• Title/Summary/Keyword: Mixed gas

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Fabrication and Characterization of Porous Non-Woven Carbon Based Highly Sensitive Gas Sensors Derived by Magnesium Oxide

  • Kim, Yesol;Cho, Seho;Lee, Sungho;Lee, Young-Seak
    • Carbon letters
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    • v.13 no.4
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    • pp.254-259
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    • 2012
  • Nanoporous non-woven carbon fibers for a gas sensor were prepared from a pitch/polyacrylonitrile (PAN) mixed solution through an electrospinning process and their gas-sensing properties were investigated. In order to create nanoscale pores, magnesium oxide (MgO) powders were added as a pore-forming agent during the mixing of these carbon precursors. The prepared nanoporous carbon fibers derived from the MgO pore-forming agent were characterized by scanning electron microscopy (SEM), $N_2$-adsorption isotherms, and a gas-sensing analysis. The SEM images showed that the MgO powders affected the viscosity of the pitch/PAN solution, which led to the production of beaded fibers. The specific surface area of carbon fibers increased from 2.0 to $763.2m^2/g$ when using this method. The template method therefore improved the porous structure, which allows for more efficient gas adsorption. The sensing ability and the response time for the NO gas adsorption were improved by the increased surface area and micropore fraction. In conclusion, the carbon fibers with high micropore fractions created through the use of MgO as a pore-forming agent exhibited improved NO gas sensitivity.

A Study on the Generating feature of Hydrogen Oxygen Gas Using Current Controlled Pulse Power Supply (전류제어형 펄스전원장치를 이용한 수산화 가스 발생 특성 연구)

  • Yang S. H.;Kang B. H.;Jun Y. S.;Mok H. S.;Choe G. H.
    • Proceedings of the KIPE Conference
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    • 2002.07a
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    • pp.257-262
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    • 2002
  • Water-Electrolyzed gas is a mixed gas has the constant volume ratio 2 1 Hydrogen and Oxygen gained from electrolyzed water, and it has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for existing gas welding equipment. So nowdays many studies of Water-Electrolyzed gas are progressed, and commercially used as a source of thermal energy for gas welding in the industry. For Water-Electrolyzed Source, it was used diode rectifier or SCR rectifier for get DC source. This method which is not looking to improve a source for impossible current control or voltage and limited control intervals. In this paper, it was relized and designed In source of pulse type for complementing existing - DC source type, also by experiment it was acquired producting characteristics of Hydrogen -Oxygen Gas through feature of source

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High Current MIG Welding of Al 5083 Alloy under Ar/He Mixed Gas Shielding (Ar/He 보호가스분위기에서 Al 5083 합금의 대전류 MIG 용접특성)

  • Choi, Young-Bae;Hwang, In-Sung;Kang, Mun-Jin;Kim, Dong-Cheol
    • Journal of Welding and Joining
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    • v.32 no.1
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    • pp.87-92
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    • 2014
  • Recently, use of thick Al 5083 plate has increased in production of LNG storage tank. In general, multi-pass welding has been used to achieve sufficient penetration in thick plate welding. High current welding which enables high deposition and deep penetration is preferred in thick plate welding because the increase of number of pass increases manufacturing cost and formation of weld defect. In this study, welding characteristics according to various Ar/He shielding gas composition was investigated in high current MIG welding. The bead-on-plate welding and V groove welding were conducted on Al 5083 alloy with a thickness of .25 mm. The effect of shielding gas composition on bead shape was evaluated and proper shielding gas composition was proposed. Also arc stability was examined under selected shielding gas composition. One side-one pass welding experiments were conducted for V groove specimen with a thickness of 25 mm. Mechanical properties and hardness profiles were measured for the V groove specimens.

Removal of Nitrogenous Compounds by Immobilized Mixed Microorganisms Including Photosynthetic Bacteria (광합성 세균을 포함한 고정화 복합미생물에 의한 질소성분 제거)

  • Cho, Kyoung Sook;Kim, Jeong Bo;Jeong, Soo Kyoung;Jeong, Hae Yoon;Cho, Jeong Sub;Kim, Joong Kyun
    • Journal of Marine Bioscience and Biotechnology
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    • v.1 no.2
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    • pp.91-97
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    • 2006
  • For efficient removal of nitrogenous compounds produced in recirculating aquaculture system, the N removal characteristics of immobilized mixed microorganisms were investigated at various mixing ratios of photosynthetic bacteria (PSB) immobilized in PVA beads or CTA cubes and ammonium utilizing bacteria (AUB) immobilized in PVA beads. On the optimal medium of AUB, the maxium gas production rate was obtained at the mixing ratio of 10:40 (PSB:AUB), and the gas production rate increased as the portion of AUB beads in the mixed beads increased. When the mixing ratios of PSB:AUB beads were 50:0, 40:10, 25:25 and 10:40, the final pHs were measured to be 6.29, 6.01, 5.69 and 5.13, respectively. On the optimal medium of PSB, however, the volume and the rate of gas production decreased remarkably as the portion of AUB beads in the mixed beads increased. The final pH was measured to be approximately 6.5, regardless of the mixing ratio. In the reactions by the mixed culture of PSB cubes and AUB beads, all results showed the same tendency of those by the mixed culture of PSB and AUB beads, but the volume and the rate of gas production decreased remarkably, even with 0.2ml of gas production in control. From all the results, the use of mixed PSB and AUB beads at the ratio of 10:40 seems to be efficient to remove nitrogenous compounds in wastewater from recirculating aquaculture system.

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Comparative analysis of two methods of laser induced boron isotopes separation

  • K.A., Lyakhov;Lee, H.J.
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.407-408
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    • 2011
  • Natural boron consists of two stable isotopes 10B and 11B with natural abundance of 18.8 atom percent of 10B and 81.2 atom percent of 11B. The thermal neutron absorption cross-section for 10B and 11B are 3837 barn and 0.005 barn respectively. 10B enriched specific compounds are used for control rods and as a reactor coolant additives. In this work 2 methods for boron enrichment were analysed: 1) Gas irradiation in static conditions. Dissociation occurs due to multiphoton absorption by specific isotopes in appropriately tuned laser field. IR shifted laser pulses are usually used in combination with increasing the laser intensity also improves selectivity up to some degree. In order to prevent recombination of dissociated molecules BCl3 is mixed with H2S 2) SILARC method. Advantages of this method: a) Gas cooling is helpful to split and shrink boron isotopes absorption bands. In order to achieve better selectivity BCl3 gas has to be substantially rarefied (~0.01%-5%) in mixture with carrier gas. b) Laser intensity is lower than in the first method. Some preliminary calculations of dissociation and recombination with carrier gas molecules energetics for both methods will be demonstrated Boron separation in SILARC method can be represented as multistage process: 1) Mixture of BCl3 with carrier gas is putted in reservoir 2) Gas overcooling due to expansion through Laval nozzle 3) IR multiphoton absorption by gas irradiated by specifically tuned laser field with subsequent gradual gas condensation in outlet chamber It is planned to develop software which includes these stages. This software will rely on the following available software based on quantum molecular dynamics in external quantized field: 1) WavePacket: Each particle is treated semiclassicaly based on Wigner transform method 2) Turbomole: It is based on local density methods like density of functional methods (DFT) and its improvement- coupled clusters approach (CC) to take into account quantum correlation. These models will be used to extract information concerning kinetic coefficients, and their dependence on applied external field. Information on radiative corrections to equation of state induced by laser field which take into account possible phase transition (or crossover?) can be also revealed. This mixed phase equation of state with quantum corrections will be further used in hydrodynamical simulations. Moreover results of these hydrodynamical simulations can be compared with results of CFD calculations. The first reasonable question to ask before starting the CFD simulations is whether turbulent effects are significant or not, and how to model turbulence? The questions of laser beam parameters and outlet chamber geometry which are most optimal to make all gas volume irradiated is also discussed. Relationship between enrichment factor and stagnation pressure and temperature based on experimental data is also reported.

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High Concentration Ozone Generation Characteristics by Variation of Additional Gases and Flow Rates of Inlet Gas (입력가스의 유량변화와 첨가가스에 따른 고농도 오존발생특성)

  • 박승록;이대희
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.16 no.6
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    • pp.95-101
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    • 2002
  • There are many effective parameters to high concentration ozone generation. These parameters became very important elements should be considered before designing ozone generator. After designing, there are many peripheral parameters to greatly affect to high concentration ozone generation also. In this study, of many effective peripheral parameters on high concentration ozone generation, the effects of flow rate of inlet oxygen gas and some kinds of additional gases on ozone concentration were investigated As a result, when inlet oxygen gas was introduced at the range of 0.75[LPM]~2.00[LPM] the highest ozone concentration of 71145[ppm] was obtained at 1.25[LPM]. When the additional nitrogen gas was mixed to oxygen gas at the range of 0.0[vol%]~6.4[vol%] the highest ozone concentration of 73135[ppm] was obtained at 0.8[vol%] of nitrogen gas. This showed 3[%] increasing compared to the case of pure oxygen gas inlet. When the additional argon gas was mixed to oxygen gas at the range of 0.0[vol%]~6.4[vol%] the highest concentration of 67288[ppm]was obtained at 0.8[vol%]of argon gas. This is decreased value compared to that of introducing the pure oxygen.

A Study on Evaporative Characteristics of Multi-component Mixed Fuels Using Mie Scattered Light and Shadowgraph Images (Mie 산란광법 및 Shadowgraph법을 이용한 다성분 혼합연료의 증발특성연구)

  • Yoon, Jun-Kyu;Myong, Kwang-Jae;Jiro Senda;Fujimoto Hajime;Cha, Kyung-Ok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.7 s.250
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    • pp.682-691
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    • 2006
  • This study was conducted to assess the effect of mixed fuel composition and mass fraction on spray inner structure in evaporating transient spray under the various ambient conditions. Spray structure and spatial distribution of liquid phase concentration are investigated using a thin laser sheet illumination technique on the multi-component mixed fuels. A pulsed Ar+ laser was used as a light source. The experiments were conducted in a constant volume vessel with optical access. Fuel was injected into the vessel with electronically controlled common rail injector. Used fuel contain $i-octane(C_8H_{18}),\;n-dodecane(C_{12}H_{26})$ and $n-hexadecane(C_{16}H_{34})$ that are selected as low-, middle- and high-boiling point fuel, respectively. Experimental conditions are 25Mpa, 42MPa, 72MPa and 112MPa in injection pressure, $5kg/m^3,\;15kg/m^3\;and\;20kg/m^3$ in ambient gas density, 400K, 500K, 600K and 700K in ambient gas temperature, 300K and 368K in fuel temperature, and different fuel mass fraction. Experimental results indicate that the more high-boiling point component, the longer the liquid phase it were closely related to fuel physical properties, but injection pressure had no effect on. And there was a high correlation between the liquid phase length and boiling temperature at 75% distillation point.

The Effect of Deoxidizers in a Wire on Spatter Generation in Gas Metal Arc Welding (GMA용접에 있어서 스패터 발생에 미치는 와이어 탈산원소의 영향)

  • 방국수;안영호
    • Journal of Welding and Joining
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    • v.14 no.5
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    • pp.145-150
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    • 1996
  • The variation of spatter generation in gas metal arc welding with welding conditions and wire compositions was investigated and interpreted in terms of arc stability. The transition range from a short circuit mode to a spray mode in the mixed gas welding showed an unstable arc and generated the largest amount of spatters. Titanium reduced spatters only in the globular mode of $CO_2$welding and silicon and manganese showed the same effect The effect of silicon and manganese, however, was no longer seen when titanium was added simultaneously to the wire. It is believed that deoxidizers easily form oxides on the anode and make the arc stable even in DCRP welding. The wires with deoxidizers also showed low short circuit frequency, resulting in the increase of large size spatters.

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A Study on Color Control in Gas Discharge Tube with the Variation of Frequency (주파수 변화에 따라 기체 방전관 색상 제어에 관한 연구)

  • Lee, Jong-Chan;Park, Dae-Hee
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 1996.11a
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    • pp.53-56
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    • 1996
  • In this paper, the pulsed mode operated gas discharge tube is composed with mixed gas of Hg-Ne (10 Torr), in the tube of 15.0 mm outer diameter and has variable color from red to blue with changing frequency high voltage. As increasing frequency in the gas discharge tube, the phenomena, that the electron temperature in the positive column increases and the radiation from atoms of higher upper state energy levels increases, exist The color have the locus from red (0.4972, 0.3128) to blue (0.2736, 0.2619) in CIE chromacity diagram with increasing frequency. The method of changing frequency has been shown to be suitable for the luminous color control.

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An Effect of $O_2/Ar$ Ratio on the Characteristics of RF Magnetron Sputtered $BaTiO_3$ Thin Film (RF Magnetron Sputtering법으로 $BaTiO_3$ 박막 증착시 $O_2/Ar$비가 박막의 특성에 미치는 영향)

  • 안재민;최덕균;김영호
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.886-892
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    • 1994
  • Structural and electrical properties of BaTiO3 thin films deposited on Pt/SiO2/Si substrates by RF magnetron sputtering method have been investigated. Crystallization behavior and electrical properties were studied for the films deposited under various sputtering gas compositions (Ar+O2 gas mixture) and substrate temperatures. All the films deposited above 50$0^{\circ}C$ were all crystallized and their preferred orientation changed from (001) to (111) with the addition of oxygen gas. The dielectric constant of films deposited in pure argon was about 110 and showed little dependence on the substrate temperature. But that was increased as the ratio of O2/Ar increased and its substrate temperature dependence was discernible. The highest dielectric constant reached to 550. In addition, the films deposited in mixed gas showed stable dielectric properties against the frequency and temperature.

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