• Membrane and Water Treatment
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• v.4 no.1
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• pp.69-81
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• 2013

The pH-dependent inter-conversion of the three free chlorine species ($Cl_2$, HOCl, OCl-) present in the aqueous hypochlorite solution was theoretically investigated. Each species was found overwhelmingly present in a characteristic pH range. Hypochlorite treatment of the polyamide membrane was carried out over these pH ranges and various membrane responses were observed. As pH is less than 8, membrane tends to be N-chlorinated by $Cl_2$ and HOCl, and N-chlorinated membrane showed reduced water permeance and salt rejection. As pH rises to 10-12, $OCl^-$ appears to be the dominating chlorine species. Membrane hydrolysis was found to well interpret the improved water permeance and salt rejection. When the pH is between 8-10, both N-chlorination and hydrolysis contribute to the response of the membrane, and the treated membrane showed improved salt rejection but reduced water permeation. Excessive hydrolysis occurred while the membrane was treated at pH 13 for the much stronger alkalinity.

• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.635-642
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• 1995

Improved sample introduction system has been investigated for the determination of volatile organic compounds in water using a purge & trap preconcentration apparatus and a capillary gas chromatography/mass spectrometry. The present limitations associated with the moisture control module and cryorefocusing system suggested by EPA were discussed. To solve the problems such as improper separation of peaks due to the adsorption of water and contamination of purge & trap system, a more efficient connection system between the purge & trap apparatus and the gas chromatograph was introduced and the optimum operational conditions were suggested. A carbopack B/carboxen 1000 and 1001 trap was used for the purge & trap procedure and a custom made crosslinked dimethyldiphenylpolysiloxane capillary column was used for the separation of compounds. Accuracy and precision of the method suggested in this report were examined and the method detection limit of each compound was proposed for the simultaneous determination of 54 volatile organic compounds in water.

• Proceedings of the Korean Institute of Intelligent Systems Conference
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• 2003.09a
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• pp.372-375
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• 2003

The incidence of blindness resulting from diabetic retinopathy has significantly increased despite the intervention of insulin to control diabetes mellitus. Early signs are microaneurysms, exudates, intraretinal hemorrhages, cotton wool patches, microvascular abnormalities, and venous beading. Advanced stages include neovascularization, fibrous formations, preretinal and vitreous microhemorrhages, and retinal detachment. Microaneurysm count is important because it is an indicator of retinopathy progression. The purpose of this paper is to apply data mining to detect diabetic retinopathy patterns in routine fundus fluorescein angiography. Early symptoms are of principal interest and therefore the emphasis is on detecting microaneurysms rather than vessel tortuosity. The analysis does not involve image-recognition algorithms. Instead, mathematical filtering isolates microaneurysms, microhemorrhages, and exudates as objects of disconnected sets. A neural network is trained on their distribution to return fractal dimension. Hausdorff and box counting dimensions grade progression of the disease. The field is acquired on fluorescein angiography with resolution superior to color ophthalmoscopy, or on patterns produced by physical or mathematical simulations that model viscous fingering of water with additives percolated through porous media. A mathematical filter and neural network perform the screening process thereby eliminating the time consuming operation of determining fractal set dimension in every case.

• 한국지구물리탐사학회:학술대회논문집
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• 2003.11a
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• pp.42-51
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• 2003

The global demand for underground facilities has increased substantially in the past decades, and a substantial number of underground projects have had to deal with challenging ground conditions in urban environments. Particularly challenging are weak and unstable water bearing soils. Advancements in shielded TBM tech-nology have led to significant improvements regarding the ability to control ground deformations in soft ground. Nonetheless, ground collapse may occur even when the most advanced TBM designs are employed if unexpected adverse ground conditions are encountered or if insufficient stabilizing pressure is transferred to the tunnel face. This paper reviews common approaches for face stability and face pressure transmission calculations, and provides an overview of some of the latest technological developments and considerations for soft ground TBM applica-tions.

• 한국지구물리탐사학회:학술대회논문집
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• 2003.11a
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• pp.122-128
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• 2003

Rock bolts are widely used as a supplementary roof support system in hard-rock mining since a long time. Since the performance of fully grouted passive bolts depends on bond strength, in the present investigation extensive laboratory pull-out as well as push-out tests were conducted varying the bolt diameter, length and cement-water mixing ratios of grout. The load-displacement curves were developed and were verified with the numerical results obtained from finite element analysis using ALGOR software. Numerical models were validated for push-out tests and a detailed analysis was carried out to know the displacement, stress, strain distribution along the bolt.

• Environmental Engineering Research
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• v.17 no.1
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• pp.9-15
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• 2012

The effect of a rhamnolipid biosurfactant produced by a Pseudomonas aeruginosa MA01 strain on desulfurization of iron concentrates was studied. Surface tension measurement and frothing characterization indicated better surface activity and frothability of rhamnolipid compared to methyl isobutyl carbinol (MIBC) as an operating frother. Reverse flotation tests using rhamnolipid either as a sole frother or mixed with MIBC, showed that the desulfurization process is more efficient at pH 4.5 and high concentration of rhamnolipid in the presence of MIBC. However, under these conditions water recovery decreased due to the change in rhamnolipid aggregates morphology. Results from the present study seemed promising to introduce the biosurfactant from Pseudomonas aeruginosa as a new frother.

• Journal of the Korean Chemical Society
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• v.11 no.1
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• pp.8-11
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• 1967

A method of determination of gold in ores has been established: Disolved ore solution is evaporated to dryness, redissolved with 0.1N HCl then chloroaurate formed is adsorbed on anion exchange resin, Dowex $1\;{\cdot}\;{\times}4$. The resin is ignited and the residue is dissolved with HCl-$HNO_3$. After evaporation of the acid, and then dilution with water, sodium azide is added. The gold is extracted with amyl alcohol from the solution buffered to pH 6. The gold is determined by measuring absorbancy of the alcohol layer spectrophotometricaly at $385m{\mu}$. Various factors, HCl concentration, amount of the resin rate, if adsorption, foreign ions, effecting to the method, have been examined. This method seems to be satisfactory for the determination of gold presented dawn to 1g per metric ton in ore.

• Advances in concrete construction
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• v.4 no.4
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• pp.243-261
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• 2016

This research study focuses on utilizing sandstone which is overburden waste rock in coal mines to use in concrete as a replacement of fine aggregate. Physical properties of sandstone like water absorption, moisture content, fineness modulus etc., were found to be similar to conventional fine aggregate. Scanning Electron Microscope (SEM) analysis was carried out for analysing elemental composition of sandstone. There was no sulphur content in sandstone which is a good sign to carry the replacement. Fine aggregate was replaced with sandstone at 25%, 50%, 75% and 100% by volume and moulds of concrete cubes and cylinders were prepared. Compressive strength of concrete cubes was tested after 3, 7 and 28 days and split tensile & flexural strength was determined after 28 days. The strength was found to be increasing marginally with increase in sandstone content. Fine aggregate that was replaced by 100% sandstone gave highest strength among all the replacements for the compressive, split tensile and flexural strengths. Though increase in strength was marginal, still sandstone can be an effective replacement for sand in order to save the natural resource and utilize the waste sandstone.

• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.674-680
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• 2023

The brine and seawater are important and largely untapped sources of critical trace metals and elements. The coupling of selective recovery of trace metals from seawater/brine with desalination plants gives an added advantage of energy credits to desalination plants and as well as reduce the cost of desalinated water. In this paper, status review on recovery of important trace metals and other alkali metals from seawater is presented. The potential of Indian desalination plants for recovery of trace metals, based on recovery ratio of 0.35 is also highlighted. Studies carried out by the process based on adsorption using Radiation Induced Grafted (RIG) polymeric adsorbents and then fractional elutions are presented. The fouling factors due to bio fouling and dirt fouling have been estimated for various locations of interest through field trails. The pay loader in the form of compact Contactor Assembly with minimum pressure drop, for loading specially designed radiation grafted sorbent in leaflet form has been briefed, as required for plant scale facility. The typical conceptual process design details of farm assembly of project CRUDE are described.

• Structural Engineering and Mechanics
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• v.89 no.4
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• pp.399-409
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• 2024

Assessment of existing concrete bridges is a challenge for owners. It has greater economic impact when compared to designing new bridges. When using conventional linear analyses, judgment of the engineer is required to understand the behavior of redundant structures after the first element in the structural system reaches its ultimate capacity. The alternative is to use a predictive tool such as advanced nonlinear finite element analyses (ANFEA) to assess the overall structural behavior. This paper proposes a new reliability framework for the assessment of existing bridge structures using ANFEA. A general framework defined in previous works, accounting for material uncertainties and concrete model performance, is adapted to the context of the assessment of existing bridges. A "shifted" reliability problem is defined under the assumption of quasi-deterministic dead load effects. The overall exercise is viewed as a progressive pushover analysis up to structural failure, where the actual safety index is compared at each event to a target reliability index.