Browse > Article
http://dx.doi.org/10.4491/eer.2012.17.1.009

An Efficiency Evaluation of Iron Concentrates Flotation Using Rhamnolipid Biosurfactant as a Frothing Reagent  

Khoshdast, Hamid (Department of Mining Engineering, Shahid Bahonar University)
Sam, Abbas (Department of Mining Engineering, Shahid Bahonar University)
Publication Information
Abstract
The effect of a rhamnolipid biosurfactant produced by a Pseudomonas aeruginosa MA01 strain on desulfurization of iron concentrates was studied. Surface tension measurement and frothing characterization indicated better surface activity and frothability of rhamnolipid compared to methyl isobutyl carbinol (MIBC) as an operating frother. Reverse flotation tests using rhamnolipid either as a sole frother or mixed with MIBC, showed that the desulfurization process is more efficient at pH 4.5 and high concentration of rhamnolipid in the presence of MIBC. However, under these conditions water recovery decreased due to the change in rhamnolipid aggregates morphology. Results from the present study seemed promising to introduce the biosurfactant from Pseudomonas aeruginosa as a new frother.
Keywords
Desulfurization; Froth flotation; Iron concentrate; Rhamnolipid biosurfactant;
Citations & Related Records
Times Cited By KSCI : 1  (Citation Analysis)
Times Cited By SCOPUS : 0
연도 인용수 순위
1 Champion JT, Gilkey JC, Lamparski H, Retterer J, Miller RM. Electron-microscopy of rhamnolipid (biosurfactant) morphology: effects of pH, cadmium, and octadecane. J. Colloid Interface Sci. 1995;170:569-574.   DOI   ScienceOn
2 Ozdemir G, Malayglu U. Wetting characteristics of aqueous rhamnolipids solutions. Colloids Surf. B Biointerfaces 2004;39:1-7.   DOI   ScienceOn
3 Bulatovic SM. Handbook of flotation reagents. Amsterdam: Elsevier; 2007.
4 Montgomery DC. Design and analysis of experiments. 5th ed. New York: John Wiley & Sons; 2001.
5 Xia Y, Peng FF. Frothability characterization of residual organic solvents. Miner. Eng. 2007;20:241-251.   DOI   ScienceOn
6 Cho YS, Laskowski JS. Effect of flotation frothers on bubble size and foam stability. Int. J. Miner. Process. 2002;64:69-80.   DOI   ScienceOn
7 Melo F, Laskowski JS. Fundamental properties of flotation frothers and their effect on flotation. Miner. Eng. 2006;19:766-773.   DOI   ScienceOn
8 Rezaei B. Flotation. Tehran: Tehran University Press; 1996.
9 Laskowski JS. Fundamental properties of flotation frothers. In: Proceedings of the 22nd International Mineral Processing Congress; 2003 Sep 29 - Oct 3; Cape Twon, South Africa. p. 788-797.
10 Laskowski JS. Testing flotation frothers. Physicochem. Prob. Miner. Process. 2004;38: 13-22.
11 Khoshdast H, Sam A, Manafi Z. Comparison of surface activity from rhamnolipid biosurfactants and industrial flotation frothers. In: The 1st National Copper Conference; 2011: Iran. p. 544-552.
12 Ishigami Y, Gama Y, Nagahora H, Yamaguchi M, Nakahara H, Kamata T. The pH sensitive conversion of molecular aggregates of rhamnolipid biosurfactant. Chem. Lett. 1987;16:763-766.   DOI
13 Boekhoven J. Self-assembling systems - research - orthogonal self-assembly. Delft: Delft University of Technology; 2009 [cited 2011 May 1]. Available from: http://www.tnw.tudelft.nl/live/css/styles_tamtam.css.
14 Benincasa M, Marqués A, Pinazo A, Manresa A. Rhamnolipid surfactants: alternative substrates, new strategies. In: Sen R, ed. Biosurfactants. New York: Springer Science; 2010. p. 170-184.
15 Banford AW, Aktas Z, Woodburn ET. Interpretation of the effect of froth structure on the performance of froth flotation using image analysis. Powder Technol. 1998;98:61-73.   DOI   ScienceOn
16 Khoshdast H, Sam A. Flotation frothers: review of their classifications, properties and preparation. Open Miner. Process. J. 2011;4:25-44.   DOI
17 Fazaelipoor MH, Khoshdast H, Ranjbar M. Coal flotation using a biosurfactant from Pseudomonas aeruginosa as a frother. Korean J. Chem. Eng. 2010;27:1527-1531.   DOI
18 Engelbrecht JA, Woodburn ET. The effects of froth height, aeration rate, and gas precipitation on flotation. J. S. Afr. Inst. Min. Metall. 1975;76:125-132.
19 Neethling SJ, Cilliers JJ. The entrainment of gangue into flotation froths. Int. J. Miner. Process. 2002;64:123-134.   DOI   ScienceOn
20 Ekmekci Z, Bradshaw DJ, Harris PJ, Buswell MA. Interactive effects of the type of milling media and CuSO4 addition on the flotation performance of sulphide minerals from Merensky ore part II: froth stability. Int. J. Miner. Process. 2006;78:164-174.   DOI   ScienceOn
21 ChemSW. Chemsite pro demo software [Internet]. Fairfield: ChemSW Inc.; c2012. Availabe from: http://www.chemsw.com.
22 Hein M. Foundations of college chemistry: the alternative edition. New York: Brooks/Cole Publishing Company; 1980.
23 Luan F, Liu H, Gao Y, Li Q, Zhang X, Guo Y. Prediction of hydrophile- lipophile balance values of anionic surfactants using a quantitative structure-property relationship. J. Colloid Interface Sci. 2009;336:773-779.   DOI   ScienceOn
24 Cohen R, Exerowa D. Surface forces and properties of foam films from rhamnolipid biosurfactants. Adv. Colloid. Interface Sci. 2007;134-135:24-34.   DOI   ScienceOn
25 Guo X, Rong Z, Ying X. Calculation of hydrophile-lipophile balance for polyethoxylated surfactants by group contribution method. J. Colloid and Interface Sci. 2006;298:441-450.   DOI   ScienceOn
26 Helvaci SS, Peker S, Ozdemir G. Effect of electrolytes on the surface behavior of rhamnolipids R1 and R2. Colloids Surf. B Biointerfaces 2004;35:225-233.   DOI   ScienceOn
27 Ozdemir G, Peker S, Helvaci SS. Effect of pH on the surface and interfacial behavior of rhamnolipids R1 and R2. Colloids Surf. A Physicochem. Eng. Asp. 2004;234:135-143.   DOI   ScienceOn
28 Sanchez M, Aranda FJ, Espuny MJ, et al. Aggregation behaviour of a dirhamnolipid biosurfactant secreted by Pseudomonas aeruginosa in aqueous media. J. Colloid Interface Sci. 2007;307:246-253.   DOI   ScienceOn
29 York JD, Firoozabadi A. Comparing effectiveness of rhamnolipid biosurfactant with a quaternary ammonium salt surfactant for hydrate anti-agglomeration. J. Phys. Chem. B 2008;112:845-851.   DOI   ScienceOn
30 Pornsunthorntawee O, Chavadej S, Rujiravanit R. Solution properties and vesicle formation of rhamnolipid biosurfactants produced by Pseudomonas aeruginosa SP4. Colloids Surf. B Biointerfaces 2009;72:6-15.   DOI   ScienceOn
31 Pornsunthorntawee O, Wongpanit P, Chavadej S, Abe M, Rujiravanit R. Structural and physicochemical characterization of crude biosurfactant produced by Pseudomonas aeruginosa SP4 isolated from petroleum-contaminated soil. Bioresour. Technol. 2008;99:1589-1595.   DOI   ScienceOn
32 Fu H, Zeng G, Zhong H, et al. Effects of rhamnolipid on degradation of granular organic substrate from kitchen waste by a Pseudomonas aeruginosa strain. Colloids Surf. B Biointerfaces 2007;58:91-97.   DOI   ScienceOn
33 Guo YP, Hu YY, Gu RR, Lin H. Characterization and micellization of rhamnolipidic fractions and crude extracts produced by Pseudomonas aeruginosa mutant MIG-N146. J. Colloid Interface Sci. 2009;331:356-363.   DOI   ScienceOn
34 Hanumantha Rao K, Vilinska A, Chernyshova IV. Minerals bioprocessing: R & D needs in mineral biobeneficiation. Hydrometall. 2010;104:465-470.   DOI   ScienceOn
35 Ishigami Y. Characterization and functionalization of biosurfactants. In: Esumi K, Ueno M, eds. Structure-performance relationships in surfactants. 2nd ed. New York: Marcel Dekker Inc.; 2003. p. 285-308.