• Title/Summary/Keyword: Mixed Particle

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양이온 물질로 오염된 지하수 정화를 위한 반응벽체 개발 : 제올라이트의 적용성 평가

  • 이승학;이재원;김시현;박준범;박상권
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.09a
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    • pp.23-26
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    • 2001
  • Batch test and column test were performed to develop the design factors for PRBs against the contaminated groundwater by ammonium and lead. Clinoptilolite, one of the natural zeolites having excellent cation exchange capacity(CEC), was chosen as the reactive material through the ion-exchange mechanism. In the batch test, the reactivity of Clinoptilolite to ammonium and lead was examined with varying the particle size of Clinoptilolite. The nit weight of Clinoptilolite showed removal efficiencies of 65 % against the ammonium and 98% against lead. The effect of particle size of Clinoptilolite was not noticeable. In the column test, the permeability was examined using flexible-wall permeameters with varying the particle size of Clinoptilolite. When the washed Clinoptilolite having the diameter of 0.42-0.85 nm was mixed with Jumunjin sands in 20:80 ratio (w/w), the highest permeability of 2$\times$10$^{-3}$ -7 x 10$^{-4}$ cm/s was achieved. The reactivity and the strength property of the mixed material were investigated using fixed wall column having 8 sampling ports on the wall and the direct shear test, respectively. Clinoptilolite was found to be a suitable material for PRBs against the contaminated groundwater with ammonium and/or heavy metals.

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Preparation of Submicron Barium Titanate Powders. (초미립 $BaTiO_3$의 합성)

  • 안영필;김복희;황재석;유경섭
    • Journal of the Korean Ceramic Society
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    • v.21 no.3
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    • pp.278-282
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    • 1984
  • Barium titanate powder was made by firing the complex hydroxide which had been synthesized with chemical wet process by the medium of $H_2O_2$. This experiment was done as following A mixed solution of $BaCl_2$, $TiCl_4$ and $H_2O_2$ with 1:1:10 mol ratio was prepared. Ammonium hydroxide was added into the mixed solution. In the range of pH 8-10 $BaTiO_3$ complex hydroxide was obtained and treated at room temperature 11$0^{\circ}C$, 20$0^{\circ}C$, 40$0^{\circ}C$ and $600^{\circ}C$. The results obtaiined from this experiment were as follows. At room temperature $BaTiO_3$ complex hydroxide was amorphous. Above 10$0^{\circ}C$ crystalline $BaTiO_3$ was obtained and particle size of $BaTiO_3$ was increased with elevated temperature. So the particle size of BaTiO3 could be controlled by the firing temperature. After treating $BaTiO_3$ complex hydroxide at 10$0^{\circ}C$ the average particle size of $BaTiO_3$ was 0.22$\mu\textrm{m}$.

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The Development of Slag Based Materials for the Reformation of Soft Ground

  • Byeon, Tae-Bong;Kim, Hyung-Suek;Han, Ki-Hyun
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.537-541
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    • 2001
  • For the development of reformation material of soft ground using the LD slag, the relation to the particle condition of LD slag and the pH behavior of slag dissolution water, extraction properties of slag, and origination of white water were investigated. When the LD slag is mixed with sea water, the pH of solution ranged between 9.47 and 10.0. On the other hand, when mixed with distilled water, the pH was about 10.4 to 12.1. For the as-received slag and the aged slag in sea water, a pH of 11.5 to 12.0 was observed when the particle size was less than 0.5mm. For the reoxidized slag in seawater, the pH of the solution was lower than 9.5 when the particle size was bigger than 0.075mm. For the aged slag and reoxidized slag, the pH of the solution remained constant when the addition ratio of sea water to the slag was higher than 500 times. The main elements dissolved from the slag were Ca and Mg ions. When the pH went over 9.0, the white water started to font which was caused by the CaCO$_3$and Mg(OH)$_2$.

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Rheological Properties and Particle Size Distribution of Northeast Mixed Hardwood for Enzymatic Saccharification Processing with High Substrates Loading

  • Um, Byung-Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.5
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    • pp.56-65
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    • 2008
  • In this paper experimental results are presented for the rheological behavior of high-solids saccharification of mixed northeast hardwood as a model feedstock. The experimental determination of the viscosity, shear stress, and shear rate relationships of the 10 to 20 percent slurry concentrations with constant enzyme concentrations were performed under variable rotational speed of a viscometer (2.0 to 200 RPM) at combined temperatures (50 to $30^{\circ}C$) for the initial four hours. The viscosities of saccharification slurries observed were in the ranges of 0.024 to 0.028, 0.401 to 0.058, and 0.840 to 0.087 Pa s for shear rates up to 100 reciprocal seconds at 10, 15, and 20 percent initial solids (w/v) respectively. The fluid behavior of the suspensions was modeled using the power-law, the Herschel-Bulkley, the Casson, and the Bingham model. The results showed that broth slurries were pseudoplastic with a yield stress. The model slope increased and the model intercept decreased with increasing fermentation time at shear rates normal for the fermentor. The broth slurries exhibited Newtonian behavior at high and low shear rates during initial saccharification process. The solid particle size ranged from 57.8 to $70.0{\mu}m$ for $40^{\circ}C$ and from 44.0 to 57.5 11m for combined temperatures at 10, 15, and 20 percent initial solids (w/v) respectively.

Investigation on Properties of Concrete with Crushed Sand on Site (부순모래를 사용한 콘크리트의 현장 품질 특성에 관한 실험 연구)

  • Lee, Sung-Bok;Lee, Do-Heon;Jee, Nam-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.3 no.3
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    • pp.107-112
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    • 2003
  • This study is to investigate the properties of concrete with crushed sand on site and to propose a quality guideline for its use as artificial sand and concrete. From our experimental result in laboratory and site, we found that demand water of concrete with crushed sand for target slump increased by 18kg/m3 compared to mixed sand and l8kg/m3 compared to sea sand respectively. The compressive strength increased by around 3∼6% when compared to concrete with sea sand. Accordingly, our study showed that the combined sand mixed with sea sand would be desirable to obtain workability and strength of concrete including dry shrinkage and bleeding test. Furthermore, the optimal replacement percentage of crushed sand was 50% with sea sand. As such, crushed sand would be sufficient as fine aggregate for concrete in terms of economic efficiency and quality. Crushed sand, on the other hand can only be used as fine aggregate when VFS(Very Fine Sand) is below 3.5 percentage of weight of sand and particle shape is above 55 percentage. Also, the particle shape and microsand passing NO.200 sieve should continually be improved to increase workability of concrete on site.

Microstructure Characteristics of Conductive Cement Mortar with Deterioration Damage (열화손상이 발생된 전도성시멘트모르타르의 미세구조 특성)

  • Kim, Young-Min;Lee, Gun Cheol;Yun, Hyun Do;Kwon, Hyun Woo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.05a
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    • pp.195-196
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    • 2021
  • The pore distribution of the cement mortar mixed with carbon nanotubes was found to have a large number of pores at (370~80)㎛, and the distribution ratio was larger as the carbon nanotubes were mixed. However, the pores with a fine particle diameter of (10-0.5) ㎛ were found to be larger as the carbon nanotubes were incorporated. However, the distribution of pores of the test specimens of conductive cement mortar with deterioration damage was found to be distributed in a number of particle diameters of (500 to 100) ㎛ and (10 to 0.5) ㎛. It is judged that the particle diameter of the internal pores increased due to the damage. However, as the mixing ratio of the test specimen with carbon nanotubes increased, the distribution of voids was relatively lower than that of plain, and it was judged to have excellent resistance to deterioration damage.

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Influence of Domestic Aggregates Quality on Concrete Properties (지역별 골재 품질변화가 콘크리트 물성에 미치는 영향)

  • 노재호;조일호;이선우;정재동
    • Proceedings of the Korea Concrete Institute Conference
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    • 1993.04a
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    • pp.34-39
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    • 1993
  • Recently inappropriate aggregates are used as a raw material for ready-mixed concretes, due to the shortage of natural aggregate resources and the prohibition of their extraction for the environmental protection. We, therefore, have conducted experiments to obtain some knowledge of properties of domestic aggregates and to investigate subsequent changes in the properties of the fresh and hardened concretes. To this end, aggregates currently used in 13 domestic ready-mixed concrete plants were collected. Most of aggregate used in this experiment satisfied the KS in density and unit weight. But some of the aggregates have the particle size distribution that can effect bad influence on concrete. In this experiment the aggregates are found to have a bad particle size distribution, resulting in high amount of a unit water content and a unit cement content in concrete.

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A Study on Behavior of Heavy Metals during Waste Incineration (폐기물 소각시 중금속 성분의 거동에 관한 연구)

  • 박용이;허철구
    • Journal of Environmental Science International
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    • v.5 no.6
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    • pp.785-799
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    • 1996
  • The incineration tests of mixed industrial wastes using the stoker type incinerator are carried out to investigate the partitioning characteristics of heavy metals during incineration. The results obtained from this study are as follow. The partitioning characteristics of heavy metals throughout this incinerator are found that, at given condition of $700^{\circ}C$, the elements with the relatively high boiling point such as Cr, Cu and Pb are partitioned into a bottom ash, a fry ash captured tv cyclone, and a flue gas stream, 67~88%, 2~19% and 6~16% of initial amount entering the incinerator, respectively, but the Cd and Hg of 75~81% is vaporized into the flue gas. It appears that the partitioning characteristics according to the particle size of ash is different between the bottom ash and the fly ash. For bottom ash, the fraction of partitioning into 75${\mu}{\textrm}{m}$ oversized particles is reatively high. For fly ash, the characteristics of distributions with the particle size can not be clearly shown.

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Fabrication of tungsten carbide by pulsed electric current heating (펄스통전가열에 의한 텅스텐 탄화물의 제조)

  • Hong, Seong-Hyeon;Kim, Hyun-Jin
    • Particle and aerosol research
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    • v.5 no.4
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    • pp.153-158
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    • 2009
  • Tungsten carbide powder was fabricated with carbothermal reaction by pulsed electric current flowing in compact of tunsten oxide and carbon. The mixed powder of tunsten oxide and carbon was ball-milled into ultrafine powders. The mixed powder of tungsten oxide and carbon was put into carbon mold and heat-treated at $1050{\sim}1200^{\circ}C$ by pulsed electric current flowing. The formation of tungsten carbide powder could be achieved by heat treatment at $1200^{\circ}C$ for 10 minitues.

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Development of a meshless finite mixture (MFM) method

  • Cheng, J.Q.;Lee, H.P.;Li, Hua
    • Structural Engineering and Mechanics
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    • v.17 no.5
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    • pp.671-690
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    • 2004
  • A meshless method with novel variation of point collocation by finite mixture approximation is developed in this paper, termed the meshless finite mixture (MFM) method. It is based on the finite mixture theorem and consists of two or more existing meshless techniques for exploitation of their respective merits for the numerical solution of partial differential boundary value (PDBV) problems. In this representation, the classical reproducing kernel particle and differential quadrature techniques are mixed in a point collocation framework. The least-square method is used to optimize the value of the weight coefficient to construct the final finite mixture approximation with higher accuracy and numerical stability. In order to validate the developed MFM method, several one- and two-dimensional PDBV problems are studied with different mixed boundary conditions. From the numerical results, it is observed that the optimized MFM weight coefficient can improve significantly the numerical stability and accuracy of the newly developed MFM method for the various PDBV problems.