• Proceedings of the KIEE Conference
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• 1988.11a
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• pp.241-245
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• 1988

This paper reports the experiments regarding to diagnosis techniques for power transformers by measuring dissipation factor and moisture contents of mineral oils. Thermal aging environments of mineral oils were varied by the specially designed systems. Thermal aging of elevated temperature of $90^{\circ}C$ was performed for about 240 and 460 hours, respectively. Dissipation factor, permittivity, and water content were measured. Our test samples were not exposed to air. Dissipation factor increased while permittivity did not change. The level of dissipation factor determining the insulating quality of mineral oil was compared with the previous results of resistivity and several correction factor.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.495-501
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• 2016

Mineral oil has been widely used as an insulating oil for electrical transformers for a long time, but the necessity of employing new insulation oil such as vegetable oil has been increased due to urgent needs for the biodegradability when it leaks and also for the thermal stability at a higher operation temperature. Although specific periods are required between the production and consumption, there are still short of the data to prove the insulation oils' storage stability depending upon various circumstances and their resources. Thus, this paper demonstrates the insulation oils' oxidation characteristics of both mineral and vegetable oils when each was exposed to different environments for 12 weeks. From this test, some properties including total acid number, water content and dielectric breakdown were changed under specific conditions and resources. Vegetable oils showed higher hydrophilicity and water saturation than those of mineral oils due to their molecular compositions. Under sunlight exposure condition, all insulation oils oxidized and changed their properties when exposing to the direct light, regardless of the resource used.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.60 no.6
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• pp.1163-1168
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• 2011

Most transformers use insulating and cooling fluids derived from petroleum crude oil, but mineral oil has some possibility of environmental pollution and fire with explosion. vegetable oil fluids extracted from seed has superior biodegradation and fire-resistant properties including an exceptionally high fire point enhancing fire safety. In this study, it is aimed at the practicality of substituting natural ester dielectric fluid for mineral oil in liquid insulation system of transformers. As a rise in coil winding temperature has a direct influence on transformer life time, it is important to evaluate the temperature rise of coil winding in vegetable oil in comparison with mineral oil. Four transformers for the test are designed with 10KVA, 13.2KV, one phase unit. The temperature are directly measured in insulating oil of these transformers with the two sorts of natural ester and mineral oil dielectric fluid respectively. Experiment for aging carry out two means. First means remained $120^{\circ}C$ that transformer of mineral oil were operated at 185% load. Second means is that insulating oils of two natural ester and mineral oil were aged by thermal cycles repeating from $30^{\circ}C$ to $120^{\circ}C$. For the heating, Transformers were operated at 185% load. For the cooling, cooling system was operated in the chamber. Samples were analyzed at 42, 63, 93, 143, 190, 240 300cycles. Analysis contents are dielectric strength, total acid value. Mineral oils compared results of first means with results of second means. And compared two sort natural esters respectively with mineral oil in second means.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.6 no.4
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• pp.439-452
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• 1994

One of the chlorofluorocarbon compounds. R-12 deplete atmospheric ozone. It leads to international agreement to reduce CFC production. R-134a has similar thermodynamic properties to CFC-12. It has zero ODP(Ozone Depletion Potential). This Paper focuses on the lubricating oils for using with R-134a PAGs(Polyalkylene Glycol's) and esters are primary lubricants that are now being tested for use with R-134a Because of extreme polarity of R-134a. there are many problems in the selection of lubricating oil. This investigation analyzes compressor working conditions and calculates wear parts friction for simulation testing. Miscibility and material compatibility is proved by sealed glass tests. Friction was tested on the closed type pin on disk wear tester. This equipment simulates actual refrigerating compressor. Environment controlled test made more reliable result than field test Conventional oils(mineral oils, Alkylbenzene, PAO(Polyalpha Olefin) are immiscible with R-134a. PAGs and ester oils are miscible with R-134a. Friction coefficient is similar to conventional system(mineral oil/R-12 systems) at operating condition. At start & stop condition, PAGs/R-134a system has high friction coefficient. It provide reliable result on the lubricity, miscibility, material compatibility of R-134a with these new lubricants. It suggests proper selection of refrigeration oil that may improve compressor durability of performance.

• Proceedings of the KIEE Conference
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• 2004.07c
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• pp.1829-1831
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• 2004

This paper described the capacitive sensor for the diagnosis of deterioration of electrical insulating oils applying guard-ring type the 3-terminal electrodes. To measure stable capacitance of the sensor and to determine the design factors of the sensor, we utilized computational analysis, FEM software. This capacitive sensor discern the extent of deterioration measuring relative permittivity of electrical insulating oils. The result of measuring numerous sample, mineral oils, as serviced year, we confirmed an increase in relative permittivity of oils. Moreover, we confirmed the superior characteristics of the sensor as a species, aged pattern of oils and operating temperature.

• Proceedings of the KIEE Conference
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• 2004.11d
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• pp.89-92
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• 2004

This paper described the capacitive sensor for the diagnosis of deterioration of electrical insulating oils applying guard-ring type the 3-terminal electrodes. To measure stable capacitance of the sensor and to determine the design factors of the sensor, we utilized computational analysis, FEM software. This capacitive sensor discern the extent of deterioration measuring relative permittivity of electrical insulating oils. The result of measuring numerous sample, mineral oils, as serviced year, we confirmed an increase in relative permittivity of oils. Moreover, we confirmed the superior characteristics of the sensor as a species, aged pattern of oils and operating temperature.

• Tribology and Lubricants
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• v.17 no.2
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• pp.146-152
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• 2001

Environmentally adapted synthetic base oils of polyalkylene glycols (PAGs) and polyol esters (POEs) show a high polarity because of their functional groups containing oxygen atom. The lubricating performance of these polar base oils was investigated by using a four-ball tribometer under boundary lubrication condition. Four polyalkylene glycols and five polyol ester base oils were used as sample base oils of high polarity. A mineral oil (MO) and alkylnaphthalene (AN) were used as low polarity base oils. Tricrecylphosphate (TCP) was added to all the base oils, in the range of 10 mmol/L-2000 mmol/L, as an antiwear additive. All the TCP-for-mutated base oils showed optimum concentration characteristics for minimizing wear. The order of optimum concentration of all the base oils was in a good accordance with the order of relative stability of TCP in base oils. The interaction model on solvation between additive and different polar base oils can expect the stability order of TCP. Thus, the model on solvation can explain well the order of optimum concentration of all the base oils, by using the effect of polarity (dielectric constant, $\varepsilon$) and molecular size (molecular weight, MW) of them on stability of TCP in polar base oils. Finally, a good correlation of the optimum concentration for all the base oils was obtained when it was arranged as a function of C∝(M $W_{Base Oil}$/M $W_{TCP}$)$^{-2}$.71/.($\varepsilon$$_{Base Oil}$)$^{3.38}$ by these two parameters.s..

• Tribology and Lubricants
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• v.17 no.2
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• pp.109-115
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• 2001

The lubricating performance of 23 kinds of polyol ester base oils 〔POEs〕 having different branch shapes was investigated by using a four ball tribometer under boundary lubrication condition. All the polyol ester base oils used in this study were made up of polyhydric alcohols of two-four valence and normal or branched fatty acids of different carbon number. The wear characteristics of polyol ester base oils are different from those of mineral oil, strongly affected by the branch shapes of fatty acids in their molecles. In particular, the polyol ester base oils having normal fatty acids such as n-octanoic acid, n-nonanoic acid etc. show much better wear performance than POEs having branched fatty acids such as 2-ethylhexanoic acid, 3,5,5-trimethyl hexanoic acid, etc. As the carbon chain length of normal fatty acids, in case of POEs of normal fatty acids, is increased, their wear rate is decreased and, in case of POEs of branched fatty acids, as the degree of branch of branched fatty acids is decreased, their wear rate is decreased. All the wear results of polyol ester base oils could be reasonably explained by comparing cohesive ability among fatty acid molecules in adsorption film by fatty acids obtained as POEs were decomposed.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.10a
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• pp.187-188
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• 2005

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11b
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• pp.605-608
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• 2001

With the intention of investigating the breakdown properties of oil-immersed transformer oils in temperature range of $20\sim100[^{\circ}C]$, we are made researches AC breakdown in the gap of $500\sim2500[{\mu}m]$. The classification for the physical properties of oil for oil-immersed transformer by FTIR and H-NMR experiments was confirmed to type of mineral oils. As the dependance of breakdown properties due to electrode gap length variation, breakdown voltage was found increasing according to the increase of gap, while dielectric strength was decreasing. As a result the characteristics for AC breakdown, It goes to prove that the breakdown voltage was increased to $90[^{\circ}C]$ but decreased over $90[^{\circ}C]$ in the temperature range. Also, breakdown voltage was found increasing in the increase of gap and the rising of temperature according to Weibull distribution.