• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.181-185
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• 2008

The new concept for liquefaction of natural gas has been designed and simulated in this paper. Conventional liquefaction cycles are usually composed with Joule-Thomson valves at lower temperature refrigerant cycle. The new concept of natural gas liquefaction is discussed. The main difference with conventional liquefaction process is the presence of the turbine at low temperature of MR (mixed refrigerant) cycle. The turbine acts as expander but also as an energy generator. This generated energy is provided to the compressor which consumes energy to pressurize refrigerants. The composition of the mixed refrigerant is investigated in this study. Components of the refrigerant are methane, propane and nitrogen. Composition for new process is traced with Aspen HYSYS software. LNG heat exchangers are analyzed for the new process. Heating and cooling curves in heat exchangers were also analyzed.

• Journal of the Semiconductor & Display Technology
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• v.21 no.2
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• pp.144-149
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• 2022

A cryogenic Mixed Refrigerant Joule-Thomson refrigeration cycle was designed to be applied to the semiconductor etching process with non-flammable constituents. 3-stage cascade refrigerator, single mixed refrigerant Joule-Thomson refrigerator, and 2-stage cascade type mixed refrigerant Joule-Thomson refrigerator are analyzed to figure out the coefficient of performance. Non-flammable mixture of argon(Ar), tetrafluoromethane(R14), trifluoromethane (R23) and octafluoropropane(R218) were utilized to analyze the refrigeration cycle efficiency. The designed refrigeration cycle was adapted to cool down the coolant of HFE7200(Ethoxy-nonafluorobutane, C₄F₉OC₂H₅) with certain constraints. Maximum coefficient of performance of the refrigeration system is obtained as 0.289 for the cooling temperature lower than -100℃. The detailed result of the coefficient of performance according to the mixture composition is discussed in this study.

• Journal of the Society of Naval Architects of Korea
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• v.49 no.1
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• pp.33-44
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• 2012

In this study, the optimal operating conditions for the dual mixed refrigerant(DMR) cycle were determined by considering the power efficiency. The DMR cycle consists of compressors, heat exchangers, seawater coolers, valves, phase separators, tees, and common headers, and the operating conditions include the equipment's flow rate, pressure, temperature, and refrigerant composition per flow. First, a mathematical model of the DMR cycle was formulated in this study by referring to the results of a past study that formulated a mathematical model of the single mixed refrigerant(SMR) cycle, which consists of compressors, heat exchangers, seawater coolers, and valves, and by considering as well the tees, phase separators, and common headers. Finally, in this study, the optimal operating conditions from the formulated mathematical model was obtained using a hybrid optimization method that consists of the genetic algorithm(GA) and sequential quadratic programming(SQP). Moreover, the required power at the obtained conditions was decreased by 1.4% compared with the corresponding value from the past relevant study of Venkatarathnam.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.16 no.3
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• pp.305-314
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• 1987

Thermodynamic analysis of a mixed refrigerant refrigeration cycle has been performed by computing thermodynamic properties of various refrigerants. The analyses are carried cut to identify the sources and distribution of the energy degradation by irreversible processes. Heat exchange process with the surroundings produces the entropy and the irreversible loss can be reduced by the mixed refrigerant whose phase change temperature varies during the phase change processes in the evaporator and the condenser. The concept has been applied to find the minimum compression work and thus the minimum energy loss in the overall system, specifically in the case of the mixed refrigerant of R12 and R114. Parametric studies have been added to recognize the various factors affecting the system performance.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.4
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• pp.502-507
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• 2014

In this paper, performance characteristics of cycles were studied when mixed working fluid was used for ocean thermal energy conversion (OTEC). Among the various mixed refrigerants for industrial heat-pump, R32/R152a used in ocean thermal energy conversion system. For simulations, R32/R152a were used in existing closed cycle and Kalina cycle which is used only ammonia and water as mixed refrigerant. Temperature of the warm heat source was 26 and 29 celsius degree, temperature of the cold heat source was 5 celsius degree. In results of simulation, Gross power of the closed cycle on R32 was 22kW, and efficiency of the cycle was 2.02%. When the mixed refrigerant of R32/R152a, in the ratio of 90 to 10, gross power of the closed cycle was 29.93kW, and efficiency of the cycle was 2.78%. Gross power and cycle efficiency of R32/R152a increased by 36% and 37% than those of existing single refrigerant. Additionally, the same simulations were conducted in Kalina cycle with the same various composition ratio of mixed refrigerant.

• Journal of the Korean Institute of Gas
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• v.15 no.6
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• pp.38-43
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• 2011

Natural gas liquefaction process runs under cryogenic condition, and it spends large amount of energy. Minimizing energy consumption of natural gas liquefaction process is an important issue because of its physical characteristics. Among many kinds of natural gas liquefaction processes, C3-MR(Propane Pre-cooled Mixed Refrigerant) process uses two kind of refrigerants. One is the propane as the pure refrigerant(PR) and the other is the mixed refrigerant(MR). In this study, to find the optimal compressing level, propane cycle is simulated on different pressure level. The case study result shows relationship between energy consumption and pressure level. As a result, the conclusion is that at a higher pressure level, process consumes lower energy. At 5 pressure-levels, energy consumption is 23.7% lower than 3 pressure-levels.

• Journal of the Semiconductor & Display Technology
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• v.23 no.2
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• pp.6-11
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• 2024

This paper presents the design and experimental analysis of a cryogenic refrigeration system for -100 ℃, primarily intended for semiconductor etching process. The refrigeration system utilizes non-flammable mixed refrigerant Joule-Thomson refrigeration cycle, incorporating a precooling stage to enhance overall performance. The selected refrigerants for the system include R1234yf for the precooling stage, and Ar, R14, R23 and R218 for the main cooling stage of the Joule-Thomson refrigeration cycle. Design results according to the system constraints and experimental results are discussed, including lowest evaporation temperature, compressor isentropic efficiency and overall pressure tendencies. The achieved refrigerant fraction from optimal design is Ar: R14: R23: R218 = 0.15: 0.4: 0.15: 0.3, indicating COP of 0.1118 at the isentropic compressor efficiency of 50%. The experimental result shows the developed system reaches steady state in approximately 3 hours.

• Journal of the Korean Institute of Gas
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• v.17 no.3
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• pp.27-32
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• 2013

Natural gas liquefaction process which is operated under cryogenic condition spends large amount of energy. Most of energy in the natural gas liquefaction process is consumed by compressors. Therefore, minimizing energy consumption of compressors is an important issue in process design and operation. Among various natural gas liquefaction processes, propane pre-cooled mixed refrigerant (C3MR) process consists of mixed refrigerant system and pure refrigerant system. In this study, to find the optimal design of pure refrigerant system, pure refrigerant cycle is simulated on different number of pressure levels and the necessary energy of each design is compared. After that, the driver selection model is applied to analyse each processes, which has different number of equipments, in terms of cost. As the result, the design using many equipments spends lower energy. Using this result, this study suggests standard of process design selection by the cost term.

• Korean Chemical Engineering Research
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• v.51 no.6
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• pp.677-684
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• 2013

A mixed refrigerant cycle (MRC) has been widely used in liquefaction of natural gas because it is simple and easily operable with reasonable equipment costs. One of the important techniques in MRC is selection of a refrigerant mixture and decision of its optimum mixing ratio. In this work, it is examined whether mixture components (refrigerants) and their mixing ratio influence performance of general MRC processes. In doing this, mixture design and response surface method, which are well-known statistical techniques, are used to find optimal mixture refrigerants and their optimal mixing ratio that minimize total energy consumption of the entire liquefaction process. A MRC process using several refrigerants and various mixing ratios is simulated by Aspen HYSYS and mixture design and response surface method are implemented using Minitab. According to the results, methane ($C_1$), ethane ($C_2$), propane ($C_3$) and nitrogen ($N_2$) are selected as best mixture refrigerants and the determined mixture ratio (mole ration) can reduce total energy consumption by up to 50%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.12 no.10
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• pp.901-907
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• 2000

The conceptual determination of mixed-refrigerant (MR) for a closed Joule-Thomson cryocooler is described in this paper. The thermodynamic cycle design was mainly considered to develop a cryocooler by using a compressor of domestic air-conditioning unit. The target cooling performance of the designed cryocooler is 10 W around 70 K with less than 5 kJ/kg enthalpy rise. The systematic approach of choosing a proper refrigerant among 20 different kinds of mixture for such cryogenic temperature was introduced in detail. The main components of the cryocooler are compressor, evaporator, oil separator, after-cooler, counterflow heat exchanger, and J-T expansion device. Due to the limitation of the compressor operation range, the temperature after the compression was limited below $117^{\circ}C$ (390 K) and the temperature before compression was restricted above $5^{\circ}C$ (278 K). 20 atm of discharging pressure (high pressure) and less than 3 atm suction pressure (low pressure) were the design conditions. The inlet temperature of a counterflow heat exchanger in the high Pressure side was about 300 K. The proper composition of the mixed refrigerant for the designed J-T cryocooler is 15% mol of$ N_2, 30% mol of $CH_4,\; 30% mol\; of C^2H^ 6,\; 10%\; mol\; of\; C_3H_8\; and \;15%\; mol\; of\; i-C_4H_10$.