• Title/Summary/Keyword: Mixing of materials

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Electrochemical Properties of Lithium Anode for Thermal Batteries (열전지용 리튬음극의 전기화학적 특성)

  • Im, Chae-Nam;Yoon, Hyun Ki;Ahn, Tae-Young;Yeo, Jae Seong;Ha, Sang Hyeon;Yu, Hye-Ryeon;Baek, Seungsu;Cho, Jang Hyeon
    • Applied Chemistry for Engineering
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    • v.29 no.6
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    • pp.696-702
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    • 2018
  • Recently, the current thermal battery technology needs new materials for electrodes in the power and energy density to meet various space and defense requirements. In this paper, to replace the pellet type Li(Si) anode having limitations of the formability and capacity, electrochemical properties of the lithium anode with high density for thermal batteries were investigated. The lithium anode (Li 17, 15, 13 wt%) was fabricated by mixing the molten lithium and iron powder used as a binder to hold the molten lithium at $500^{\circ}C$. The single cell with 13 wt% lithium showed a stable performance. The 2.06 V (OCV) of the lithium anode was significantly improved compared to 1.93 V (OCV) of the Li(Si) anode. Specific capacities during the first phase of the lithium anode and Li(Si) were 1,632 and $1,181As{\cdot}g^{-1}$, respectively. As a result of the thermal battery performance test at both room and high temperatures, the voltage and operating time of lithium anode thermal batteries were superior to those of using Li(Si) anode thermal batteries. The power and energy densities of Li anode thermal batteries were also remarkably improved.

Recycle of Unburned Carbon and Microceramics as Alternatives to Rubber Weight-Adding Materials and Polypropylene Filling Agents (고무증량재 및 플라스틱 충진재의 대체재로 UC와 CM의 재활용)

  • Han, Gwang Su;Kim, Dul-Sun;Lee, Dong-Keun
    • Clean Technology
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    • v.27 no.1
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    • pp.24-32
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    • 2021
  • Unburned carbon (UC) was successfully separated from fly ash by up to 85.8% in weight via froth flotation using soybean oil as a collector. An 18 wt% yield of microceramics (CM) could be achieved by employing a hydro cyclone separator located immediately after the flotation equipment. UC and CM were tested as alternatives to weight-adding material and polymer (especially polypropylene in this study) filler, respectively. Large particles of UC were broken down into smaller ones via ball milling to have an average particle diameter of 10.2 ㎛. When crushed UC was used as an alternative to clay as a rubber weight-adding material, a somewhat lower tensile strength and elongation rate than the allowed values were unfortunately obtained. In order to satisfy the standard limits, further treatment of UC is required to enhance surface energy for more intimate bonding with rubber. CM was observed in spherical forms with an average diameter of 5 ㎛. The surface of the CM particles was modified with phenol, polyol, stearic acid, and oleic acid so that the surface modified CM could be used as a polypropylene-filling agent. The flowability was good, but due to the lack of coupling forces with polypropylene, successful impact strength and flexural strength could not be obtained. However, when mixing the surface-modified CM with 1% silane by weight, a drastic increase in both the impact strength and flexural strength were obtained.

Evaluation of the HACCP System on Microbiological Hazard during Dressing Production (드레싱 제조업체의 HACCP 시스템 적용을 위한 미생물학적 위해도 평가)

  • Kwon, Sang-Chul
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.3
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    • pp.457-463
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    • 2013
  • The purpose of this study was to apply the Hazard Analysis Critical Control Point (HACCP) system to the production of dressing. The hazard analysis examined the main materials, industrial water, microbial evaluation, and airborne microorganisms of each working area, as well as the pathogenic microbial contamination risk. The survey was conducted at SJ Company in Jincheon (Chungchengbuk-do), Korea for 30 days from April 1, 2012 to April 30, 2012. The results showed that raw material microorganisms had a total plate count in industrial water below $3.00{\times}10$ CFU/mL in working room I, working room II, the packing room, washing water, and the inspection room for five times in each place. During dressing production (including heat treatment and mixing), general bacteria were detected at an average of $3{\times}10$ CFU/mL, but yeast, mold, and pathogenic bacteria were not detected. Airborne microbiological evaluation (for total plate count, yeast, and mold) found levels below the legal limit at each working area. While workers were positive for microbes in total plate counts, coliform and Staphylococcus aureus were not detected. In conclusion, standards for hygienic management should be established to prevent and decrease hazards, such as general bacteria and pathogenic microorganisms (for example, E. coli, B. cereus, Listeria spp, Salmonella spp, Staph. aureus, Clostridium perfringens, yeast, and mold), and to found critical limits for microorganisms with an HACCP system.

An Experimental Study for Electro-active Polymer Electrode and Actuator (전기활성 고분자 전극 및 구동기에 관한 실험적 연구)

  • Lee, Jun-Man;Ryu, Sang-Ryeoul;Lee, Dong-Joo;Lin, Zheng-Jie
    • Composites Research
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    • v.26 no.5
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    • pp.289-294
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    • 2013
  • A thinner is used to improve the multi-walled carbon nano-tube (CNT) and carbon black (CB) dispersion in a polymer matrix and to make a soft electrode. The electrical and mechanical properties of the soft electrodes are investigated as functions of CNT, CB and thinner content. The optimal mixing condition for the electrode is thinner 80, CNT 3.5, CB 18 (phr) on the basis of matrix (KE-12). The specific resistance of that is 73 (${\Omega}{\cdot}cm$), and tensile strength, tensile modulus, and elongation of that is 0.45 MPa, 0.21 MPa, and 184%, respectively. Also, a simple structure of the actuator with an optimized electrode and elastomer is fabricated and its characteristic is evaluated. At the operating voltage 25 kV, the displacement of an elastomer KE-12 is 2.24 mm, and that of an elastomer KE-12 with thinner 50 (phr) is 4.05 mm. It shows a higher displacement compared to that of 3M 4910 which has similar modulus. The actuator made with elastomer and electrode of the same material (KE-12) may have advantages for fatigue life and application.

The Post Annealing Effect of Organic Thin Film Solar Cells with P3HT:PCBM Active Layer (P3HT:PCBM 활성층을 갖는 유기 박막태양전지의 후속 열처리 효과)

  • Jang, Seong-Kyu;Gong, Su-Cheol;Chang, Ho-Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.2
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    • pp.63-67
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    • 2010
  • The organic solar cells with Glass/ITO/PEDOT:PSS/P3HT:PCBM/Al structure were fabricated using regioregular poly (3-hexylthiophene) (P3HT) polymer:(6,6)- phenyl $C_{61}$-butyric acid methyl ester (PCBM) fullerene polymer as the bulk hetero-junction layer. The P3HT and PCBM as the electron donor and acceptor materials were spin casted on the indium tin oxide (ITO) coated glass substrates. The optimum mixing concentration ratio of photovoltaic layer was found to be P3HT:PCBM = 4:4 in wt%, indicating that the short circuit current density ($J_{SC}$), open circuit voltage ($V_{OC}$), fill factor (FF) and power conversion efficiency (PCE) values were about 4.7 $mA/cm^2$, 0.48 V, 43.1% and 0.97%, respectively. To investigate the effects of the post annealing treatment, as prepared organic solar cells were post annealed at the treatment time range from 5min to 20min at $150^{\circ}C$. $J_{SC}$ and $V_{OC}$ increased with increasing the post annealing time from 5min to 15min, which may be originated from the improvement of the light absorption coefficient of P3HT and improved ohmic contact between photo voltaic layer and Al electrode. The maximum $J_{SC},\;V_{OC}$, FF and PCE values of organic solar cell, which was post annealed for 15min at $150^{\circ}C$, were found to be about 7.8 $mA/cm^2$, 0.55 V, 47% and 2.0%, respectively.

An Experimental Study for the Development of Soil Injection Materials using Vietnam's Circulating Resources (베트남 순환자원을 활용한 지반주입재 개발을 위한 실험적 연구)

  • Young-Won, Lee;Kwang-Wu, Lee;Se-Gwan, Seo;Wan-Kyu, Yoo;Jae-Hyun, Park
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.457-464
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    • 2022
  • In this study, XRF, Loss on ignition, SEM, and PSA analysis were performed on four types of fly ash in Vietnam and compared with fly ash in Korea. As a result, PC boiler fly ash in Vietnam has a similar chemical composition to that of PC boiler fly ash in Korea, where the content of SiO2, Al2O3, and Fe2O3 accounts for about 70%. In addition, the result showed that blast furnace slags in Vietnam and Korea have similar quality criteria and performance. A binder material mixing test using four types of fly ash supplied from Vietnam was conducted, and the compressive strength ranged from 7.60 to 13.25 MPa after 28 days of curing. Vinh Tan fly ash showing the highest compressive strength was selected as the soil injection material for the chemical grouting method. For the formulation of the chemical grouting method, sodium silicate No.3 and silica-sol were used as liquid-A. As a result of measuring the gel time and the compressive strength of the homogel, they showed good performance satisfying the quality criteria applied in Korean construction fields. Therefore, Vinh Tan fly ash can be used as a soil injection material for the chemical grouting method.

Mantle Source Lithologies of Late Cenozoic Basaltic Rocks and Two Varieties of Enriched Mantle in the Korean Peninsula (한반도 신생대 후기 현무암의 근원 맨틀 암상과 두 종류의 부화 맨틀)

  • Choi, Sung Hi
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.183-197
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    • 2022
  • Geochemical data, including Sr-Nd-Pb-Mg-Zn isotopes, reported on the late Cenozoic intraplate basaltic rocks in the Korean Peninsula (Mt. Baekdu, Jeongok, Baengnyeong Island, Pyeongtaek, Asan, Ganseong, Ulleung Island, Dok Island, and Jeju Island) are summarized to constrain their mantle source lithologies, and the nature of mantle end-members required. In the Sr-Nd isotope correlation diagram, Jeju basalts plot in the field of EM2-type oceanic island basalts (OIB), while the other basalts fall in the EM1-type OIB field. In Pb-Pb isotope space, Jeju basalts show a mixing array between Indian MORB and EM2 component, whereas the other basalts display an array with EM1 component. The Korean basalts were derived from a hybrid source of garnet lherzolite and recycled stagnant slab materials (eclogite/pyroxenite, pelagic sediments, carbonates) in the mantle transition zone. The EM1 component could be ancient (~2.0 Ga) K-hollandite-bearing pelagic sediments that were isolated for a long period in the mantle transition zone due to their neutral buoyancy. The EM2 component might have been relatively young (probably Pacific slab) and recently recycled clay-rich pelagic sediments. Eclogite and carbonates are unlikely to account for the EM components, but they are common in the mantle source of the Korean basalts.

Manufacturing Tailored Powder Activated Carbon for Removing Perchlorate in Water (수중 과염소산염(Perchlorate) 제거를 위한 맞춤 분말활성탄 제조)

  • Kim, Sang-Goo;Song, Mi-Jeong;Choi, Keun-Joo;Ryu, Pyung-Jong;Kim, Shin-Chul;Lee, Yong-Doo
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.6
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    • pp.637-641
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    • 2008
  • The aims of this research were to manufacture tailored powder activated carbon having a higher prechlorate removal efficiency and to compare perchlorate removal efficiency with different carbon materials for applying to the drinking water treatment plant. Activated carbon pre-loaded with cetyltrimethylammonium chloride(CTAC) has been researched to be an effective adsorbent for removing perchlorate in the water. 10,000 mg/L tailored powder activated carbon were manufactured by mixing 5.0 g of powder activated carbon(PAC) into 500 mL of 5,000 mg/L CTAC solution. The tailored powder activated carbon had 10 times higher perchlorate removal efficiency than virgin powder activated carbon. The residual perchlorate gradually decreased with the first 15 minute contact time with the tailored powder activated carbon, however, the longer contact time did not affect perchlorate removal. Tailored powder activated carbon by manufactured with 1,083 mg/g iodine value carbon had almost 4 times higher perchlarate removal efficiency than the 944 mg/g iodine value carbon. Dosage of 5 mg/L tailored powder activated carbon, which can adaptable dosage at the treatment plant, could decrease the perchlorate concentration from 50 $\mu$g/L to 15 $\mu$g/L.

Experimental Study of Removing Epoxy Resin from Iron Object using Nd:YAG Laser Cleaning System (철제유물에 사용된 에폭시수지 제거를 위한 Nd:YAG 레이저 클리닝 실험 연구)

  • Lee, Hye-Youn;Cho, Nam-Chul;Lee, Jong-Myoung;Yu, Jae-Eun
    • Journal of Conservation Science
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    • v.27 no.3
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    • pp.301-312
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    • 2011
  • Epoxy resin has superior durability and adhesive strength and proper physical strength so that it is used to diversity materials for multi-purposes. However epoxy resin is hardly removed after hardening specially once it is applied to artefacts, it is difficult to remove them under re-conservation. This paper is an experimental study on removing epoxy resin applied to iron objects using Nd:YAG laser cleaning system. Tests conducted in this study investigated how increasing laser energy and pulses would give effect on samples. The samples were prepared in a way that epoxy resin, itself pure and one which was mixed with pigment and they were applied to iron coupons and corroded iron coupons respectively. As a result of experiment, pure epoxy resin applied to corroded iron coupons was ablated at high laser energy but epoxy resin applied to iron coupons and mixing with pigment were not ablated but discolored and bubbled due to laser-induced heat generation. Results of FT-IR showed no component alteration of shifted resins and no residues on the surfaces ablated by laser irradiation. From SEM-EDS for removed surfaces, the debris from epoxy resin and melting iron was observed. Therefore, this study demonstrated the possibilities and limitations for laser cleaning to remove epoxy resin from iron objects.

A Study on Plywood Glue Extender from Bark and Particle Board Sander Dust (수피(樹皮) 및 파티클보드 폐기분말(廢棄粉末)을 이용(利用)한 합판(合板)의 증량(增量)에 관(關)한 연구(硏究))

  • Lee, Phil-Woo;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.11 no.1
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    • pp.12-17
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    • 1983
  • The shear strength of plywoods using Douglus-fir bark powder and particlebard sander dust(PSD), abandoned materials in plywood and particleboard industries, as extender to UF resin, was compared with that of plywoods using wheat flour. Extenders were mixed at the rate of 0%, 5%, 10%, 20%, and 30% of UF resin weight. In obtained results, the dry shear strength of all extended plywoods was highest at extending ratio 5% and the wet shear strength was highest at no extending and 5%. Douglas-fir bark powder-and PSD-extended plywoods had as high dry and wet shear strength as wheat flour-extended plywoods up to extending ratio 10% and 20% respectively. But at 300%, wheat flour-extended plywoods had higher shear strength. Douglas-fir bark powder and PSD size should have been reduced (enough to pass through 325 mesh screen) in order to develop the satisfactory mixing, spreading and plywood bond quality. But in this study the powders to pass through 100 mesh screen were used.

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