/Keyword: Mixture Electrode

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Improvement in Catalytic Activity of Ag Catalyst via Simple Mixing with Carbon

  • Choun, Myounghoon;Baek, Ji Yun;Eom, Taehyoung
    • KEPCO Journal on Electric Power and Energy
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    • 제5권4호
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    • pp.331-335
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    • 2019
  • In this study we investigate catalytic activity and selectivity of mixture of Ag and ketjenblack according to their ratios by product analysis and electrochemical experiments, such as cyclic voltammetry, linear sweep voltammetry and chronoamperometry. We reveal that catalytic activity toward CO2 reduction to CO is improved by simple mixing Ag nanoparticle and ketjenblack because addition of ketjenblack suppresses aggregation of Ag nanoparticles and brings increase in electrochemical active surface area. However, excess amount of ketjenblack rather inhibit the CO2 reduction to CO. These observations provide clues to develop highly active Ag catalyst or electrode toward electrochemical reduction of CO2.

Casein - Ammonium bichromate 감광성수지의 패턴형성 및 에칭공정에 있어서 Facter들에 관한 연구 (A Study on the factors of Casein-Ammonium bichromate photoresist in pattern formation and etching process)

  • 이형관
    • 한국인쇄학회지
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    • 제12권1호
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    • pp.67-80
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    • 1994
  • Electrochrominm is a phenomenon of reversible change in optical properties produced electrochromically. Among the several organic type electrochromic displays(ECD), the one based on viologen solution is still attractive and become of the possibility for choosing various colors by introducing different substituents in viologen molecules. But these has been rather a severe problem in this type of ECD, which is the erasing failure caused by the recrystallized molecule sticking to the display electrode.This paper was investigated on developing a new class of composite materials which consists of the mixture of BV2+ . 2BF4-, TMPD with TBABF4 as supporting electrolyte to overcome the above mentioned problem of viologen solution.

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ER 유체를 이용한 미세3차원 행상의 초정밀연마 (Ultraprecision Polishing Technique for Micro 3-Dimensional Structures using ER Fluids)

  • 김욱배;이상조;김용준;이응숙
    • 한국정밀공학회지
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    • 제19권12호
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    • pp.134-141
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    • 2002
  • The ER fluid can be one of efficient materials in ultraprecision polishing for optics, ceramics and semiconductors because of electrically controllable apparent viscosity. To finish small 3 dimensional structures such as the aspherical surface in optical elements, the possible arrangement of a tool, workpiece and auxiliary electrode is described. We examined the influence of the addition of a few abrasive particles on the performance of the ER fluid by measuring yield stress, and observed the behavior of abrasive particles in the ER fluid by a CCD camera, which is also theoretically predicted from the electromechanical principles of particles. On the basis of the above results, the steady flow analysis around the rotating micro tool is worked out considering the non-uniform electric field. Finally, Pyrex glass is polished using the mixture of the ER fluid and abrasive particles, and the effect of the electric field strength is evaluated.

전기장 분산기술을 이용한 에폭시 마이크로-나노 입자가 혼합된 콤포지트의 전기적 그리고 기계적특성 (Electrical and Mechanical Properties for Micro-and-Nano Mixture Composites using Electric Field Dispersion Technique)

  • Cho, Dae-Lyoung;Han, Jin-Hee;Kim, Jung-Joong;Kim, Jung-Hoon;Yoo, Byoung-Bok;Park, Jae-Jun
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2010년도 하계학술대회 논문집
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    • pp.98-98
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    • 2010
  • A epoxy/multilayered silicate nanocomposite was prepared by a new AC electric application method and micro silica particle was poured into the nanocomposite in order to prepare epoxy/micro-and-nano- mixed composites (EMNC). Electric insulation breakdown strength was measured in a sphere-sphere electrode system designed for the prevention of edge breakdown and the data were estimated by Weibull plot. As the exfoliated silicate nano-plates were homogeniously dispersed in the micro silica particles, the insulation property was higher.

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Comparison of chemical properties of Co(II) and Cu(II) Compounds with Bis-Phenol A(Endocrine Disrupter)

  • Park, Chil-Nam
    • 한국환경과학회지
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    • 제11권5호
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    • pp.437-443
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    • 2002
  • The chemical behavior and properties of the redox state of environmental pollutants were investigated using electrochemical methods. Cyclic voltammograms were performed on the compounds to measure the variations in the redox reactions. Temperature and pH were established as influencing the redox potential and current. The electrode reactions were a mixture of quasi-reversible and irreversible Precesses, which changed according to the reaction current. Although the Co(BPA)$_2$ and Cu(BPA)$_2$ compounds were not found to dissociate in wastewater, they were very unstable(K=1.02).

액상수은 제어를 위한 다공성 탄소입자 제조에 관한 연구 (Synthesis of Porous Carbon Particles for the Absorption of Mercury)

  • 이정민;강신재;박수진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.305-305
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    • 2009
  • The carbon nano-structured materials could be applied to the fields of advanced fillers, templates, electrode materials, sensor, storage, and absorption materials. The polyacrylonitrile (PAN) based carbon nano-particles provide the remarkable properties of high specific surface area, large pore volume, chemical inertness, and good mechanical stability. In this study, well-defined carbon nano-particles were obtained through pyrolysis of polyacrylonitrile based particles. The precursor nano-particles were prepared by modified aqueous dispersion polymerization using hydrophilic poly(vinyl alcohol) in a water/ N,N-dimethylformamide mixture media. Synthesized precursor nanoparticles have relatively monodisperse particles ranging 80 ~ 250nm. Stable spherical particles are obtained without coagulum or secondary particles in our system. The characteristic of the carbon nanoparticles were investigated in terms of surface area, morphology, and size distribution.

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정적 연소실 내에서의 2유체 가솔린 분사기의 착화 특성에 대한 실험적 연구 (An experimental study on the ignition characteristics of an air-assisted gasoline injector in a constant volume combustion chamber)

  • 이용표;김승수
    • 오토저널
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    • 제14권4호
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    • pp.31-38
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    • 1992
  • The objective of this study is to determine the ignition feasibility of a single shot, air-assisted gasoline fuel injector operated in a constant volume combustion chamber under atmospheric condition. A number of parameters has been selected for this experiments, such as dwelling time, spark gap position(r,z), spark electrode geometry, supplied air and fuel masses and spray cone deflector angle. On-site visual inspection of the instantaneous flame glow was chosen as one way to judge the successful ignition. In addition, chamber pressure and occasional photography were mobilized as for data recording. It was clearly observed that there was an entrainment air-fuel mixture toward spray axis from the spray formation and its development later on. The optimum ignition conditions were found for those parameters given above.

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Effect of bath conditions and pulse parameters on tin surface finish for microelectronic packaging applications

  • Sharma, Ashutosh;Jung, Do-hyun;Jung, Jae-pil
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2015년도 추계학술대회 논문집
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    • pp.232-233
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    • 2015
  • The effects of various bath conditions such as surfactant concentration, bath pH, bath temperature, agitation of bath; as well as pulse parameters such as cathodic current density, pulse duty cycle and frequency, on the grain size, surface finish, and appearance of the tin plated coatings have been investigated. The plating bath under investigation is an aqueous acidic solution composed of a mixture of $SnSO_4$, $H_2SO_4$, and a surfactant. The bath conductivity and pH are measured by a glass pH electrode. The microstructure of the coatings produced is characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and surface profilometry. XRD analysis shows that the deposits consist of tetragonal ${\beta}$-Sn crystal structure irrespective of plating conditions. The mechanism involved in the morphology evolution in response to various parameters and conditions has also been discussed.

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반응성 마그네트론 스퍼터링으로 제작한 TiN의 전기적 특성 (The electric properties of TiN made by reactively magnetron sputtering)

  • 김종진;신인철;이상미;김홍배
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
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    • pp.75-78
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    • 1996
  • The deposition condition Gf TiN films as electrode was studied by sheet resistance, TiN depositon Thickness X-ray diffraction. TiN was made by reactively DC magnetron sputtering with varying $N_2$/Ar mixture gas and substrate temperature. After finding The deposition condition of TiN films, The samples with the structure of Cu/Ta$_2$O$_{5}$, TiN/Ta$_2$O$_{5}$Si, Cu/TiN/Ta$_2$O$_{5}$ Si were prepared and were measured I-V, C-V. As a results, it was found that when TiN was deposited in an $N_2$a results, it was found that when TiN was deposited in an $N_2$atmosphere its Sheet resistance is lower n than n V$_2$Ar mixtureixture

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Rugate 광결정에서 광학띠와 식각전류의 상관관계 (Intercorrelation between Photonic Band and Etch Current on Rugate Photonic Crystals)

  • 박종선;김용민
    • 통합자연과학논문집
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    • 제2권3호
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    • pp.207-210
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    • 2009
  • Multiple rugate structures can be etched on a silicon wafer and placed in the same physical location, showing that many sharp spectral lines can be obtained in the optical reflectivity spectrum. Porous silicon samples were prepared by electrochemical etch of heavily doped p-type silicon wafers. The etching solution consisted of a 3:1 volume mixture of aqueous 48% hydrofluoric acid and absolute ethanol. Galvanostatic etch was carried out in a Teflon cell by using a two-electrode configuration with a Pt mesh counterelectrode. A sinusoidal current density waveform varying between 51.5 and $74.6mA/cm^2$ is applied. The anodization current was supplied by a Keithley 2420 high-precision constant current source which is controlled by a computer to allow the formation of PSi multilayer.

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