• Title/Summary/Keyword: Miscibility

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The Dyeing Characteristics of Wool Fabrics by Combination Dyeing of Gardenia and Sappan Wood (치자와 소목의 혼합염색에 의한 양모직물의 염색특성)

  • Sung, Woo-Kyung
    • Fashion & Textile Research Journal
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    • v.6 no.2
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    • pp.239-244
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    • 2004
  • On the whole the various medium colors were developed by repeat dyeing with different colorants after dyeing with one colorant in case of natural dyeing. In this study, in order to obtain various colors on wool fabrics with Gardenia and Sappan wood colorants, pre-mordanting and combination dyeing were carried out. Gardenia and Sappan wood used as natural colorants for combination dyeing showed good miscibility in dye bath, Metal compounds containing alum, copper and iron were used for pre-mordants. The various medium colors such as yellow-red were obtained according to various metal compounds for pre-mordants and various mixing portion of these natural colorants. The surface reflactance spectra and color characteristics of wool fabrics by mordanting and combination dyeing were investigated.

Study of Muffler for Rotary Compressor by Taguchi Method Viewpoint (회전형 압축기용 머플러의 연구 (1) : 다꾸찌 기법 관점에서)

  • 박성근
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 1998.04a
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    • pp.542-547
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    • 1998
  • As the concern for a global energy conservation and environmental protection are increasing, it has been more important thing to correspond with CFC depletion. Alternate refrigerants have merit such as lower global warming effect, but also have demerits such as lower efficiency, miscibility, increasing noise and poor reliability problems. Then we have to develop more efficient, silent and robust compressors to satisfying world-wide demand. In this paper, parametric study on rotary compressor muffler for a room air-conditioner was carried out to investigate the effect of important design variables on noise by using Taguchi robust design method with signal-to-noise(S/N) ratio. Taguchi method seems to be helpful for finding optimum value of design variables for noise level. We also applied neural network to find optimal value of design variables.

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Miscibility of TPU(PCL diol)/PCL Blend and its Effect on PCL Crystallinity

  • Ajili Shadi Hassan;Ebrahimi Nadereh Golshan
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.371-372
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    • 2006
  • Poly(${\varepsilon}-caprolactone$) (PCL) is a highly crystalline polymer that is miscible with several amorphous polymers including chlorinated polyether, poly(vinylchloride), poly(hydroxyether) and Bisphenol A polycarbonate. The crystallization behavior of miscible blend of amorphous/crystalline polymers has widely been studied. Generally a depression of the crystallization ability has been found with addition of amorphous component because of the reduction of chain mobility, the change of free energy of nucleation as a result of a specific interaction, and so on [1]. In this work, for the first time, the blend of PCL and copolymer of polyurethane containing polycaprolactone as a soft segment is considered. The structural similarity of TPU soft segment with PCL affects on formation of the miscible component and crystallization behavior of PCL in the blend. This has been studied using differential scanning calorimetry (DSC) and Wide-angle X-ray Scattering (WAXS).

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Enhanced Compatibility of PC/PMMA Alloys by Adding Multiwall Carbon Nanotubes

  • Bae, Do-Young;Lee, Heon-Sang
    • Carbon letters
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    • v.11 no.2
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    • pp.83-89
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    • 2010
  • We prepared polycarbonate (PC)/poly(methyl methacrylate) (PMMA)/multiwall carbon nanotube (MWCNT) nanocomposites by co-rotating twin screw extruder at 533 K. Thermal analysis results indicate that the miscibility of PC and PMMA is enhanced by MWCNTs. Bead necklace-like morphology of PMMA-rich phase is observed in PC/PMMA/MWCNT nanocomposites with increasing PMMA weight fraction due to the bead necklace-like morphology. The tensile strength of PC/PMMA (75/25)/MWCNT (1 wt.%) nanocomposite is 3% higher than those of PC/PMMA (75/25) alloy. Suppression of die swell by MWCNT filler is observed in the melt flow of PC/PMMA/MWCNT nanocomposites during extrusion.

The Effect of Barium Sulfate on the Structural Transformations in Tricalcium Silicate (3CaO.$SiO_2$의 구조전이에 미치는 $BaSO_4$의 영향)

  • 서일영;최상흘
    • Journal of the Korean Ceramic Society
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    • v.11 no.2
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    • pp.17-21
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    • 1974
  • Miscibility of barium sulfate in tricalcium silicate was investigated by firing 3CaCO3·SiO2 mixture containing barium sulfate at 1530℃. Added amount of barium sulfate to the mixture was zero to 5 mole % with intervals of 1 mole %. Lattice parametres were also calculated. Results were as follow; 1) Dissolution of barium sulfate in tricalcium silicate does not alter the symmetry in room temperature, but influences it's polymorphic transition forms, temperatures and thermal effects; modification triclinic Ⅱ is stabilized in room temperature. 2) Barium sulfate dissolves about up to 2 mole % in tricalcium silicate and more than this amount, tricalcium silicate formation is inhibited. 3) Unit cell volume of tricalcium silicate is slightly decreased with dissolution of barium sulfate, mainly because of contraction in c axis.

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The Dyeing Characteristics of Silk by Combination Dyeing of Gardenia and Sappan Wood (치자와 소목의 혼합염색에 의한 견의 염색특성)

  • Sung, Woo-Kyung
    • Fashion & Textile Research Journal
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    • v.4 no.2
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    • pp.192-197
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    • 2002
  • On the whole the various medium colors were developed by repeat dyeing with different colorants after dyeing with one colorant in case of natural dyeing. In this study, however in order to obtain various colors on silk fabrics with natural dyes, pre-mordanting and combination dyeing were carried out. Metal compounds containing alum, copper and iron were used for pre-mordants. Gardenia and Sappan wood were used as colorants for combination dyeing. In combination dyeing of Gardenia and Sappan wood, these two natural colorants showed good miscibility in dye bath. The various colors were obtained according to various metal compounds for pre-mordants and various mixing portion of Gardenia and Sappan wood.

Partial Miscibility in Polymer Mixtures from a Viewpoint of the Theory of Flory's Equation of State (Flory의 상태방정식 이론의 관점에서 본 고분자 혼합물에서의 부분혼합도)

  • Jung, Hae-Young
    • Journal of the Korean Chemical Society
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    • v.35 no.6
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    • pp.730-736
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    • 1991
  • In terms of the theory of Flory's Equation of State, the generalized condition for each case of partial miscibilities appearing in the polymer solutions or blends is given. And observing the changes of terms for energies and free volumes in ${\Delta}G_{mix}$ with increasing temperature, their effects on the partial miscibilities are generalized, and the effects of other parameters are also generalized.

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A Study on the Solidified Structures of Al-Pb Alloy Solidified by Rapid Cooling (급냉응고 시킨 Al-Pb 합금의 응고조직에 관한 연구)

  • Kim, Yong-Kil;Kim, Tong-Hoon
    • Journal of Korea Foundry Society
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    • v.2 no.1
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    • pp.12-18
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    • 1982
  • The present investigation was made to abtain a fine distribution of Pb Particles in AL - Pb binary alloys , which have a broad miscibility gap and large specific difference, by means of rapid Cooling of the molten alloys. Al-2.4% Pb, Al-5.5wt% Pb and Al-8.0wt % Pb alloy were used. The rapid cooling operation was performed by free falling of homogeneous liquid Al-Ph alloys into the water-cooled copper mold, and thermal analysis was made. Microstructures were observed, and variations of size and number of Pb particles were analysicle analyzer. By the result of examination with the varing cooling rates 100 to $210^{\circ}C/sec$ fine distributions of Pb particles were obtained with high cooling rate. Under same cooling condition, the best rapid cooling effect was recognized in Al-5.5wt% Pb alloy.

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Poly-${\varepsilon}$-caprolactone(PCL) / Polyvinyl chloride(PVC) 블렌드의 기계적 성질 및 생분해성

  • Seo, Hae-Jeong;Ha, Gi-Ryong;Gang, Seon-Cheol
    • 한국생물공학회:학술대회논문집
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    • 2002.04a
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    • pp.379-380
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    • 2002
  • Biodegradable polymers have been regarded as a good alternative to solve the plastic waste problems caused by nondegradable synthetic polymers such as polyethylene and polystyrene. In the soil environment, plastics are mainly being used as a mulching film for agricultural purposes. In this research, the miscibility, tensile properties and biodegradation effect of poly-${\varepsilon}$-caprolactone(PCL) with polyvinyl chloride(PVC) have been studied. After 8 weeks of biodegradation, PCL/PVC(9/91) blend surface showed newly formed many holes. Consequently, the antiplasticization phenomenon and biodegradation were observed in the PCL/PVC blends. It was confirmed that a test for general biodegradation condition can be applied to plastic biodegradation in soil.

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Phase Separation and Precipitation Characteristics in ZnS doped Borosilicate Glasses (ZnS 미립자 분산 붕규산엽계 유리에서의 분상 및 미립자 석출 특성)

  • 이승환;류봉기
    • Journal of the Korean Ceramic Society
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    • v.35 no.12
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    • pp.1337-1342
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    • 1998
  • To investigate an effect of phase separation on precipitation characteristics of ZnS microcrystals in ma-trix glass ZnS doped borosilicate glasses for nonlinear optical applications were prepared by melting and pre-cipitation process. ZnS dopant contributed to phase separation promotion which increased the phase separa-tion of the matrix glass within immiscibility region. It was also found that ZnS as phase separation promoter showed a similar contribution for some selected glass compositions in miscibility region. The precipitation of ZnS microcrystals occurred in thephase separable glass compoitions. The radius of ZnS microcrystals in-creased with increasing the heat treatment temperature and Na2O contents of matrix glass composition. The ZnS particle sizes estimated by effective mass approximation ranged from about 30 to 80${\AA}$ It was suf-ficiently small to show quantum confinement effect.

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