• Title/Summary/Keyword: Mixture Behavior

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Investigation of Linear Viscoelastic Properties of Xanthan-Carob Mixture in Sol and Gel States

  • Yoon, Won-Byong;Gunasekaran, Sundaram
    • Food Science and Biotechnology
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    • v.18 no.3
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    • pp.618-623
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    • 2009
  • Synergistic interactions between xanthan (X) and carob (C) were investigated by studying the linear viscoelastic behavior of X, C, and X/C mixtures at sol and gel states. At the solution state, storage modulus (G') dominates the linear viscoelastic properties of X/C mixtures. The gelation temperature (52 to $57^{\circ}C$) was weakly dependent on the xanthan fraction (${\phi}x$) in the mixture. The ${\phi}x$ also had a strong effect on G' until ${\phi}x=0.5$. The elastic active network concentration (EANC) of X/C gels was estimated from the pseudo-equilibrium modulus. The EANC for systems with ${\phi}x=0.25$, 0.5, 0.75, and 1 at 1% total concentration was 2.3, 4.4, 4.1, and 0.32 (${\times}10^{-3}\;mol/m^3$), respectively. The maximum synergistic effect was observed at about ${\phi}x=0.5$. The G' at the transition state of X/C mixed gel was proportional to ${\omega}^{3/2}$ at ${\omega}$>${\omega}_{tr}$ (the onset transition frequency) compared to the theoretical limit of ${\omega}^{1/2}$.

Microstructure and Sintering Behavior of W-15 wt%Cu Nanocomposite Powder Prepared from W-CuO Mixture (W-CuO 혼합물을 이용하여 제조된 W-Cu나노복합분말의 미세구조와 소결거동에 관한 연구)

  • 김길수;김대건;김영도
    • Journal of Powder Materials
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    • v.10 no.4
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    • pp.270-274
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    • 2003
  • Recently, the fabrication process of W-Cu nanocomposite powders has been researched to improve the sinterability by mechanochemical process (MCP), which consists of ball milling and hydrogen-reduction with W- and Cu-oxide mixture. However, there are many control variables in this process because the W oxides are hydrogen-reduced via several reduction stages at high temperature over 80$0^{\circ}C$ with susceptive reduction conditions. In this experiment, the W-15 wt%Cu nanocomposite powder was fabricated with the ball-milling and hydrogen-reduction process using W and CuO powder. The microstructure of the fabricated W-Cu nanocomposite powder was homogeneously composed of the fine W particles embedded in the Cu matrix. In the sintering process, the solid state sintering was certainly observed around 85$0^{\circ}C$ at the heating rate of 1$0^{\circ}C$/min. It is considered that the solid state sintering at low temperature range should occur as a result of the sintering of Cu phase between aggregates. The specimen was fully densified over 98% for theoretical density at 120$0^{\circ}C$ for 1 h with the heating rate of 1$0^{\circ}C$/min.

Effect of performance method of sand compaction piles on the mechanical behavior of reinforced soft clay

  • Kwon, Jeonggeun;Kim, Changyoung;Im, Jong-Chul;Yoo, Jae-won
    • Geomechanics and Engineering
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    • v.14 no.2
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    • pp.175-185
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    • 2018
  • Sand Compaction Piles (SCPs) are constructed by feeding and compacting sand into soft clay ground. Sand piles have been installed with irregular cross-sectional shapes, and mixtures of both sand and clay, which violate the design requirement of circular shape according to the replacement area ratio due to various factors, including side flow pressure. Therefore, design assumptions cannot be satisfied according to the conditions of the ground and construction and the replacement area ratio. Two case histories were collected, examined, and interpreted in order to study the effect of the shape of SCPs. The effects of the distortion of SCP shape and the mixture of sand and clay were studied with the results of large direct shear tests. The design internal friction angle was secured with the irregular cross-sectional sand piles regardless of the replacement area ratio. The design internal friction angle was secured regardless of mixed condition when the mixture of sand and clay was higher than the replacement area ratio of 65%. Therefore, systematic construction management is recommended with a replacement area ratio below 65%.

Synthesis of Glycidyl Azido Copolyetherdiol for Solid Propellant Polyurethane Binder (Glycidyl Azido Copolyetherdiol을 이용한 Polyurethane의 합성과 특성분석)

  • Shin, Bum-Sik;Lee, Bum-Jae;Park, Young-Chul;Hwang, Kab-Sung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.231-236
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    • 2008
  • The well-defined copolymers derived from Epichlorohydrin(ECH), Tetrahydrofuran(THF) were synthesized by Cationic ring-opening polymerization(CROP) with 1,4-Butandiol, a initiator, and $BF_3THF$ Complex, a catalyst via Activated monomer mechanism, which could lead to hydroxyl-terminated polyethers. The molecular weight of polymers were dependant on the ratio of [monomer]/[diol], Copolymer structures were controlled by monomers feed ratio, ECH and THF added. This polymers were functionalized from Chlorine group to Azide group using $S_N2$ reaction. Synthesized polymers were found to be as the prepolymer for polyurethane. Polyurethane was synthesized in the presence of N-100/IPDI mixture, a curing agent, and TPB(triphenyl bismuth)/MA(Maleic anhydride) mixture, a catalyst system. The curing behavior and mechanical properties of polyurethane after mixing with various prepolymer’s composition and the molecular weight were studied.

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Energy Ratio Factor and Phase Angle Based Fatigue Prediction Model for Flexible Pavements

  • Kim, Nak-Seok
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.2
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    • pp.75-80
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    • 2011
  • The main objective of this research is to develop fatigue prediction model for flexible pavements using energy ratio factor and phase angle. The two parameters are considered as fundamental properties of time and temperature dependent viscoelastic asphalt concrete materials. The energy ratio factor is defined as the ratio of the pseudo-total cumulative dissipated energy to the cumulative dissipated energy to failure during the test. The phase angle between the stress and strain ware signals stems from the intrinsic the dependent asphalt mixture behavior. The phase angle was computed and the relationship between the initial mixture stiffness and the initial phase angle is presented. As a result, fatigue prediction model for flexible pavements was proposed using intrinsic properties of viscoelastic asphalt concrete materials.

Development of an ECCS Injection Model By Gravity and Flow Rate Distributions in the Passive Reactor Systems (비상노심냉각수의 중력에 의한 주입 및 피동형노심내의 흐름율 분포모델의 개발)

  • Lim, H.G.;Kim, G.S.;Lee, U.C.
    • Nuclear Engineering and Technology
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    • v.26 no.4
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    • pp.562-569
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    • 1994
  • In this study improvement of transient analysis model, KOTRAC, for the passive reactor has been performed. In the KOTRAC, mixture drift flux model is adopted to simulate thermal hydraulic behavior, which can simulate ECCS injection in the passive plant. However, there is a difficulty to handle complete phase separation phenomena due to the near-zero density, which may occur in the pressurizer surge line or horizontal flow paths. In this study, a couple of model changes to over-come Courant limit feilure has been examined. One of key features is to substitute flow distribution parameters with Ishii's correlation. Corrected results are nil compared to those of RELAP/MOD3 analysis.

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Fabrication of $YBa_2Cu_3O_{7-{\delta}}$ Superconducting Coils with Polymer Binder (유기물 바인더를 사용한 $YBa_2Cu_3O_{7-{\delta}}$ 초전도 Coil의 제조)

  • 정해원;박승만;김재묵;김성수
    • Journal of the Korean Ceramic Society
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    • v.27 no.3
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    • pp.355-360
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    • 1990
  • One of the possible ways to make a flexible wire of high-Tc superconductiong ceramics is the extrusion of a mixture slurry of superconducting powder with an appropriate polymer binder. The fabrication procedure for $YBa_2Cu_3O_{7-{\delta}}$ superconducting coils with this plastic mass is described. The major factors limiting the formation of extruded wire are the binder content, powder size, and entrapped gas in the mixture slurries. The optimum content of binder for both good flexbility and strength of wire was estimated to be 30wt%. The finer the powder size is, the more homogeneous structure the extruded wire has. The vacuum degassing before extrusion was necessary to remove the entrapped gas in as-extruded wire. The formability of wire depends greatly on the wire radius and binder content. After burning out the binder and the successive sintering, the contacts between the superconducting grains could be made. The resistivity vs. temperature behavior measured in the final wire showed the transition temperature of 90K with narrow transition width. However, the critical current densities of these wires are much lower in comparison to those of conventional bulk specimens.

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Motion Planning of Autonomous Racing Vehicles for Mimicking Human Driver Characteristics (운전자 주행 특성 모사를 위한 트랙 한계 자율 주행 차량의 거동 계획 알고리즘)

  • Changhee Kim;Kyongsu Yi
    • Journal of Auto-vehicle Safety Association
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    • v.16 no.1
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    • pp.6-11
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    • 2024
  • This paper presents a motion planning algorithm of autonomous racing vehicles for mimicking the characteristics of a human driver. Time optimal maneuver of a race car has been actively studied as a major research area over the past decades. Although the time optimization problem yields a single time series solution of minimum time maneuver inputs for the vehicle, human drivers achieve similar lap times while taking various racing lines and velocity profiles. In order to model the characteristics of a specific driver and reproduce the motion, a stochastic motion planning framework based on kernelized motion primitive is introduced. The proposed framework imitates the behavior of the generated reference motion, which is based on a small number of human demonstration laps along the racetrack using Gaussian mixture model and Gaussian mixture regression. The mean and covariance of the racing line and velocity profile mimicking the driver are obtained by accumulating the outputs tested at equidistantly sampled input points. The results confirmed that the obtained lateral and longitudinal motion simulates the driver's driving characteristics, which are feasible for actual vehicle test environments.

Using 3D theory of elasticity for free vibration analysis of functionally graded laminated nanocomposite shells

  • R. Bina;M. Soltani Tehrani;A. Ahmadi;A. Ghanim Taki;R. Akbarian
    • Steel and Composite Structures
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    • v.52 no.4
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    • pp.487-499
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    • 2024
  • The primary objective of this study is to analyze the free vibration behavior of a sandwich cylindrical shell with a defective core and wavy carbon nanotube (CNT)-enhanced face sheets, utilizing the three-dimensional theory of elasticity. The intricate equations of motion for the structure are solved semi-analytically using the generalized differential quadrature method. The shell structure consists of a damaged isotropic core and two external face sheets. The distributions of CNTs are either functionally graded (FG) or uniform across the thickness, with their mechanical properties determined through an extended rule of mixture. In this research, the conventional theory regarding the mechanical effectiveness of a matrix embedding finite-length fibers has been enhanced by introducing tube-to-tube random contact. This enhancement explicitly addresses the progressive reduction in the tubes' effective aspect ratio as the filler content increases. The study investigates the influence of a damaged matrix, CNT distribution, volume fraction, aspect ratio, and waviness on the free vibration characteristics of the sandwich cylindrical shell with wavy CNT-reinforced face sheets. Unlike two-dimensional theories such as classical and the first shear deformation plate theories, this inquiry is grounded in the three-dimensional theory of elasticity, which comprehensively accounts for transverse normal deformations.

Antipruritic Effects of Puerariae Radix on 5-HT or AEW-Induced Itch Behavior in Mice (5-HT 및 AEW로 소양증(搔痒症)을 유발한 흰쥐에 대한 갈근(葛根)의 진양(鎭痒)효과)

  • Han, Jae-Bok;Sun, Bo-Ram;Bu, Yung-Min;Kim, Ho-Cheol
    • The Journal of Korean Medicine
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    • v.28 no.3 s.71
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    • pp.165-172
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    • 2007
  • Objectives : To find antipruritic herbal medicines, we screened the water extracts of four herbal medicines which have been frequently prescribed to treat dermatologic diseases in oriental medicine. Methods : Water extracts of Bupleuri Radix, Scutellariae Radix, Cimicifugae Rhizoma and Puerariae Radix were administered at a dose of 300 mg/kg to male ICR mice. 1 hour later, serotonin hydrochloride dissolved in physiologic saline at a concentration of 100 nmol / 50${\mu}{\ell}$ was administered intradermally to the nape of the neck at a dose of 50${\mu}{\ell}$. Then the scratching behavior was observed. Dry skin pruritus was induced with cutaneous application of acetone / ether (1:1) mixture and water (AEW) to the rostral back of male ICR mice, twice a day for 5 days. 14 hours after the last application, the most effective material in the first experiment was administered perorally at doses of 75, 150, 300, 600 and 1200 mg/kg. 1 hour later, the scratching behavior was observed. Results : Water extracts of Puerariae Radix significantly inhibited the serotonin-induced scratching behavior and the mean of scratching bouts was reduced by half compared with the control group. Bupleuri Radix group also showed a 29% decrease in the mean of scratching bouts, but there was no statistical significance. Water extracts of Puerariae Radix also inhibited the AEW-induced scratching behavior, in a dose-dependent manner. The dose of 150 mg/kg showed the highest and statistically significant antipruritic effect. Conclusions : These results suggest that Puerariae Radix and its constituents have antipruritic effect, and are new candidates as antipruritic agents.

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