• Title/Summary/Keyword: Mineralogical analysis

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Occurrence and Mineralogy of Serpentine Minerals in the Calc-silicate Rock Sheets from the Bonghwa Area, Kyungsangbuk-do (경북 봉화지역의 석회규산염층에서 산출되는 사문석광물의 산상 및 광물학적 특성)

  • Bae, Sung-Woo;Hwang, Jin-Yeon;Lee, Son-Kap;Kwack, Kyu-Won;Yoon, Ji-Hae;Cho, Sung-Hwi
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.1
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    • pp.85-98
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    • 2008
  • Calc-silicate rock sheet occurs within the Precambrian metasedimentary rocks in Bonghwa area, Kyungsangbuk-do, Korea. The calc-silicate rock runs parallel to bedding plane with $14{\sim}18$ meters in width. Calcite, dolomite, serpentine and tremolite are occurred as major minerals and talc is occurred as a miner mineral. Serpentine mainly occurs in the upper part and tremolite occurs in lower part of calc-silicate rock sheet. Colors of calc-silicate rock change to deeper green with increasing amounts of serpentine mineral. XRD, FT-IR analyses indicates that serpentine mineral is antigorite. Platy structure of antigorite is well observed by SEM analysis. EPMA data indicates that chemical composition of antigorite is very close to ideal ($SiO_2$: 44.3 wt% and MgO: 40.8 wt%). The chemical formula of antigorite is calculated as $Mg_{2.82}Al_{0.04}Fe^{3+}_{0.04}Si_{2.05}O_5(OH)_4$. From careful study by comparing mineralogical analysis data and occurrence, calc-silicate rock sheet was formed by metamorphism of calcareous sedimentary rocks having different mineralogical and chemical compositions. It is considered that the host rock of serpentine enriched upper part was more Mg-rich rocks than the host rocks of tremolite enriched lower part.

Separation and Mineralogy of Marine Sand Near Haeju bay, North Korea (북한 해주만 부근 해사의 선별 및 광물학적 특성)

  • Chae, Soo-Chun;Shin, Hee-Young;Bae, In-Kook;Kwon, Sung-Won;Lee, Soo-Jung;Kim, Wan-Tae;Lee, Chun-Oh;Jang, Young-Nam
    • Journal of the Mineralogical Society of Korea
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    • v.22 no.3
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    • pp.217-227
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    • 2009
  • Heavy minerals in the marine sand near Haeju bay, Hwanghae-do, North Korea were separated using the gravity and the magnetic separators. And their mineralogical study was carried out. Ilmenite, magnetite, hematite, zircon and monazite were observed as the valuable minerals, and quartz, orthoclase, muscovite, hornblende and garnet existed as gangue minerals. In the result of quantitative analysis with SIROQUANT program, the contents of the valuable minerals separated with the 2nd gravity separation (the shaking table separation), the 1st magnetic separation (rare earth magnetic separation) and the 2nd magnetic separation (the Eddy current magnetic separation) were increased into 4%, 10% and 76~89% (under the condition of 7000 G and 10000 G in magnetic strength), respectively. The contents of ilmenite, monazite and zircon recalculated from the chemical composition differed from the results of the quantitative analyses by SIROQUANT program, but the entire tendency bears some analogy with it. Under the conditions of 7000 G and 10000 G in 2nd magnetic separation the contents of ilmenites were concentrated with 53% and 66%, respectively. The content of monazite was 1.2% in the magnetic fractions of the 1st magnetic separation. The content of zircon was shown 1.4% under the condition of 10000 G in the 2nd magnetic separation, and was displayed 9% in +50 mesh of non-magnetic fraction of 1st magnetic separation, especially.

Trace Element Compositions and Optically Stimulated Luminescence Characteristics of Sedimentary Quartz (퇴적물 내 석영의 광여기 루미네선스 특성과 미량원소 조성)

  • Jeon, Gi-Young;Choi, Jeong-Heon;Kil, Young-Woo
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.357-365
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    • 2010
  • Optically stimulated luminescence (OSL) of quartz is commonly applied to the age dating of Quaternary sediments. However, one of the issues is that some of the quartz samples are not suitable to OSL dating. Mineralogical analysis of the quartz samples with diverse OSL signals are required to strengthen the reliability and applicability of the OSL dating. We analysed the OSL signal characteristics of sedimentary quartz samples from diverse geological environments and measured their trace element contents using laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS). Quartz samples could be grouped into ones suitable to OSL dating and ones unsuitable on the basis of their OSL signal characteristics. The average trace element contents ranged from 73 to 260 ppm (Al), and from 61 to 248 ppm (Ti) with minor Li, Mg, Cr, Mn, and Fe contents below 40 ppm. We did not find any significant variation of trace element contents of quartz samples consistent with their OSL signal characteristics. This indicates unknown mineralogical factors causing diverse OSL characteristics which should be confirmed by further analysis of sufficient set of samples.

Field Measurement and Analysis of Fluvial Sediment in the Cheongmi-Stream(II) - Mineralogical and Contaminative Characteristics of Sediment Particles - (청미천에서의 하천 유사 측정 및 분석(II) - 유사의 광물특성 및 오염도 -)

  • 우효섭;이진국
    • Water for future
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    • v.24 no.3
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    • pp.49-60
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    • 1991
  • As a second part of the study entitled "Field Measurement and Analysis of Fluvial Sediment in the Cheongmi-Strea", this study concerns mineralogical and contaminative characteristics of sediment particles collected at Wonbu-Gyo and Hanpyeong-Gyo in the Cheongmi-Stream. The mineralogical analysis of the bed sediment collected reveals that, in general , quarz is the most abundant mineral found in sands with feldspars and rock fragments in the next, which confirms what is known in the literature. The shape factor of sand particles is about 0.7, which also agrees to what is known in the foreign literature. The analysis also reveals that the clay particles collected are composed mainly of illite, kaolinate, and chlorite. The analysis of contamination reveals that there is no substantial difference between the contents of organic material and heavy metals in the surface water and those in the pore water beneath the river bed. It is because the sampling for this analysis was conducted right after the September flood during which the fresh top soil from the upstream watershed replaced the old bed sediment and pore water that would probably be more contaminated. The contents of geavy metals in the bed sediment of sand particles do not exceed those in the soils adjacent to the river. For fine sediment such as clays, however, the contents of heavy metals, especially of mercury and zinc, far exceed those in the soils adjacent to the river. These fine sediments are transported downstream in the form of wash load and deposited in part on flood plains, which could be a new source of contaminants.taminants.

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Characterization of Hydroxy-interlayered Mineral in Non-Andic Soils from Jeju Island

  • Lee, Gyoo-Ho;Yungoo Song;Ha, Dae-Ho;Moon, Hi-Soo;Moon, Ji-Won
    • Proceedings of the Mineralogical Society of Korea Conference
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    • 2001.06a
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    • pp.45-47
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    • 2001
  • Jeju island is composed mainly of volcanic rocks such as basalts, trachytic andesites, tracytes, and sedimentary rocks. About 80% of Jeju soils are classified as Andisols. The amount of annual precipitation in Jeju island is about 1872mm, which is 1.5 times the annual precipitation of south Korea. There is a significant difference In amount of precipitation with regions even within Jeju island. In study area, the annual amount of rainfall is about 1280mm, the lowest in Jeju island while south part of the island has the annual precipitation of 2056mm, though they are only tens of kilometers apart. The parent materials of soils in study area are pyroclastic rocks and tuffs. The soils of non-andic properties have developed in this area since pedogenic process of pyroclastic materials is strongly influenced by climatic factor, especially precipitation. In order to investigate the mineralogical characteristics of soils, X-ray analysis for <0.2 and 2-0.2$\mu\textrm{m}$ size fractions was performed with ethylene glycol solvation, K-, Mg-saturation, heat treatment(110, 330, 550$^{\circ}C$). Acid-oxalate and DCB(sodium hydrosulfite, sodium citrate, sodium bicarbonate) dissolution method was used to assess tile total amounts or Al, si, and hydroxy interlayer or 2:1 layer silicates. XRD was also applied for samples treated with DCB only and DCB-oxalate sequentially. XRD patterns showed that 2:1 and 1:1 layer silicates were found, which are different from soils of Andisols. Vermiculite, chlorite, hydroxy interlayered minreals, and interstratified minerals(vermiculite/chlorite) were observed in 2-0.2$\mu\textrm{m}$ size fractions. After DCB treatments, ethylene glycolated samples with Mg-saturation showed expanded d-spacing, suggesting the possibility of hydroxy interlayered minerals. The amounts of hydroxy interlayered minerals increased in surface soil. Unlike Andisols, short range ordered minerals such as allophane, imogolite and gibbsite were hardly found. Mica and kaolinte existed in small amounts. Results are summarized in Fig 1 and Fig. 2.

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Mineralogical Characteristics and Origins of Smectite in the Marine Sediment around South Shetland Islands, Antarctica (남극 사우스셰틀란드 해양퇴적물내 스멕타이트의 광물학적 특성과 기원)

  • 정기영;윤호일
    • Journal of the Mineralogical Society of Korea
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    • v.15 no.1
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    • pp.22-32
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    • 2002
  • Mineral composition and chemistry of the clay minerals in the three cores from the continental shelves of South Shetland Islands (NCS09) and Anberse Island (GC98-2), and from the fjord of King George Island (A10-01) were determined by X-ray diffraction and electron microprobe analysis in search of the distributions and origin of the clay minerals in the Antarctic marine sediments. Smectite content is relatively high in NCS09 regardless of core depths (av. 8.3%), but low in GC98-2 (1.1%). In Al0-01, smectite content is higher in the upper section than in the lower section. Kaolinite was not detected from all the cores in this study Yellow to yellowish green clay granules were commonly scattered in the sediments of NCS09 cores. The clays contain 16.97% and 2.53% $Fe_2$$O_3$$K_2$O. Average structural formula of the clay indicates ferrian beidellite . The (Fe, K)-rich smectite of NSC09 must have been derived from relatively young basaltic volcanics altered by reaction with seawater near Shetland Islands by glacial erosion or eolian process related to volcanic eruption. GC98-2 nearer to Antarctic continent is very low in smectite content. In A10-01, the lower diamicton was deposited from the glacial erosion of smectite-free ancient volcanics in the interior of King George Island, while the upper section was derived from the smectite-bearing terrestrial debris and eolian materials after retreat of glaciers in Marian Cove and ice cover in Barton Peninsula. Thehigh K contents of smectites suggest the interstratification of illite and smectite layers, which might be observed by future TEM lattice fringe imaging.

Chemical Weathering of Hornfels Pebbles in the Marine Terrace Deposits, Yangnam-Myon, Gyeongju (경주시 양남면 제4기 해안단구퇴적층내 혼펠스 자갈의 화학적 풍화작용)

  • 정기영;이봉호
    • Journal of the Mineralogical Society of Korea
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    • v.17 no.1
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    • pp.85-97
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    • 2004
  • Weathering of hornfels pebble in the marine terrace deposits, Yangnam-Myon, Gyeongju was investigated by X-ray diffraction, scanning electron microscopy, and chemical analysis. In the early stage of weathering, only plagioclase was leached leaving pores. With progress of weathering, biotite and chlorite were tranformed to hydrobiotite and chlorite-vermiculite, respectively. Quartz, K-feldspar, and muscovite were not altered. Thickness of weathering rinds and their mineralogical characteristics were different between terraces of different elevations. In the lower second terrace, the weathering of pebble was dominated by the decomposition of plagioclase, while in the upper third terrace, weathering was characterized by the transformation of biotite and chlorite with precipitation of halloysite from the weathering of plagioclase. Thickness of weathering rind and weathering products were varied even within the same terrace deposit probably due to local variation of drainage conditions.

A Study o the Geological Occurrence, the Mineralogical and Physico-chemical Properties of the Sericite Ore from the Yangbuk Area, Kyungsangbuk-do (경북 양북지역산 견운모광석의 물성 및 부존산상)

  • 이동진;고상모
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.2
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    • pp.85-96
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    • 1998
  • The sericite ore is formed by the hydrothermal alteration of rhyodacitic welded tuff. The alteration zone of the host rock can be classified into four types based on the mineral assemblages ; sericite, quartz-sericite, silicified and propylite zone. The sericite ore mainly occurs as vein types and fault clay along the fault plane in the quartz-sericite zone. Mineral components of the sericite ore are mainly sericite with minor diaspore, corundum and pyrite. The sericitic porcelaineous ore is mainly composed of quartz and sericite. Accessory minerals are muscovite, diaspore, sphene, corundum, pyrite, iron-oxides and etc. The chemical compositions of K2O, Al2O3, and ignition loss in the sericite ore increase largely than that of the host rock, while the compositions of SiO2, Na2O and Fe2O3 decrease. XRD patterns of the heat-treated sericite ores show the formation of mullite at $1,200^{\circ}C$. and the diaspore-bearing sericite ore forms mullite and corundum at $1,200^{\circ}C$. The differential thermal analysis of the sericite ores show small endothermic peak at 645~668$^{\circ}C$. and the diaspore-bearing sericite ore shows a strong endothermic peak at $517^{\circ}C$. It indicates that the decomposition of diaspore appear at lower temperature than that of sericite. The thermal expansivity of the sericite ores show the similar pattern. The sericite ores show the thermal expansivity of 3.3~4.7% at 900$^{\circ}C$ and 0.39~0.75% at 1,20$0^{\circ}C$, respectively. DTA-TG curves of the sericite ores show closely relations with the thermal expansivity.

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Distribution of Clay Minerals in Soils on the Northern Drainage Basin of the Nakdong River (낙동강 북부 배수유역의 토양 점토광물 분포)

  • Lee, Bong-Ho;Jeong, Gi-Young
    • Journal of the Mineralogical Society of Korea
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    • v.21 no.4
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    • pp.349-354
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    • 2008
  • Semiquantitative mineralogical analysis of clays in soils was performed to understand the distribution of clay minerals in relation to bedrock lithology on the northern basin of the Nakdong River. The soils developed on the granitic bedrocks have high contents of kaolinite and smectite. mite was the major clay mineral in the soils from sedimentary bedrocks, with minor kaolinite, smectite, and intergrade (interstratified chlorite-smectite or hydroxy-interlayed vermiculite) clay minerals. Illite and kaolinite contents of the soils from metamorphic and volcanic bedrocks fall between those of the soils from the granitic bedrocks and those of the soils from the sedimentary bedrocks. The clay mineralogy of the soils depends on the compositions of bedrock minerals and their susceptibility to chemical weathering. The weathering of plagioclase resulted in the high kaolinite content of the soils derived from granitic bedrocks, while the soils derived from sedimentary bedrocks are abundant in residual illite.

Mineralogical Characteristic and Occurrence of Tremolite and Actinolite in the Dong-A mine, Korea (동아광산 일대 투각섬석과 양기석의 산출상태 및 광물학적 특성 연구)

  • Kim, Seong Ho;Kim, Jeong Jin
    • Journal of the Mineralogical Society of Korea
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    • v.28 no.4
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    • pp.333-341
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    • 2015
  • As results of X-ray diffraction analysis, samples of asbestos and soil were composed maily of dolomite ($CaMg(Co_3)_2$, tremolite ($Ca_2Mg_5Si_{18}O_{22}(OH)_2$), actinolite ($Ca(Mg,\;Fe)_6Si_8O_{22}(OH)_2$), talc ($Mg_3Si_4O_{10}(OH)_2$), calcite ($CaCO_3$) and small amounts of quartz ($SiO_2$) and clay minerals. The average size of asbestos fibers was about $100{\mu}m$ and maximum of some asbestos was $250.0{\mu}m$ in length. The aspect ratio of asbestos fiber were over 3 : 1 and inclined extinction in the range of $8.0-19.5^{\circ}$. Single isolated fragments of asbestos are probably fiber and acicula form in crystal edge along the cleavage plane. Tremolite that composed main asbestos mineral in rock and soil around Dong-a mine is higher content of Fe than actinolite asbestos.