• 천문학논총
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• 제27권4호
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• pp.201-207
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• 2012

Following the first Public Release of the AKARI Point Source catalogues, we have worked on the production of a new far-infrared All-Sky Diffuse mapping product. In this paper we report first results from the All Sky diffuse maps that will shortly be released to the community, based on analysis of data from the Far Infrared Surveyor ($65{\mu}m-160{\mu}m$) instrument. These data are likely to have a strong impact on studies of extended structures, and the diffuse ISM.

• Bulletin of the Korean Chemical Society
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• 제35권9호
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• pp.2649-2654
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• 2014

Synthesis of north-5'-methylbicyclo[3.1.0]hexyl adenine and hypoxanthine nucleosides with an ethenyl group at C3' position was successfully achieved by a highly facile method. Methylbicyclo[3.1.0]hexanone (${\pm}$)-7 with three contiguous chiral centers and its epimer (${\pm}$)-6 was remarkably simply constructed only by four steps involving a carbenoid insertion reaction in the presence of rhodium (II) acetate dimer as a metal catalyst, giving a correct relative stereochemistry of the generated three chiral centers. Due to steric hindrance from the concave face of the bicyclo[3.1.0]hexanone system, a Grignard reaction of (${\pm}$)-7 with ethenylmagnesium bromide showed exclusive diastereoselectivity towards the b-face. The Grignard reaction chemoselectively proceeded without reacting with ester functionality. Coupling reaction of glycosyl donor (${\pm}$)-11 with 6-chloropurine nucleobase afforded only the desired $N^9$-alkylated nucleoside without the formation of $N^7$-regioisomer. By the conventional method, 6-chloro group was converted into 6-amino and 6-hydroxy groups to give the desired adenine and hypoxanthine bicyclo[3.1.0]hexyl carbanucleosides with 3'-ethenyl group, respectively.

• Bulletin of the Korean Chemical Society
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• 제30권9호
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• pp.2043-2050
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• 2009

2′-$\beta$-C-Methylneplanocin A (3) was synthesized via 2-$\beta$-C-methylribonolactone, prepared by a modified Whistler and BeMiller’s method developed by our laboratory, as potential anti-HCV agent. Reduction of 14 with Dibal-H afforded 26 in a good yield with a trace of 25, whereas a Luche reduction gave 26/25 = 4/1 mixture. Several attempts were made to chemoselectively remove TBS group in the presence of TBDPS group and treatment with both PPTS and TsOH showed the best result. Condensation of 26 with 6-chloropurine under Mitsunobu conditions produced an $S_N$2 product 27 along with an $S_N$2′ product 28.

• 천문학논총
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• 제32권1호
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• pp.63-65
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• 2017

The zodiacal light emission is the thermal emission from the interplanetary dust and the dominant diffuse radiation in the mid- to far-infrared wavelength region. Even in the far-infrared, the contribution of the zodiacal emission is not negligible at the region near the ecliptic plane. The AKARI far-infrared all-sky survey covered 97% of the whole sky in four photometric bands with band central wavelengths of 65, 90, 140, and $160{\mu}m$. AKARI detected the small-scale structure of the zodiacal dust cloud, such as the asteroidal dust bands and the circumsolar ring, in far-infrared wavelength region. Although the most part of the zodiacal light structure in the AKARI far-infrared all-sky image can be well reproduced with the DIRBE zodiacal light model, there are discrepancies in the small-scale structures. In particular, the intensity and the ecliptic latitude of the peak position of the asteroidal dust bands cannot be reproduced precisely with the DIRBE models. The AKARI observational data during more than one year has advantages over the 10-month DIRBE data in modeling the full-sky zodiacal dust cloud. The resulting small-scale zodiacal light structure template has been used to subtract the zodiacal light from the AKARI all-sky maps.

• 천문학논총
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• 제32권1호
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• pp.11-15
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• 2017

We present the AKARI far-infrared (FIR) all-sky maps and describe its characteristics, calibration accuracy and scientific capabilities. The AKARI FIR survey has covered 97% of the whole sky in four photometric bands, which cover continuously 50-180 micron with band central wavelengths of 65, 90, 140, and 160 microns. The data have been publicly released in 2014 (Doi et al., 2015) with improved data quality that have been achieved since the last internal data release (Doi et al., 2012). The accuracy of the absolute intensity is ${\leq}10%$ for the brighter regions. Quantitative analysis of the relative intensity accuracy and its dependence upon spatial scan numbers has been carried out. The data for the first time reveal the whole sky distribution of interstellar matter with arcminute-scale spatial resolutions at the peak of dust continuum emission, enabling us to investigate large-scale distribution of interstellar medium in great detail. The filamentary structure covering the whole sky is well traced by the all-sky maps. We describe advantages of the AKARI FIR all-sky maps for the study of interstellar matter comparing to other observational data.

• ALGAE
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• 제22권1호
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• pp.37-44
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• 2007

In order to understand the impact of the heavy-oil pollution by the 1997 Nakhodka oil spill on the intertidal macroalgal vegetation, we have been monitoring succession in the intertidal flora since 1997 at Oh-ura, Takno, and Imago-Ura Cove, Kasumi in Hyogo Prefecture, northwestern coast of Honshu, Japan. We employed two different monitoring methods: 1) The percent cover of macro-algae (seaweeds) in 1 x 1 m quadrats along 450 m intertidal transects parallel to the shoreline were assessed and recorded by photographic imaging until 2002, and for 30-40 m transects of the most heavily polluted areas in 2004 and 2006; 2) The percent cover of macro-algae in 0.5 x 0.5 m quadrats along a transect line perpendicular to the shore were recorded and all macrophytes within the quadrat were completely removed to record the wet weight of each taxon (1997-2006). Based on the monitoring data, we conclude that the high intertidal zone at Imago-ura, where a large part of the stranded oil accumulated, suffered the heaviest damage and experienced the slowest recovery. In addition, although the original status of macroalgal vegetation before the impact was not well-documented, it appeared that recovery from the damage caused by the oil pollution required four to five years.

• STI Policy Review
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• 제4권2호
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• pp.113-135
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• 2013

This paper explores how research excellence is perceived among researchers in Thailand and Japan with an aim to explore whether there are any new indicators that could later be proposed and adopted as criteria of excellence. Based on a questionnaire survey, the findings reflect ideas and viewpoints that could be found among researchers in both countries. Creative researchers are crucial to a strong national research and innovation system. Institutions should provide an environment or incentives based on research performance for their researchers to flourish and be productive. For decades, bibliometrics have been used to evaluate individual research performance for its easy approach and faster speed than a qualitative assessment would warrant. Nonetheless, there have been a number of studies on research performance evaluating systems that point out how a purely bibliometric approach is inadequate in summarizing the quality of the scientific performance. The pressures on researchers today influence their thinking and oppose their creativity. To investigate the perception of research excellence, three key research questions were set in this study: what counts as excellence, how to measure excellence, and how to support excellence. The findings confirm that traditional granting criteria that frames an idea of excellence remain valid, but they also suggest novel criteria be considered and prioritized. This paper argues that the existing evaluating system is insufficient for unleashing the curiosity and creativity of researchers and fostering excellence. In the final section, the paper discusses factors that contribute to scientific creativity that we should not overlook.

• 천문학논총
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• 제27권4호
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• pp.111-116
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• 2012

Far-infrared observations provide crucial data for the investigation and characterisation of the properties of dusty material in the Interstellar Medium (ISM), since most of its energy is emitted between ~ 100 and $200{\mu}m$. We present the first all-sky image from a sensitive all-sky survey using the Japanese AKARI satellite, in the wavelength range $50-180{\mu}m$. Covering > 99% of the sky in four photometric bands with four filters centred at $65{\mu}m$, $90{\mu}m$, $140{\mu}m$, and $160{\mu}m$ wavelengths, this achieved spatial resolutions from 1 to 2 arcmin and a detection limit of < 10 MJy $sr^{-1}$, with absolute and relative photometric accuracies of < 20%. All-sky images of the Galactic dust continuum emission enable astronomers to map the large-scale distribution of the diffuse ISM cirrus, to study its thermal dust temperature, emissivity and column density, and to measure the interaction of the Galactic radiation field and embedded objects with the surrounding ISM. In addition to the point source population of stars, protostars, star-forming regions, and galaxies, the high Galactic latitude sky is shown to be covered with a diffuse filamentary-web of dusty emission that traces the potential sites of high latitude star formation. We show that the temperature of dust particles in thermal equilibrium with the ambient interstellar radiation field can be estimated by using $90{\mu}m$, $140{\mu}m$, and $160{\mu}m$ data. The FIR AKARI full-sky maps provide a rich new data set within which astronomers can investigate the distribution of interstellar matter throughout our Galaxy, and beyond.