• Title/Summary/Keyword: Mixing intensity

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Study of dry etching chrateristics of freeoelectric $YMnO_{3}$ thin films (강유전체 $YMno_{3}$ 박막의 건식식각 특성연구)

  • Kim, In-Pyo;Park, Jae-Hwa;Kim, Kyoung-Tae;Kim, Chang-Il;Jang, Eui-Goo;Eom, Joon-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.159-162
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    • 2002
  • Ferroelectric $YMnO_{3}$ thin films were etched with $Ar/Cl_{2}$ and $CF_{4}/Cl_{2}$ inductivly coupled plasma (ICP). The maximum etch rate of $YMnO_{3}$ thin film was $300{\AA}/min$ at a $Ar/Cl_{2}$ gas mixing ratio of 2/8, a RF power of 800 W, a dc bias of 200 V, a chamber pressure of 15 mTorr, and a substrate temperature of ${30^{\circ}C}$. From the X-ray photoelectron spectroscopy (XPS) analysis , yttrium not only etched by chemical reactions with Cl radicals, but also assisted by Ar ion bombardments in $Ar/Cl_{2}$ plasma. In $CF_{4}/Cl_{2}$ plasma, yttrium are remained on the etched surface of $YMnO_{3}$ and formed of nonvolatile YFx compounds Manganese etched effectively by chemical reactions with Cl and F radicals. From the X-ray diffraction (XRD) analysis, the (0004) diffraction peak intensity of the $YMnO_{3}$ thin film etched in $Ar/Cl_{2}$ plasma shows lower value than that in $CF_{4}/Cl_{2}$ plasma. It is indicates that the crystallinty of $YMnO_{3}$ thin film is more easily damaged by the Ar ion bombardment than the changes of stoichiometry due to nonvolatile etch by-products.

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Numerical investigation of flow characteristics through simple support grids in a 1 × 3 rod bundle

  • Karaman, Umut;Kocar, Cemil;Rau, Adam;Kim, Seungjin
    • Nuclear Engineering and Technology
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    • v.51 no.8
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    • pp.1905-1915
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    • 2019
  • This paper investigated the influence of simple support girds on flow, irrespective of having mixing vanes, in a 1 × 3 array rod bundle by using CFD methodology and the most accurate turbulence model which could reflect the actual physics of the flow was determined. In this context, a CFD model was created simulating the experimental studies on a single-phase flow [1] and the results were compared with the experimental data. In the first part of the study, influence of mesh was examined. Tetra, hybrid and poly type meshes were analyzed and convergence study was carried out on each in order to determine the most appropriate type and density. k - ε Standard and RSM LPS turbulence models were used in this section. In the second part of the study, the most appropriate turbulence model that could reflect the physics of the actual flow was investigated. RANS based turbulence models were examined using the mesh that was determined in the first part. Velocity and turbulence intensity results obtained on the upstream and downstream of the spacer grid at -3dh, +3dh and +40dh locations were compared with the experimental data. In the last section of the study, the behavior of flow through the spacer grid was examined and its prominent aspects were highlighted on the most appropriate turbulence model determined in the second part. Results of the study revealed the importance of mesh type. Hybrid mesh having the largest number of structured elements performed remarkably better than the other two on results. While comparisons of numerical and experimental results showed an overall agreement within all turbulence models, RSM LPS presented better results than the others. Lastly, physical appearance of the flow through spacer grids revealed that springs has more influence on flow than dimples and induces transient flow behaviors. As a result, flow through a simple support grid was examined and the most appropriate turbulence model reflecting the actual physics of the flow was determined.

Reliability Analysis of Steel Fiber Reinforced Concrete Continuous Beams (강섬유 보강 철근콘크리트 연속보의 신뢰성 해석)

  • Yoo Han-Shin;Jang Hwa-Sup;Kwak Kae-Hwan
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.17 no.4
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    • pp.443-449
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    • 2004
  • Methods for mixing variable types of steel fibers have been developed recently to suppress outbreak of crack or to control the width of crack and improve the load resistible capacity at the same time. On the other hand, uncertainty by complex nature of destruction dynamics of steel fiber reinforced concrete(SFRC) is included. In this study, analysis of reliance considering uncertainty of SFRC beam is done. For this, intensity limit state model was proposed. Moreover, characteristic values about almost every kinds of probability variables were collected and presented according to home and foreign references. Process of improving uncertainty from the result of experiments by Bayseian updating method is also proposed on the purpose of offering better statistical characteristic values with more data in the new future. Fatigue fracture probability equation is proposed and needed statistical characteristic values were presented to analyze fatigue reliance

Evaluation of Operation Parameters for the Removal of Algae by Electro-Coagulation (수계 내 조류 제거를 위한 전기응집 운전 특성 평가)

  • Jeong, Kwon;Kim, Do-Gun;Kim, Seog-Ku;Kim, Weon-Jae;Ko, Seok-Oh
    • Journal of Korean Society on Water Environment
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    • v.31 no.2
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    • pp.94-102
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    • 2015
  • Electro-coagulation experiments were conducted with aluminum (Al) or iron (Fe) electrode in order to determine the optimal electrode material and operation conditions for algae removal. Al electrode showed higher removal rate of algae than Fe electrode because Al flocs have positive surface charges which electrostatically attract algae species having negative surface charges. Removal rate of algae and total phosphorous (T-P) was increased as current density and electrode area increases. It was also found that initial pH with neutral range was optimum for T-P removal by electro-coagulation. Bench-scale continuous flow experiments consisted of electro-coagulation reactor, agitation tank and settling tank were conducted. In electro-coagulation reactor, a large fraction of Al flocs were distributed to scum layer, due to the gas bubbles generated by electrolysis reaction. In agitation tank, most of Al flocs were settled and the optimal mixing intensity was found to be 50 rpm to achieve good settleability. The removal rate of algae was about 90-95%. Additionally, the removal rate of the T-P and COD was observed to be $73.8{\pm}8.0%$ and $75.0{\pm}3.8%$, respectively. Meanwhile, the removal rate of total nitrogen (T-N) was relatively low at only 24%.

Effect of Ambient Gases on the Characteristics of ITO Thin Films for OLEDs

  • Lee, Yu-Lim;Lee, Kyu-Mann
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.6
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    • pp.203-207
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    • 2009
  • We have investigated the effect of ambient gases on the structural, electrical, and optical characteristics of ITO thin films intended for use as anode contacts in OLED (organic light emitting diodes) devices. These ITO thin films are deposited by radio frequency (RF) magnetron sputtering under different ambient gases (Ar, Ar+$O_2$, and Ar+$H_2$) at $300{^{\circ}C}$. In order to investigate the influences of the oxygen and hydrogen, the flow rate of oxygen and hydrogen in argon mixing gas has been changed from 0.5 sccm to 5 sccm and from 0.01 sccm to 0.25 sccm, respectively. The intensity of the (400) peak in the ITO thin films increased with increasing $O_2$, flow rate whilst the (400) peak was nearly invisible in an atmosphere of Ar+$H_2$. The electrical resistivity of the ITO thin films increased with increasing $O_2$ flow rate, whereas the electrical resistivity decreased sharply under an Ar+$H_2$ atmosphere and was nearly similar regardless of the $H_2$ flow rate. The change of electrical resistivity with changes in the ambient gas composition was mainly interpreted in terms of the charge carrier mobility rather than the charge carrier concentration. All the films showed an average transmittance of over 80% in the visible range. The OLED device was fabricated with different ITO substrates made with the configuration of ITO/$\alpha$-NPD/DPVB/$Alq_3$/LiF/Al in order to elucidate the performance of the ITO substrate. Current density and luminance of OLED devices with ITO thin films deposited in Ar+$H_2$ ambient gas is the highest among all the ITO thin films.

Electrical Properties of Nanostructured Carbon Black-filled HDPE Composites: Effect of Electron Beam Irradiation on PTC Characteristics (나노구조 카본블랙/HDPE 복합재료의 전기적 특성: 전자선 조사에 의한 PTC 특성변화)

  • 박수진;송수완;서민강;이재락
    • Composites Research
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    • v.16 no.1
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    • pp.19-25
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    • 2003
  • In this paper, electrical properties of nanostructured carbon blacks (CB)-filled high density polyethylene (HDPE) composites were investigated as a function of temperature, which were prepared by the conventional melt-mixing method. The composites were irradiated with electron beam in a dosage of 30∼150 kGy to enhance an electronical reproducibility and to reduce a negative temperature coefficient (NTC) phenomenon. And, gel contents (%) of irradiated CB/HDPE composites were estimated by solvent extraction method. From the experimental results. the positive temperature coefficient (PTC) intensity of the composites was strongly depended on the CB content and particle size. And, the increase of gel contents (%) and disappearance of NTC behavior of the composites were identified at a dosage of 60 kGy. It was also found that the electron beam irradiation made an improvement of electrical reproducibility of the composites. This result was probably due to the reduction of the freedom of CB movement at above the melting temperature of the polymer crystalline, resulting in increasing the crosslinking structure of the composites.

Development of Hybrid/Dual Swirl Jet Combustor for a MGT (Part II: Numerical Study on Isothermal Flow) (마이크로 가스터빈용 하이브리드/이중 선회제트 연소기 개발 (Part II: 비반응 유동에 관한 수치해석))

  • Mun, Sun-Yeo;Hwang, Cheol-Hong;Lee, Kee-Man
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.5
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    • pp.70-79
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    • 2013
  • The isothermal flow structure and mixing characteristics of a hybrid/dual swirl jet combustor for micro-gas turbine (MGT) were numerically investigated. Location of pilot burner, swirl angle and direction were varied as main parameters with the identical thermal load. As a result, the variations in location of pilot nozzle, swirl angle and direction resulted in the significant change in turbulent flow field near burner exit, in particular, center toroidal recirculation zone (CTRZ) as well as turbulent intensity, and thus the flame stability and emission performance might be significantly changed. With the comparison of experimental results, the case of swirl angle $45^{\circ}$ and co-swirl flow including optimum location of pilot burner were chosen in terms of the flame stability and emissions for the development of hybrid/dual swirl jet combustor.

Effects of Combustion Instability by Swirl Intensity in Hybrid Rocket (스월 강도에 따른 하이브리드 로켓의 연소 불안정 영향)

  • Kim, Jungeun;Lee, Sulha;Kim, Ji Eun;Kim, Ji Hye;Yoo, Min Jeong;Han, Songee;Lee, Changjin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.672-674
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    • 2017
  • The addition of swirl is a common technique used in premixed combustors in order to gain stability of the combustion with the improvements in mixing characteristics. recent experimental studies have observed that the addition of swirl oxidizer flow can effectively reduce the combustion instability in hybrid rocket. Investigation was continued to analyze the effect of the swirl on the internal flow of hybrid rocket engine main combustion chamber. The flow influenced by wall blowing as a representation of fuel evaporation interacts with swirling flow. Swirl angle increases, the amplitude of the combustion pressure decrease as the unstable combustion processes. These results suggest that the oxidizer swirling flow by the swirl angle causes the change of the turbulent flow characteristics inside the combustion chamber and suppresses the factors causing the combustion instability.

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Synthesis and Characterization of CoAl2O4 Inorganic Pigment Nanoparticles by a Reverse Micelle Processing (역-마이셀 공정에 의한 CoAl2O4 무기안료 나노 분말의 합성 및 특성)

  • Son, Jeong-Hun;Bae, Dong-Sik
    • Korean Journal of Materials Research
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    • v.24 no.7
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    • pp.370-374
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    • 2014
  • Inorganic pigments have high thermal stability and chemical resistance at high temperature. For these reasons, they are used in clay, paints, plastic, polymers, colored glass and ceramics. $CoAl_2O_4$ nano-powder was synthesized by reverse-micelle processing the mixed precursor(consisting of $Co(NO_3)_2$ and $Al(NO_3)_3$). The $CoAl_2O_4$ was prepared by mixing an aqueous solution at a Co:Al molar ratio of 1:2. The average particle size, and the particle-size distribution, of the powders synthesized by heat treatment (at 900; 1,000; 1,100; and $1,200^{\circ}C$ for 2h) were in the range of 10-20 nm and narrow, respectively. The average size of the synthesized nano-particles increased with increasing water-to-surfactant molar ratio. The synthesized $CoAl_2O_4$ powders were characterized by X-ray diffraction analysis(XRD), field-emission scanning electron microscopy(FE-SEM) and color spectrophotometry. The intensity of X-ray diffraction of the synthesized $CoAl_2O_4$ powder, increased with increasing heating temperature. As the heating temperature increased, crystal-size of the synthesized powder particles increased. As the R-value(water/surfactant) and heating temperature increased, the color of the inorganic pigments changed from dark blue-green to cerulean blue.

Reflection on Kinetic Models to the Chlorine Disinfection for Drinking Water Production

  • Lee, Yoon-Jin;Nam, Sang-ho
    • Journal of Microbiology
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    • v.40 no.2
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    • pp.119-124
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    • 2002
  • Experiments for the characterization of inactivation were performed in a series of batch processes with the total coliform used as a general indicator organism based on the chlorine residuals as a disinfectant. The water samples were taken from the outlet of a settling basin in a conventional surface water treat- ment system that is provided with the raw water drawn from the mid-stream of the Han River, The inactivation of total coliform was experimentally analysed for the dose of disinfectants contact time, filtration and mixing intensity. The curves obtained from a series of batch processes were shaped with a general tailing-off and biphasic mode of inactivation, i.e. a sharp loss of bacterial viability within 15 min followed by an extended phase. In order to observe the effect of carry-over suspended solids on chlorine consumption and disinfection efficiency, the water samples were filtered, prior to inoculation with coliforms, with membranes of both 2.5$\mu$m and 11.0 $\mu$m pore size, and with a sand tilter of 1.0 mm in effective size and of 1.4 in uniformity coefficient. As far as the disinfection efficiency is concerned, there were no significant differences. The parameters estimated by the models of Chick-Wat-son, Hom and Selleck from our experimental data obtained within 120 min are: log(N/N$\_$0/)=-0.16CT with n=1, leg(N/N$\_$0/)=-0.71C$\^$0.87/ with n 1 for the Chick-Watson model, log (N/N$\_$0/)=-1.87C$\^$0.47/ T$\^$0.36/ for the Hom model, log (MHo)=-2.13log (1+CT/0.11) for the Selleck model. It is notable that among the models reviewed with regard to the experimental data obtained, the Selleck model appeared to most closely resemble the total coliform survival curve.