• Title/Summary/Keyword: Minimum spontaneous ignition temperatures

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Prediction of Minimum Spontaneous Ignition Temperature(MSIT) of the Mixture of n-Pentanol and Ethylbenzene (n-Pentanol과 Ethylbenzene 혼합물의 최소자연발화온도의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.16 no.2
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    • pp.45-51
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    • 2012
  • The MSITs(Minimum Spontaneous Ignition Temperatures) or AITs(Autoignition Temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. This study measured the MSITs(Minimum Spontaneous Ignition Temperatures) of n-pentanol+ethylbenzene system by using ASTM E659 apparatus. The MSITs of pure n-pentanol and ethylbenzene were $285^{\circ}C$ and $475^{\circ}C$, respectively. The experimental MSITs of n-pentanol+ethylbenzene system were a in good agreement with the MSIT calculated by the proposed equations with a few A.A.D.(average absolute deviation).

A Study on the Spontaneous Ignition Characteristics and Fire Risk of Commercial Wood Pellets (산업용 우드펠릿의 자연발화 특성과 화재위험성에 관한 연구)

  • Choi, Yu-Jung;Kim, Jung-Hun;Choi, Jae-Wook
    • Korean Chemical Engineering Research
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    • v.55 no.5
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    • pp.623-628
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    • 2017
  • Using wood pellets, which are used as fuel for thermal power generation plants, as test specimens, the minimum spontaneous ignition temperatures according to the size of the container for the test specimens were measured, and by applying the Frank-Kamenetskii theories on thermal energy to these temperatures, the danger factor of the materials were calculated by deriving the apparent activation energies. The results confirmed that the ignition threshold temperature decreased as the size of the container increased and that the spontaneous ignition energy was 37.83 kcal/mol. The results also confirmed that the larger the container for the test specimens was the time to arrive at the spontaneous ignition time and maximum temperature also increased.

A Study on the Spontaneous Ignition of Gasoline and Additive of Fuel (Gasoline과 연료첨가제(Cenox)의 자연발화에 관한 연구)

  • Choi, Jae-Wook;Mok, Yun-Soo;Choi, Il-Gon;Jeon, Se-Ho;Lim, Woo-Sub;Min, Chul-Woong
    • Fire Science and Engineering
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    • v.20 no.1 s.61
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    • pp.1-5
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    • 2006
  • The spontaneous ignition of a flammable matter is a crucial factor for the prevention of a fire. The minimum ignition temperatures of Gasoline and Cenox in $1000{\mu}l$ of a sample were determined to be $340.5^{\circ}C\;and\;368.5^{\circ}C$ respectively. In addition when the time taken for ignition was 1.0 sec, the instantaneous ignition temperatures were $416^{\circ}C\;and\;427^{\circ}C$ respectively. Moreover, the changes in the minimum ignition temperature were small when less than 60 v/v% of Cenox was added, but the changes were great when 80 v/v% or more was added. Therefore, it is hypothesized that, when used as a fuel in the Gasoline engine, the ratio of the mixture of Cenox and Gasoline will be a very important factor.

A Study on the Flash Point and Spontaneous Ignition Determination of Diethylene Glycol

  • Kim, Jung-Hun;Choi, Jae-Wook
    • Journal of the Korean Solar Energy Society
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    • v.36 no.2
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    • pp.73-78
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    • 2016
  • This study investigates the main factors of fire prevention, such as spontaneous ignition and flash point, while using Diehylene Glycol (DEG) as the antifreeze for automobile and industrial machines. Our results show the flash point of $142^{\circ}C$ and the minimum ignition temperature of $388^{\circ}C$ in the range of $130{\mu}{\ell}{\sim}150{\mu}{\ell}$. By increasing temperature to ignite in 1 second, an instantaneous ignition temperature of the sample is $569^{\circ}C$ in the sample amount of $140{\mu}{\ell}$.

Measurement and Prediction of Combustion Properties of n-Phenol (페놀의 연소특성치의 측정 및 예측)

  • Ha, Dong-Myeong
    • Korean Journal of Hazardous Materials
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    • v.6 no.2
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    • pp.23-29
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    • 2018
  • The fire and explosion properties necessary for waste, safe storage, transport, process design and operation of handling flammable substances are lower explosion limits(LEL), upper explosion limits(UEL), flash point, AIT( minimum autoignition temperature or spontaneous ignition temperature), fire point etc., An accurate knowledge of the combustion properties is important in developing appropriate prevention and control measures fire and explosion protection in chemical plants. In order to know the accuracy of data in MSDSs(material safety data sheets), the flash point of phenol was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of phenol was measured by ASTM 659E apparatus. The explosion limits of phenol was investigated in the reference data. The flash point of phenol by using Setaflash and Pensky-Martens closed-cup testers were experimented at $75^{\circ}C$ and $81^{\circ}C$, respectively. The flash points of phenol by Tag and Cleveland open cup testers were experimented at $82^{\circ}C$ and $89^{\circ}C$, respectively. The AIT of phenol was experimented at $589^{\circ}C$. The LEL and UEL calculated by using Setaflash lower and upper flash point value were calculated as 1.36vol% and 8.67vol%, respectively. By using the relationship between the spontaneous ignition temperature and the ignition delay time proposed, it is possible to predict the ignition delay time at different temperatures in the handling process of phenol.